期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 33, 页码 13538-13541出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja304219s
关键词
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资金
- Global COE program Center for Practical Chemical Wisdom by MEXT
- Waseda University Grant for Special Research Projects
- [2105]
- [24750096]
- Grants-in-Aid for Scientific Research [23659014, 24750096, 21106009] Funding Source: KAKEN
In this report, we describe an iron(III) complex containing a carbazole-based tridentate ligand that catalyzes highly enantioselective asymmetric epoxidation of (E)-alkenes at room temperature. The non-heme iron(III) complex has a five-coordinated trigonal-bipyramidal structure, and its two-electron oxidized state has the similar electronic structure as that of iron porphyrins.
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