α-MsO/TsO/Cl Ketones as Oxidized Alkyne Equivalents: Redox-Neutral Rhodium(III)-Catalyzed CH Activation for the Synthesis of N-Heterocycles

Arene CH Bond Functionalization Coupling with Cyclization of Allenes

(2013) Rong Zeng et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(III)-Catalyzed C(sp2)H Activation and Electrophilic Amidation withN-Fluorobenzenesulfonimide

(2013) Ren-Jin Tang et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(III)-Catalyzed CC Coupling between Arenes and Aziridines by CH Activation

(2013) Xingwei Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Oxidative Annulation of Sulfoximines and Alkynes as an Approach to 1,2-Benzothiazines

(2013) Wanrong Dong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Indole Synthesis by Rhodium(III)-Catalyzed Hydrazine-Directed CH Activation: Redox-Neutral and Traceless by NN Bond Cleavage

(2013) Dongbing Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Intramolecular Hydroarylation, Amidoarylation, and Heck-type Reaction: Three Distinct Pathways Determined by an Amide Directing Group

(2013) Tyler A. Davis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Redox-Neutral Coupling ofN-Phenoxyacetamides and Alkynes with Tunable Selectivity

(2013) Guixia Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Cp-Rhodium(III)-Catalyzed Asymmetric Hydroarylations of 1,1-Disubstituted Alkenes

(2013) Baihua Ye et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild Rhodium(III)-Catalyzed Cyclization of Amides with α,β-Unsaturated Aldehydes and Ketones to Azepinones: Application to the Synthesis of the Homoprotoberberine Framework

(2013) Zhuangzhi Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

General and Efficient Synthesis of Indoles through Triazene-Directed C-H Annulation

(2013) Chengming Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Oxide as a Traceless Oxidizing Directing Group: Mild Rhodium(III)-Catalyzed CH Olefination for the Synthesis ofortho-Alkenylated Tertiary Anilines

(2013) Xiaolei Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-catalyzed oxidative coupling through C–H activation and annulation directed by phosphonamide and phosphinamide groups

(2013) Sangjune Park et al.   CHEMICAL COMMUNICATIONS

[Cp*RhCl2]2-catalyzed ortho-C–H bond amination of acetophenone o-methyloximes with primary N-chloroalkylamines: convenient synthesis of N-alkyl-2-acylanilines

(2013) Ka-Ho Ng et al.   CHEMICAL COMMUNICATIONS

Transition Metal-Mediated Synthesis of Monocyclic Aromatic Heterocycles

(2013) Anton V. Gulevich et al.   CHEMICAL REVIEWS

Microwave-Assisted, Rhodium(III)-Catalyzed N-Annulation Reactions of Aryl and α,β-Unsaturated Ketones with Alkynes

(2013) Hyejeong Lee et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nickel-Catalyzed Direct Alkylation of Heterocycles with α-Bromo Carbonyl Compounds: C3-Selective Functionalization of 2-Pyridones

(2013) Akihiro Nakatani et al.   CHEMISTRY-A EUROPEAN JOURNAL

A General Method to Diverse Cinnolines and Cinnolinium Salts

(2013) Dongbing Zhao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Spirocyclic Sultam Synthesis by [3+2] Annulation with CyclicN-Sulfonyl Ketimines and Alkynes

(2013) Lin Dong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(III)-Catalyzed Synthesis of Cyclopenta[b]pyrroles from 1,2-Diketones, 2-Aminopyridine, and Alkynes

(2013) Juanjuan Du et al.   Chemistry-An Asian Journal

Aromatic C-H Addition to Ketones: The Effect of Directing Groups

(2013) Xi-Sha Zhang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Rh(III)-Catalyzed C–H Activation and Double Directing Group Strategy for the Regioselective Synthesis of Naphthyridinones

(2013) John R. Huckins et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Efficient Rh/O2 Catalytic System for Oxidative C–H Activation/Annulation: Evidence for Rh(I) to Rh(III) Oxidation by Molecular Oxygen

(2013) Guoying Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Room-Temperature Synthesis of Trisubstituted Allenylsilanes via Regioselective C–H Functionalization

(2013) Rong Zeng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Indole Synthesis Using N–N Bond as an Internal Oxidant

(2013) Baoqing Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Indazole Synthesis by C–H Bond Functionalization and Cyclative Capture

(2013) Yajing Lian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

Rh(III)-Catalyzed Addition of Alkenyl C–H Bond to Isocyanates and Intramolecular Cyclization: Direct Synthesis 5-Ylidenepyrrol-2(5H)-ones

(2013) Wei Hou et al.   ORGANIC LETTERS

Synthesis of Isoquinolines via Rh(III)-Catalyzed C–H Activation Using Hydrazone as a New Oxidizing Directing Group

(2013) Sheng-Chieh Chuang et al.   ORGANIC LETTERS

Access to Indenones by Rhodium(III)-Catalyzed C–H Annulation of Arylnitrones with Internal Alkynes

(2013) Zisong Qi et al.   ORGANIC LETTERS

Rhodium(III)-Amine Dual Catalysis for the Oxidative Coupling of Aldehydes by Directed C–H Activation: Synthesis of Phthalides

(2013) Peng Wen Tan et al.   ORGANIC LETTERS

Nickel-Catalyzed Aromatic C–H Alkylation with Secondary or Tertiary Alkyl–Bromine Bonds for the Construction of Indolones

(2013) Chao Liu et al.   ORGANIC LETTERS

Phosphoryl-Related Directing Groups in Rhodium(III) Catalysis: A General Strategy to Diverse P-Containing Frameworks

(2013) Dongbing Zhao et al.   ORGANIC LETTERS

Rhodium(iii)-catalyzed intramolecular annulations involving amide-directed C–H activations: synthetic scope and mechanistic studies

(2013) Noelia Quiñones et al.   Chemical Science

Controlling Site Selectivity in Palladium-Catalyzed C–H Bond Functionalization

(2012) Sharon R. Neufeldt et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Novel Rhodium-Catalyzed Cascade Cyclization: Direct Synthesis of 3-Substituted Phthalides from Aldehydes and Aromatic Acids

(2012) Xianying Shi et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium-Catalyzed Oxidativeortho-Acylation of Aryl KetoneO-Methyl Oximes with Aryl and Alkyl Aldehydes

(2012) Yaxi Yang et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(III)-Catalyzed Intramolecular Annulation through CH Activation: Total Synthesis of (±)-Antofine, (±)-Septicine, (±)-Tylophorine, and Rosettacin

(2012) Xianxiu Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium/Copper-Catalyzed Annulation of Benzimides with Internal Alkynes: Indenone Synthesis through Sequential CH and CN Cleavage

(2012) Bi-Jie Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Alkenyl CH Bond Functionalization: Convergent Synthesis of Furans and Pyrroles

(2012) Yajing Lian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Access to Sultams by Rhodium(III)-Catalyzed Directed CH Activation

(2012) Manh V. Pham et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

(2012) Nadine Kuhl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rh(III)-catalyzed directed C–H bond amidation of ferrocenes with isocyanates

(2012) Satoshi Takebayashi et al.   Beilstein Journal of Organic Chemistry

From C(sp2)–H to C(sp3)–H: systematic studies on transition metal-catalyzed oxidative C–C formation

(2012) Bi-Jie Li et al.   CHEMICAL SOCIETY REVIEWS

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Cu–Rh Redox Relay Catalysts for Synthesis of Azaheterocycles via C–H Functionalization

(2012) Shunsuke Chiba   CHEMISTRY LETTERS

Investigation and Comparison of the Mechanistic Steps in the [(Cp*MCl2)2] (Cp*=C5Me5; M=Rh, Ir)-Catalyzed Oxidative Annulation of Isoquinolones with Alkynes

(2012) Nuancheng Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanism of the Rhodium(III)-Catalyzed Arylation of Imines via C–H Bond Functionalization: Inhibition by Substrate

(2012) Michael E. Tauchert et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mild Rh(III)-Catalyzed C–H Activation and Annulation with Alkyne MIDA Boronates: Short, Efficient Synthesis of Heterocyclic Boronic Acid Derivatives

(2012) Honggen Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Olefinic C–H Bond Addition to Aryl Aldehyde and Its N-Sulfonylimine via Rh Catalysis

(2012) Yang Li et al.   ORGANIC LETTERS

N-Directing Group Assisted Rhodium-Catalyzed Aryl C–H Addition to Aryl Aldehydes

(2012) Yang Li et al.   ORGANIC LETTERS

Tandem Rh(III)-Catalyzed Oxidative Acylation of Secondary Benzamides with Aldehydes and Intramolecular Cyclization: The Direct Synthesis of 3-Hydroxyisoindolin-1-ones

(2012) Satyasheel Sharma et al.   ORGANIC LETTERS

Rhodium-Catalyzed Synthesis of Branched Amines by Direct Addition of Benzamides to Imines

(2012) Kevin D. Hesp et al.   ORGANIC LETTERS

Rhodium(iii)-catalyzed synthesis of phthalides by cascade addition and cyclization of benzimidates with aldehydes

(2012) Yajing Lian et al.   Chemical Science

Mechanistic understanding of Rh-catalyzed N-sulfonylaldimine insertion into aryl C–H bonds

(2012) Yang Li et al.   Chemical Science

Synthesis of Isoquinolines via Rhodium(III)-Catalyzed Dehydrative CC and CN Coupling between Oximines and Alkynes

(2011) Xingping Zhang et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium-Catalyzed Direct Addition of Aryl CH Bonds to N-Sulfonyl Aldimines

(2011) Yang Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-Pot Synthesis of Isoquinolinium Salts by Rhodium-Catalyzed CH Bond Activation: Application to the Total Synthesis of Oxychelerythrine

(2011) Jayachandran Jayakumar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective Synthesis of Indenols by Rhodium-Catalyzed CH Activation and Carbocyclization of Aryl Ketones and Alkynes

(2011) Krishnamoorthy Muralirajan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

If CH Bonds Could Talk: Selective CH Bond Oxidation

(2011) Timothy Newhouse et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Arylation of α-pivaloxyl ketones with arylboronic reagents via Ni-catalyzed sp3 C–O activation

(2011) Kun Huang et al.   CHEMICAL COMMUNICATIONS

Pyridine synthesis from oximes and alkynesviarhodium(iii) catalysis: Cp* and Cptprovide complementary selectivity

(2011) Todd K. Hyster et al.   CHEMICAL COMMUNICATIONS

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Palladium-catalyzed cross-coupling reactions of aryl mesylates

(2011) Chau Ming So et al.   CHEMICAL SOCIETY REVIEWS

C–H Functionalization in organic synthesis

(2011) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

Transition metal-catalyzed arylation of unactivated C(sp3)–H bonds

(2011) Olivier Baudoin   CHEMICAL SOCIETY REVIEWS

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation

(2011) Seung Hwan Cho et al.   CHEMICAL SOCIETY REVIEWS

Recent developments in natural product synthesis using metal-catalysed C–H bond functionalisation

(2011) Lindsay McMurray et al.   CHEMICAL SOCIETY REVIEWS

Recent Progress in Coupling of Two Heteroarenes

(2011) Dongbing Zhao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Expedient Synthesis ofN-Acyl Anthranilamides and β-Enamine Amides by the Rh(III)-Catalyzed Amidation of Aryl and Vinyl C–H Bonds with Isocyanates

(2011) Kevin D. Hesp et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Arylation of Boc-Imines via C−H Bond Functionalization

(2011) Andy S. Tsai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diverse Strategies toward Indenol and Fulvene Derivatives: Rh-Catalyzed C−H Activation of Aryl Ketones Followed by Coupling with Internal Alkynes

(2011) Frederic W. Patureau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Heterocycle Synthesis Using an Internal Oxidant: Improved Reactivity and Mechanistic Studies

(2011) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Oxidativeortho-Acylation of Benzamides with Aldehydes: Direct Functionalization of the sp2C–H Bond

(2011) Jihye Park et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Intermolecular Direct Amination of Aromatic C–H Bonds with N-Chloroamines

(2011) Ka-Ho Ng et al.   ORGANIC LETTERS

Synthesis of 1-Aminoisoquinolines via Rh(III)-Catalyzed Oxidative Coupling

(2011) Xiaohong Wei et al.   ORGANIC LETTERS

Rh[III]-Catalyzed Direct C–H Amination Using N-Chloroamines at Room Temperature

(2011) Christoph Grohmann et al.   ORGANIC LETTERS

Direct C−H Transformation via Iron Catalysis

(2010) Chang-Liang Sun et al.   CHEMICAL REVIEWS

Overview of the Mechanistic Work on the Concerted Metallation–Deprotonation Pathway

(2010) David Lapointe et al.   CHEMISTRY LETTERS

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Suzuki Cross-Couplings of Activated Secondary Alkyl Electrophiles: Arylations of Racemic α-Chloroamides

(2010) Pamela M. Lundin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Oxidative Cycloaddition of Benzamides and Alkynes via C−H/N−H Activation

(2010) Todd K. Hyster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Oxidative Coupling/Cyclization of 2-Phenylindoles with Alkynes via C−H and N−H Bond Cleavages with Air as the Oxidant

(2010) Keisuke Morimoto et al.   ORGANIC LETTERS

Rhodium-catalyzed oxidative coupling of aromatic imines with internal alkynes via regioselective C–H bond cleavage

(2009) Tatsuya Fukutani et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

Isoquinoline Synthesis via Rhodium-Catalyzed Oxidative Cross-Coupling/Cyclization of Aryl Aldimines and Alkynes

(2009) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Cross-Couplings of Racemic α-Bromoketones with Arylzinc Reagents

(2008) Pamela M. Lundin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Hiyama Cross-Couplings of Racemic α-Bromo Esters

(2008) Xing Dai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Indole Synthesis via Rhodium Catalyzed Oxidative Coupling of Acetanilides and Internal Alkynes

(2008) David R. Stuart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY