Palladium-Catalyzed Enantioselective Desymmetrizing Aza-Wacker Reaction: Development and Application to the Total Synthesis of (−)-Mesembrane and (+)-Crinane

Palladium-Catalyzed Enantioselective C–H Activation of Aliphatic Amines Using Chiral Anionic BINOL-Phosphoric Acid Ligands

(2017) Adam P. Smalley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Palladium-Catalyzed Oxidative Cascade Cyclization of Aliphatic Alkenyl Amides

(2017) Wei Du et al.   ORGANIC LETTERS

Asymmetric Syntheses of Amaryllidaceae Alkaloids (−)-Crinane and (+)-4a-Dehydroxycrinamabine

(2017) Ya-Ru Gao et al.   ORGANIC LETTERS

Efficient syntheses of (−)-crinine and (−)-aspidospermidine, and the formal synthesis of (−)-minfiensine by enantioselective intramolecular dearomative cyclization

(2017) Kang Du et al.   Chemical Science

Bioinspired enantioselective synthesis of crinine-type alkaloids via iridium-catalyzed asymmetric hydrogenation of enones

(2017) Xiao-Dong Zuo et al.   Chemical Science

Palladium(0)-catalyzed asymmetric C(sp3)–H arylation using a chiral binol-derived phosphate and an achiral ligand

(2017) Lei Yang et al.   Chemical Science

Synthesis of Diversely Functionalized Oxindoles Enabled by Migratory Insertion of Isocyanide to a Transient σ-Alkylpalladium(II) Complex

(2016) Wangqing Kong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Enantioselective Bidentate Auxiliary Directed Palladium-Catalyzed Benzylic C−H Arylation of Amines Using a BINOL Phosphate Ligand

(2016) Hao Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Desymmetrization Reactions to All-Carbon Quaternary Stereocenters

(2016) Xing-Ping Zeng et al.   CHEMICAL REVIEWS

Enantioselective Synthesis of (+)-Peganumine A

(2016) Cyril Piemontesi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Allylic C–H Alkylation of Terminal Olefins with Pyrazol-5-ones Enabled by Cooperative Catalysis of Palladium Complex and Brønsted Acid

(2016) Hua-Chen Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Amaryllidaceae and Sceletium alkaloids

(2016) Zhong Jin   NATURAL PRODUCT REPORTS

Enantioselective amine α-functionalization via palladium-catalysed C–H arylation of thioamides

(2016) Pankaj Jain et al.   Nature Chemistry

Enantioselective Total Syntheses of (−)-Rhazinilam, (−)-Leucomidine B, and (+)-Leuconodine F

(2015) Dylan Dagoneau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)/Brønsted Acid-Catalyzed Enantioselective Oxidative Carbocyclization-Borylation of Enallenes

(2015) Tuo Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Enantioselective Domino Heck/Intermolecular C–H Bond Functionalization: Development and Application to the Synthesis of (+)-Esermethole

(2015) Wangqing Kong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Syntheses of (−)-Mersicarpine, (−)-Scholarisine G, (+)-Melodinine E, (−)-Leuconoxine, (−)-Leuconolam, (−)-Leuconodine A, (+)-Leuconodine F, and (−)-Leuconodine C: Self-Induced Diastereomeric Anisochronism (SIDA) Phenomenon for Scholarisine G and Leuconodines A and C

(2015) Zhengren Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Asymmetric Arylation of C(sp3)–H Bonds of Aliphatic Amides: Controlling Enantioselectivity Using Chiral Phosphoric Amides/Acids

(2015) Shao-Bai Yan et al.   ORGANIC LETTERS

Pd(ii)-catalyzed intermolecular enantioselective hydroamination of styrenes

(2015) Feng Yu et al.   Organic Chemistry Frontiers

Phosphoric Acid Catalyzed Desymmetrization of Bicyclic Bislactones Bearing an All-Carbon Stereogenic Center: Total Syntheses of (−)-Rhazinilam and (−)-Leucomidine B

(2014) Jean-Baptiste Gualtierotti et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Counteranion Strategy for Asymmetric Oxidative C(sp3)H/C(sp3)H Coupling: Enantioselective α-Allylation of Aldehydes with Terminal Alkenes

(2014) Pu-Sheng Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Thesyn/anti-Dichotomy in the Palladium-Catalyzed Addition of Nucleophiles to Alkenes

(2014) Pavel Kočovský et al.   CHEMISTRY-A EUROPEAN JOURNAL

Importance of Ligand Exchanges in Pd(II)-Brønsted Acid Cooperative Catalytic Approach to Spirocyclic Rings

(2014) Garima Jindal et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly enantioselective oxidative tandem cyclization reaction: a chiral ligand and an anion cooperatively control stereoselectivity

(2014) Yu-Ping He et al.   Organic Chemistry Frontiers

Catalytic Enantioselective Michael Addition of α-Aryl-α-Isocyanoacetates to Vinyl Selenone: Synthesis of α,α-Disubstituted α-Amino Acids and (+)- and (−)-Trigonoliimine A

(2013) Thomas Buyck et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Palladium(II) Phosphate Catalyzed Three-Component Reactions of Pyrrole, Diazoesters, and Imines

(2013) Dan Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Decarboxylative Vinylation of Potassium Nitrophenyl Acetate: Application to the Total Synthesis of (±)-Goniomitine

(2013) Zhengren Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis ofAmaryllidaceaeAlkaloids (+)-Vittatine, (+)-epi-Vittatine, and (+)-Buphanisine

(2013) Meng-Xue Wei et al.   Chemistry-An Asian Journal

Construction of a Chiral Quaternary Carbon Center by Catalytic Asymmetric Alkylation of 2-Arylcyclohexanones under Phase-Transfer Conditions

(2013) Taichi Kano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Enantioselective C–H Iodination: Asymmetric Synthesis of Chiral Diarylmethylamines

(2013) Ling Chu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Cascade Annulation Based on Enantioselective Oxa-Diels–Alder Cycloaddition of in Situ Generated Isochromenyliums by Cooperative Binary Catalysis of Pd(OAc)2 and (S)-Trip

(2013) Shu-Yan Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Monodentate Phosphines and Bulky Carboxylic Acids: Cooperative Effects in Palladium-Catalyzed Enantioselective C(sp3)-H Functionalization

(2012) Tanguy Saget et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reconciling the Stereochemical Course of Nucleopalladation with the Development of Enantioselective Wacker-Type Cyclizations

(2012) Adam B. Weinstein et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Asymmetric Aerobic Aza-Wacker-Type Cyclization: Synthesis of Isoindolinones Bearing Tetrasubstituted Carbon Stereocenters

(2012) Guoqiang Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Above-Room-Temperature Magnetodielectric Coupling in a Possible Molecule-Based Multiferroic: Triethylmethylammonium Tetrabromoferrate(III)

(2012) Hong-Ling Cai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium(II)-Catalyzed Enantio- and Diastereoselective Synthesis of Pyrrolidine Derivatives

(2012) Ranjan Jana et al.   ORGANIC LETTERS

Pd(II)-catalyzed asymmetric Wacker-type cyclization for the preparation of 2-vinylchroman derivatives with biphenyl tetraoxazoline ligands

(2012) Qingchuan Liu et al.   TETRAHEDRON

A Highly Enantioselective Overman Rearrangement through Asymmetric Counteranion-Directed Palladium Catalysis

(2011) Gaoxi Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications

(2011) Richard I. McDonald et al.   CHEMICAL REVIEWS

Pd(II)-Catalyzed Enantioselective C–H Activation of Cyclopropanes

(2011) Masayuki Wasa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Pd(II)-Catalyzed Aerobic Oxidative Amidation of Alkenes and Insights into the Role of Electronic Asymmetry in Pyridine-Oxazoline Ligands

(2011) Richard I. McDonald et al.   ORGANIC LETTERS

Pd(II)-SPRIX catalyzed enantioselective construction of pyrrolizines/pyrroloindoles employing molecular oxygen as the sole oxidant

(2011) Chennan Ramalingan et al.   TETRAHEDRON

Desymmetrization of cyclohexadienones via cinchonine derived thiourea-catalyzed enantioselective aza-Michael reaction and total synthesis of (-)-Mesembrine

(2011) Qing Gu et al.   Chemical Science

Dimethoxydibenzophosphepine: An Axially Chiral Monophosphane for Efficient Asymmetric Catalysis

(2010) Elisabetta Alberico et al.   ChemCatChem

Unifying Metal and Brønsted Acid Catalysis-Concepts, Mechanisms, and Classifications

(2010) Magnus Rueping et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Wacker-Type Cyclization of 2-Alkenyl-1,3-diketones Promoted by Pd-SPRIX Catalyst

(2010) Kazuhiro Takenaka et al.   ORGANIC LETTERS

Pd-catalyzed asymmetric aza-Wacker-type cyclization reaction of olefinic tosylamides

(2010) Feng Jiang et al.   TETRAHEDRON LETTERS

Recent Applications of Oxazoline-Containing Ligands in Asymmetric Catalysis

(2009) Gráinne C. Hargaden et al.   CHEMICAL REVIEWS

Birch Reductive Alkylation of Biaryls: Scope and Limitations

(2009) Raphaël Lebeuf et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Intramolecular Oxidative Aminocarbonylation of Alkenylureas Catalyzed by Palladium−Spiro Bis(isoxazoline) Complexes

(2009) Tetsuya Tsujihara et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd(II)/tBu-quinolineoxazoline: An Air-Stable and Modular Chiral Catalyst System for Enantioselective Oxidative Cascade Cyclization

(2009) Wei He et al.   ORGANIC LETTERS

PdII-Catalyzed Enantioselective Activation of C(sp2)H and C(sp3)H Bonds Using Monoprotected Amino Acids as Chiral Ligands

(2008) Bing-Feng Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sceletium—A review update

(2008) N. Gericke et al.   JOURNAL OF ETHNOPHARMACOLOGY

Stereoselective Synthesis of Saturated Heterocycles via Palladium-Catalyzed Alkene Carboetherification and Carboamination Reactions

(2008) John Wolfe   SYNLETT