Synthesis of Diversely Functionalized Oxindoles Enabled by Migratory Insertion of Isocyanide to a Transient σ-Alkylpalladium(II) Complex

Pd-Catalyzed α-Selective C–H Functionalization of Olefins: En Route to 4-Imino-β-Lactams

(2016) Wei-Jun Kong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Asymmetric Reductive Heck Reaction of Aryl Halides

(2015) Guizhou Yue et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Domino Heck/borylation sequence towards indolinone-3-methyl boronic esters: trapping of the σ-alkylpalladium intermediate with boron

(2015) Dipak D. Vachhani et al.   CHEMICAL COMMUNICATIONS

Pd-Catalyzed Csp2H Functionalization of Heteroarenes via Isocyanide Insertion: Concise Synthesis of Di-(Hetero)Aryl Ketones and Di-(Hetero)Aryl Alkylamines

(2015) Upendra K. Sharma et al.   CHEMISTRY-A EUROPEAN JOURNAL

Pd/C-Catalyzed Cyclizative Cross-Coupling of Twoortho-Alkynylanilines under Aerobic Conditions: Synthesis of 2,3′-Bisindoles

(2015) Bo Yao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Domino Carbopalladation/CH Functionalization Sequence: An Expedient Synthesis of Bis-Heteroaryls through Transient Alkyl/Vinyl-Palladium Species Capture

(2015) Upendra K. Sharma et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Enantioselective Domino Heck/Intermolecular C–H Bond Functionalization: Development and Application to the Synthesis of (+)-Esermethole

(2015) Wangqing Kong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Arylative Dearomatization of Indoles via Pd-Catalyzed Intramolecular Reductive Heck Reactions

(2015) Chong Shen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Formal [4 + 1] Cycloaddition of Benzamides and Isonitriles via Directed C–H Cleavage

(2015) Kazutaka Takamatsu et al.   ORGANIC LETTERS

Difunctionalization of Acrylamides through C–H Oxidative Radical Coupling: New Approaches to Oxindoles

(2015) Jin-Heng Li et al.   SYNTHESIS-STUTTGART

Tuning the Reactivity of Isocyano Group: Synthesis of Imidazoles and Imidazoliums from Propargylamines and Isonitriles in the Presence of Multiple Catalysts

(2014) Shuo Tong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Oxidative Difunctionalization of Alkenes with α-Carbonyl Alkyl Bromides Initiated through a Heck-type Insertion: A Route to Indolin-2-ones

(2014) Jian-Hong Fan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed selective aminoamidation and aminocyanation of alkenes using isonitrile as amide and cyanide sources

(2014) Huanfeng Jiang et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Imidoylative Cyclization of α-Isocyanoacetamides: Efficient Access to C2-Diversified Oxazoles

(2014) Jian Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Alkylation of Terminal Alkynes with Transient σ-Alkylpalladium(II) Complexes: A Carboalkynylation Route to Alkyl-Substituted Alkynes

(2014) Ming-Bo Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Triple Role of Phenylselenonyl Group Enabled a One-Pot Synthesis of 1,3-Oxazinan-2-ones From α-Isocyanoacetates, Phenyl Vinyl Selenones, and Water

(2014) Thomas Buyck et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Overcoming the limitations of directed C–H functionalizations of heterocycles

(2014) Yue-Jin Liu et al.   NATURE

Palladium-Catalyzed Tandem Intramolecular Oxy/Amino-Palladation/Isocyanide Insertion: Synthesis of α-Benzofuranyl/Indolylacetamides

(2014) Nuligonda Thirupathi et al.   ORGANIC LETTERS

An Efficient Route to 3-Amidylindolesviaa Palladium- Catalyzed Tandem Reaction of 2-Alkynylanilines with Isocyanides

(2013) Guanyinsheng Qiu et al.   ADVANCED SYNTHESIS & CATALYSIS

Switchable Synthesis of 3-Cyanoindoles and 3-Amidylindolesviaa Palladium-Catalyzed Reaction ofN,N-Dimethyl-2-alkynylaniline with Isocyanide

(2013) Guanyinsheng Qiu et al.   ADVANCED SYNTHESIS & CATALYSIS

Three-Component Metal-Free Arylation of Isocyanides

(2013) Unnamatla M. V. Basavanag et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Zinc Bromide Promoted Coupling of Isonitriles with Carboxylic Acids To Form 2,4,5-Trisubstituted Oxazoles

(2013) Yann Odabachian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Michael Addition of α-Aryl-α-Isocyanoacetates to Vinyl Selenone: Synthesis of α,α-Disubstituted α-Amino Acids and (+)- and (−)-Trigonoliimine A

(2013) Thomas Buyck et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Migratory Insertion of Isocyanides: An Emerging Platform in Cross-Coupling Chemistry

(2013) Tjøstil Vlaar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Through-Space C(sp3)H and C(sp2)H Bond Activation by 1,4-Palladium Migration: Efficient Synthesis of [3,4]-Fused Oxindoles

(2013) Tiffany Piou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed Cyclizative Cross-Coupling ofortho-Alkynylanilines withortho-Alkynylbenzamides under Aerobic Conditions

(2013) Bo Yao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in isocyanide insertion chemistry

(2013) Guanyinsheng Qiu et al.   CHEMICAL SOCIETY REVIEWS

Unravelling the labyrinth of palladium-catalysed reactions involving isocyanides

(2013) Stuart Lang   CHEMICAL SOCIETY REVIEWS

Tertiary Amines as Synthetic Equivalents of Vinyl Cations: Zinc Bromide Promoted Coupling of Propargylamines with α-Isocyanoacetamides To Give 2,4,5-Trisubstituted Oxazoles Initiated by an Internal Redox Process

(2013) Yann Odabachian et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Multicomponent Synthesis of 2-Aryl-2-imidazolines from Aryl Halides and Diamines

(2013) Joanna V. Geden et al.   JOURNAL OF ORGANIC CHEMISTRY

A Transition-Metal-Free Synthesis of Arylcarboxyamides from Aryl Diazonium Salts and Isocyanides

(2013) Zhonghua Xia et al.   ORGANIC LETTERS

Pd-Catalyzed Heck-Type Cascade Reactions with N-Tosyl Hydrazones: An Efficient Way to Alkenes via in Situ Generated Alkylpalladium

(2013) Xianglei Liu et al.   ORGANIC LETTERS

Activation of a C(sp3)H Bond by a Transient σ-Alkylpalladium(II) Complex: Synthesis of Spirooxindoles Through a Palladium-Catalyzed Domino Carbopalladation/C(sp3)C(sp3) Bond-Forming Process

(2012) Tiffany Piou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed cyclization of o-alkynyltrifluoroacetanilides followed by isocyanide insertion: synthesis of 2-substituted 1H-indole-3-carboxamides

(2012) Ziwei Hu et al.   CHEMICAL COMMUNICATIONS

Direct carboxamidation of indoles by palladium-catalyzed C–H activation and isocyanide insertion

(2012) Jiangling Peng et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Synthesis of Isocoumarins and Phthalides via tert-Butyl Isocyanide Insertion

(2012) Xiang-Dong Fei et al.   JOURNAL OF ORGANIC CHEMISTRY

The asymmetric Heck and related reactions

(2011) Dennis Mc Cartney et al.   CHEMICAL SOCIETY REVIEWS

Renaissance of Organic Synthesis Using Isocyanides

(2011) Mamoru Tobisu et al.   CHEMISTRY LETTERS

Transition-Metal-Mediated Routes to 3,3-Disubstituted Oxindoles through Anilide Cyclisation

(2011) Johannes E. M. N. Klein et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

A Powerful Palladium-Catalyzed Multicomponent Process for the Preparation of Oxazolines and Benzoxazoles

(2011) Patrick J. Boissarie et al.   ORGANIC LETTERS

Isocyanides in the Synthesis of Nitrogen Heterocycles

(2010) Alexander V. Lygin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Domino Process to Spirooxindoles: Ligand Effect on Aminopalladation versus Carbopalladation

(2010) Stéphanie Jaegli et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Cyclocoupling of 2-Halobiaryls with Isocyanides via the Cleavage of Carbon−Hydrogen Bonds

(2010) Mamoru Tobisu et al.   JOURNAL OF ORGANIC CHEMISTRY

Six-Component Reactions for the Stereoselective Synthesis of 3-Arylidene-2-oxindoles via Sequential One-Pot Ugi/Heck Carbocyclization/Sonogashira/Nucleophilic Addition

(2010) Morteza Bararjanian et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Carbo-Heterofunctionalization of Alkenes for the Synthesis of Oxindoles and Spirooxindoles

(2010) Stéphanie Jaegli et al.   ORGANIC LETTERS

Palladium-catalyzed domino Heck/cyanation: synthesis of 3-cyanomethyloxindoles and their conversion to spirooxoindoles

(2010) Stéphanie Jaegli et al.   TETRAHEDRON

Palladium-Catalyzed Carbonylation Reactions of Aryl Halides and Related Compounds

(2009) Anne Brennführer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed Decarboxylative [4+1] Cyclization of γ-Methylidene-δ-valerolactones with Isocyanides

(2009) Soyoung Park et al.   CHEMISTRY LETTERS

Domino Palladium-Catalyzed Heck-Intermolecular Direct Arylation Reactions

(2009) Olivier René et al.   ORGANIC LETTERS

Enantioselective Synthesis of 3,3-Disubstituted Oxindoles through Pd-Catalyzed Cyanoamidation

(2008) Yoshizumi Yasui et al.   ORGANIC LETTERS