期刊
ORGANIC LETTERS
卷 15, 期 24, 页码 6166-6169出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol403021p
关键词
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资金
- 973 Program [2012CB725302]
- National Natural Science Foundation of China [21025206, 21272180, 21302148]
- China Postdoctoral Science Foundation [2012M521458]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1030]
A nickel-catalyzed aromatic C-H alkylation with tertiary or secondary alkyl-Br bonds for the construction of indolones was demonstrated. Various functional groups were well tolerated. Moreover, the challenging secondary alkyl bromides were well introduced in this transformation. Radical trapping and photocatalysis conditions exhibited that it is most likely to be a radical process for this aromatic C-H alkylation.
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