期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2013, 期 29, 页码 6530-6534出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201301115
关键词
Rhodium; C-H activation; Nucleophilic addition; Ketones; Directing groups
资金
- 973 Project from the Ministry of Science and Technology (MOST) of China [2009CB825300]
- National Natural Science Foundation of China (NSFC) [20925207, 21002001]
The first example of the transition-metal-catalyzed direct intermolecular C-H bond addition to ketones was achieved by using a rhodium catalyst. A significant influence of the directing group on the reactivity was observed, and sterically more hindered directing groups could promote the reaction. In addition, intermolecular hydrogen bonding played a role in stabilizing the product. The substrate scope for the quinoline derivatives was very good.
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