4.6 Article

Porous Formation in p-Type Gallium Nitride Films via 50 Hz Operated Alternating Current-Assisted Photo-Electrochemical Etching in Methanol-Sulfuric Acid Solution

期刊

JOURNAL OF THE ELECTROCHEMICAL SOCIETY
卷 165, 期 10, 页码 H620-H628

出版社

ELECTROCHEMICAL SOC INC
DOI: 10.1149/2.0591810jes

关键词

-

资金

  1. Long Term Research grant Scheme (LRGS) [203/CINOR/6720013]
  2. Universiti Sains Malaysia

向作者/读者索取更多资源

Porous p-type gallium nitride (GaN) films were successfully formed using 50 Hz operated 60 mA alternating current-assisted photo-electrochemical etching for 90 min in 1:0, 1:1, 2:1, and 1:2 volume ratios of sulfuric acid:methanol solutions. The formation of Ga-O-N passivation layer on GaN films etched in 1:1 and 1:2 solutions has served as a barrier to limit etching behavior of the films, leading to the formation of tiny pores, which attenuated emission intensities of E-2(high) and A(1)(TO) phonon modes, and near band edge (NBE) photoluminescence in addition to an emergence of yellow emission band attributable to defects originating from Ga-O-N. The increase of H2SO4 content than that of CH3OH in the 2:1 solution that resulted in the formation of the largest pore size (87.1 nm) has however enhanced emission intensities of E-2(high), A(1)(TO), and NBE without the detection of yellow emission band. Detailed explanation with regard to the pore formation accompanied with defects generation, strain changes and in-plane stress relaxation as well as corresponding effects on optical bandgap of the films has been systematically studied. (C) 2018 The Electrochemical Society.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Chemistry, Analytical

Zinc sulfide based thin film photodetector prepared by spray pyrolysis

Natheer A. Algadri, Ahmad M. AL-Diabat, Naser M. Ahmed

Summary: The chemical spray pyrolysis technique was used to synthesize zinc sulfide thin films without annealing treatment. The ZnS films showed distinct characteristics with different Zn:S ratios, and exhibited a strong response to UV illumination when used in MSM photodetectors.

INSTRUMENTATION SCIENCE & TECHNOLOGY (2023)

Article Engineering, Electrical & Electronic

Fabrication of fluorine and silver co-doped ZnO photodetector using modified hydrothermal method

Aminu Muhammad, Sabah M. Mohammad, Zainuriah Hassan, Suvindraj Rajamanickam, Shireen Mohammed Abed, M. G. B. Ashiq

Summary: The purpose of this study is to enhance the electrical and optical properties of zinc oxide (ZnO) by doping it with silver (Ag) and fluorine (F). F and Ag co-doped ZnO nanorods were synthesized using a modified hydrothermal method, and an ultraviolet metal-semiconductor-metal photodetector (PD) was fabricated. The results showed that the co-doped sample had improved crystal quality, reduced defect density, decreased bandgap, and enhanced sensitivity and response times of the PD.

MICROELECTRONICS INTERNATIONAL (2023)

Article Engineering, Electrical & Electronic

Fabrication of UV ZnO NRS photodetector based on seeded silicon substrate via the drop-casting technique

Shireen Mohammed Abed, Sabah M. Mohammad, Zainuriah Hassan, Aminu Muhammad, Suvindraj Rajamanickam

Summary: This study fabricated a UV metal-semiconductor-metal (MSM) photodetector based on zinc oxide nanorods (ZnO NRs) grown on seeded silicon substrate using a low-cost drop-casting technique. The performance of the fabricated MSM devices was investigated and discussed. The fabricated ZnO NRs UV photodetector showed high stability, photocurrent, sensitivity, and responsivity under 365 nm wavelength illumination and various applied bias.

MICROELECTRONICS INTERNATIONAL (2023)

Article Chemistry, Multidisciplinary

Rapid synthesis of bovine serum albumin-conjugated gold nanoparticles using pulsed laser ablation and their anticancer activity on hela cells

S. A. Abdulateef, Muna E. Raypah, A. F. Omar, M. Z. Mat Jafri, Naser M. Ahmed, Noor Haida Mohd Kaus, Azman Seeni, Mohd Hafiz Mail, Yasser Tabana, Marawan Ahmed, Sara Al Rawashdah, Khaled Barakat

Summary: This study successfully synthesized gold nanoparticles using pulsed laser ablation technique and explored the effects of bovine serum albumin on particle stability and aggregation. The synthesized nanoparticles showed low toxicity and high biocompatibility, making them promising for therapeutic applications.

ARABIAN JOURNAL OF CHEMISTRY (2023)

Article Chemistry, Physical

pH-EGFET Sensor Based on the Surface Modification of MacroPSi with Au-NPs

Lary H. Slewa, Fayroz A. Sabah, Bestoon A. Gozeh, Hazha Omar Othman, Tariq A. Abbas, Naser M. Ahmed

Summary: A heterostructure of (Au-NPs/MacroPSi) was synthesized to enhance the performance of MacroPSi as a pH-EGFET sensor. The results showed that the heterostructure exhibited high pH sensitivity, linearity, and hysteresis, as well as rapid acid and base response.

SILICON (2023)

Article Chemistry, Multidisciplinary

Synthesis and Deposition of Silver Nanowires on Porous Silicon as an Ultraviolet Light Photodetector

Anas A. M. Alqanoo, Naser M. Ahmed, Md. R. Hashim, Munirah A. Almessiere, Sofyan A. Taya, Ahmed Alsadig, Osamah A. Aldaghri, Khalid Hassan Ibnaouf

Summary: The applications of silver nanowires (AgNWs) depend on their purity and morphology. In this study, the morphological changes of AgNWs during growth were tracked to determine the optimal reaction time and temperature. UV-Vis absorption spectra were used to investigate the relationship between reaction time and temperature. An equation was developed to calculate reaction time at any given reaction temperature. The average diameter of the AgNWs was found to be temperature-dependent, with the minimum value observed at a reaction temperature of 150°C. A purification technique was conducted to remove by-products, and an AgNWs-based porous Si device was fabricated and showed high sensitivity and detectivity.

NANOMATERIALS (2023)

Article Materials Science, Multidisciplinary

Coating Readily Available Yet Thermally Resistant Surfaces with 3D Silver Nanowire Scaffolds: A Step toward Efficient Heater Fabrication

Anas A. M. Alqanoo, Naser M. Ahmed, Md Roslan Hashim, Ahmed Alsadig, Shahad Al-Yousif, Sofyan A. Taya, Osamah A. Aldaghri, Khalid Hassan Ibnaouf

Summary: In this study, a 3D network of silver nanowires (AgNWs) was successfully synthesized and characterized. Polyethylene glycol (PEG) and polyvinylpyrrolidone (PVP) were used as the reductant and structure-directing agent, respectively. The AgNW-based heater with a wood substrate showed the shortest response time, highest thermal resistance, and stable temperature at a low bias voltage.

COATINGS (2023)

Article Materials Science, Multidisciplinary

Effect of thermal annealing on ZnO/AlN/GaN/AlN heterostructure grown on Si substrate by radio frequency sputtering

M. Z. Mohd Yusoff, A. Mahyuddin, Z. Hassan, M. S. Yahya

Summary: The study investigates the influence of high thermal annealing on the surface morphological, structural, and optical properties of ZnO/AlN/GaN/AlN layers grown on Si substrate by MBE. ZnO thin film was deposited on AlN/GaN/AlN heterostructures using RF sputtering machine. Thermal annealing at different temperatures (600 degrees C and 800 degrees C) with nitrogen flow was applied to the samples in a vacuum tube furnace. Surface morphological, structural, and optical properties were characterized using FESEM, AFM, HR-XRD, and Raman spectroscopy. The optimal thermal annealing temperature was found to be 600 degrees C, resulting in the lowest dislocation density in the films based on the optical and structural evaluation.

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING (2023)

Article Physics, Applied

Seedless and surfactant-free growth of flower-shaped ZnO nanostructures: Growth evolution mechanism

Muna E. Raypah, Naser M. Ahmed, Naif H. Al-Hardan, Munirah A. Almessiere

Summary: In this study, a novel seedless and surfactant-free CBD method at low temperature was used to fabricate flower-shaped ZnO nanostructures (FZONSs) on glass and p-type silicon substrates for the first time. The structural properties of FZONSs were examined and showed three-dimensional flower-shaped nanomorphology. The grown FZONSs may have potential in various applications including advanced catalysts, sensing devices, and solar cells.

INTERNATIONAL JOURNAL OF MODERN PHYSICS B (2023)

Article Chemistry, Physical

Parasitic behavior of different V/III ratios on the properties of InGaN/GaN heterostructures by MOCVD technique

A. K. Tan, N. A. Hamzah, M. A. Ahmad, S. S. Ng, Z. Hassan

Summary: In this study, InGaN/GaN heterostructures were grown on a flat sapphire substrate using MOCVD technique. Results showed that a higher V/III ratio led to parasitic behavior by hydrogen dissociated from ammonia, which etched the InN and changed the growth morphology. Moreover, the InGaN thin films grown at higher V/III ratios exhibited more stable bandgap energy and improved electrical properties. The correlation between strain and carrier density was also discussed, and it was concluded that high-quality and thick InGaN thin films could be grown for solar cell applications at higher V/III ratio conditions.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Nanoscience & Nanotechnology

A green and facile synthesis of lead-free hybrid organic-inorganic bismuth halides quantum dots for nanophotonics applications

Han Yann Heng, Muhamad Fikri Zaini, Leong Wei Xian Rebecca, Muhammad Aizat Abu Bakar, Mohamad Shuaib Mohamed Saheed, Abdul Razak Ibrahim, Naser Mahmoud Ahmed, Mundzir Abdullah

Summary: There is an urgent need to remove toxic lead from popular halide perovskite used in photonics and optoelectronics. This study demonstrates the synthesis of lead-free halide perovskite using an eco-friendly solvent and characterizes its properties. It also investigates the optical and nonlinear optical properties. This green and facile synthesis approach provides an alternative for the new applications of Bi-based perovskite.

PHOTONICS AND NANOSTRUCTURES-FUNDAMENTALS AND APPLICATIONS (2023)

Proceedings Paper Polymer Science

Tea Plant Leaves for Green Synthesis of Metallic Nanoparticles

Alaa Falih Ismael, Naser M. Ahmed, Khalid H. Ibrahim, Ahmed A. AL-Kubaisi

Summary: Synthesis of metallic nanoparticles using tea plant leaves is a recognized and non-toxic method that offers reduced environmental impact and the potential for large-scale production. The use of plant extracts as both reducing and stabilizing agents allows for better control of shape and size, enabling various applications.

MACROMOLECULAR SYMPOSIA (2023)

Article Materials Science, Ceramics

Poly(ethylene) oxide/erbium oxide as T2 and T1-T2 dual-mode MRI diagnostic nanofibres

Munirah Jamil, Iskandar Shahrim Mustafa, Naser Mahmoud Ahmed, Shahrul Bariyah Sahul Hamid, Thair Hussien Khazaalah, Efenji Godwin, Nabasu Seth Ezra, Hayder Naeem Salah

Summary: Novel magnetic resonance imaging (MRI) diagnostic nanofibres were synthesized by embedding Er2O3 nanoparticles (2% to 8%) in the PEO matrix using electrospinning. The resulting PEO/Er2O3 nanofibres were characterized and evaluated for their magnetic relaxivity in MRI contrast enhancement. The addition of Er2O3 nanoparticles led to changes in the conformational structure and crystalline properties of the nanofibres, demonstrating potential T2 and T1-T2 dual-mode diagnostic capabilities in MRI 1.5T.

CERAMICS INTERNATIONAL (2023)

Article Optics

Thermoluminescence properties of TiO2/Cu/TiO2 multilayer thin films fabricated by (RF/DC) sputtering for radiation dosimetry

Ali Saleh Alkadem Idriss, Nik Noor Ashikin Nik Ab Razak, Naser M. Ahmed, Youssef Aboubaker Abdulla

Summary: A novel TiO2/Cu/TiO2 multilayer thin film dosimeter with faster deposition rate, high purity, and uniformity was fabricated. The film has an amorphous, porous structure with spherical nanoparticles and is transparent in the visible region. The optimum TL intensity was found with the TiO2 (445 nm) / 14.2 nm Cu / TiO2 (130 nm) sequence. The multilayer film is suitable for thermoluminescence dosimetric applications.

JOURNAL OF LUMINESCENCE (2023)

Review Chemistry, Physical

The most important parameters that affect the photocatalytic activity of ZnO nanostructures against organic dyes: A Review

Marwa Jawad Kadhim, Mazin Auny Mahdi, Abbas Mohammed Selman, Salwan Kamal Jamel Al-Ani, Jalal Jabar Hassan, Naser Mohammed Ahmed

Summary: Organic dyes are a major source of water pollution, causing serious health problems for living organisms. The removal of dye pollution is crucial due to its high toxicity, leading to increased interest from researchers. Heterogeneous photocatalysis based on ZnO is an important method for pollution treatment, and this review focuses on the use of ZnO nanostructure and modified ZnO as photocatalysts, discussing the mechanisms and factors influencing the photocatalytic process.

IRANIAN JOURNAL OF CATALYSIS (2023)

暂无数据