Direct Carboxylation of C(sp3)-H and C(sp2)-H Bonds with CO2 by Transition-Metal-Catalyzed and Base-Mediated Reactions

A Schiff base-modified silver catalyst for efficient fixation of CO2 as carboxylic acid at ambient pressure

(2017) Zhilian Wu et al.   GREEN CHEMISTRY

Cobalt-Catalyzed Allylic C(sp3)–H Carboxylation with CO2

(2017) Kenichi Michigami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct β-Selective Hydrocarboxylation of Styrenes with CO2 Enabled by Continuous Flow Photoredox Catalysis

(2017) Hyowon Seo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-Selective Catalytic Carboxylation of Unsaturated Hydrocarbons with CO2 and Water

(2017) Morgane Gaydou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote carboxylation of halogenated aliphatic hydrocarbons with carbon dioxide

(2017) Francisco Juliá-Hernández et al.   NATURE

Synthesis of 2-aryloxy butenoates by copper-catalysed allylic C–H carboxylation of allyl aryl ethers with carbon dioxide

(2017) Atsushi Ueno et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Transition-Metal-Free Lactonization of sp2 C–H Bonds with CO2

(2017) Zhen Zhang et al.   ORGANIC LETTERS

Mechanistic study of the rhodium-catalyzed carboxylation of simple aromatic compounds with carbon dioxide

(2017) Takuya Suga et al.   Chemical Science

The chemistry of metal–organic frameworks for CO2 capture, regeneration and conversion

(2017) Christopher A. Trickett et al.   Nature Reviews Materials

Inserting CO2into Aryl C−H Bonds of Metal-Organic Frameworks: CO2Utilization for Direct Heterogeneous C−H Activation

(2016) Wen-Yang Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lactamization of sp2 C−H Bonds with CO2 : Transition-Metal-Free and Redox-Neutral

(2016) Zhen Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Light/Ketone/Copper System for Carboxylation of Allylic C−H Bonds of Alkenes with CO2

(2016) Naoki Ishida et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carboxylation of Phenols with CO2 at Atmospheric Pressure

(2016) Junfei Luo et al.   CHEMISTRY-A EUROPEAN JOURNAL

C–H carboxylation of heteroarenes with ambient CO2

(2016) Sabine Fenner et al.   GREEN CHEMISTRY

Carboxylative cyclization of substituted propenyl ketones using CO2: transition-metal-free synthesis of α-pyrones

(2016) Wen-Zhen Zhang et al.   GREEN CHEMISTRY

Silver nanoparticles embedded over porous metal organic frameworks for carbon dioxide fixation via carboxylation of terminal alkynes at ambient pressure

(2016) Rostam Ali Molla et al.   JOURNAL OF COLLOID AND INTERFACE SCIENCE

Carbon dioxide utilization via carbonate-promoted C–H carboxylation

(2016) Aanindeeta Banerjee et al.   NATURE

Photoredox activation of carbon dioxide for amino acid synthesis in continuous flow

(2016) Hyowon Seo et al.   Nature Chemistry

Metal-Catalyzed Carboxylation of Organic (Pseudo)halides with CO2

(2016) Marino Börjesson et al.   ACS Catalysis

Synthesis of Carboxylic Acids and Esters from CO2

(2016) Xiao-Feng Wu et al.   Topics in Current Chemistry

Organocatalyzed CO2Trapping Using Alkynyl Indoles

(2015) Zhuo Xin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition metal complex catalyzed carboxylation reactions with CO2

(2015) Dingyi Yu et al.   COORDINATION CHEMISTRY REVIEWS

Using sustainable metals to carry out “green” transformations: Fe- and Cu-catalyzed CO2 monetization

(2015) Afroditi Pinaka et al.   COORDINATION CHEMISTRY REVIEWS

Lithium tert-Butoxide-Mediated Carboxylation Reactions of Unprotected Indoles and Pyrroles with Carbon Dioxide

(2015) Shū Kobayashi et al.   HETEROCYCLES

Organic reactions for the electrochemical and photochemical production of chemical fuels from CO 2 – The reduction chemistry of carboxylic acids and derivatives as bent CO 2 surrogates

(2015) Oana R. Luca et al.   JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY B-BIOLOGY

Light-Driven Carboxylation of o-Alkylphenyl Ketones with CO2

(2015) Yusuke Masuda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

How to make the most of carbon dioxide

(2015) XiaoZhi Lim   NATURE

Photochemical Reduction of CO2 Using 1,3-Dimethylimidazolylidene

(2015) Derek M. Denning et al.   ORGANIC LETTERS

Using carbon dioxide as a building block in organic synthesis

(2015) Qiang Liu et al.   Nature Communications

An Efficient Nanoscale Heterogeneous Catalyst for the Capture and Conversion of Carbon Dioxide at Ambient Pressure

(2014) Xiao-Huan Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A critical review of CO2 photoconversion: Catalysts and reactors

(2014) Kimfung Li et al.   CATALYSIS TODAY

Direct carboxylation of simple arenes with CO2 through a rhodium-catalyzed C–H bond activation

(2014) Takuya Suga et al.   CHEMICAL COMMUNICATIONS

Copper-Catalyzed Formal CH Carboxylation of Aromatic Compounds with Carbon Dioxide through Arylaluminum Intermediates

(2014) Atsushi Ueno et al.   Chemistry-An Asian Journal

Switching the Reaction Course of Electrochemical CO2 Reduction with Ionic Liquids

(2014) Liyuan Sun et al.   LANGMUIR

Photocatalytic Carboxylation of Organic Substrates with Carbon Dioxide at Zinc Sulfide with Deposited Ruthenium Nanoparticles

(2014) Tomasz Baran et al.   ChemPlusChem

Catalytic conversion of carbon dioxide to carboxylic acid derivatives

(2014) An-Hua Liu et al.   Greenhouse Gases-Science and Technology

Sequential carboxylation/intramolecular cyclization reaction of o-alkynyl acetophenone with CO2

(2014) Wen-Zhen Zhang et al.   Organic Chemistry Frontiers

Silver-catalyzed C–C bond formation with carbon dioxide: significant synthesis of dihydroisobenzofurans

(2013) Kohei Sekine et al.   CHEMICAL COMMUNICATIONS

Catalysis for the Valorization of Exhaust Carbon: from CO2 to Chemicals, Materials, and Fuels. Technological Use of CO2

(2013) Michele Aresta et al.   CHEMICAL REVIEWS

Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation

(2013) Aaron M. Appel et al.   CHEMICAL REVIEWS

Palladium(II)-Catalyzed Direct Carboxylation of Alkenyl C–H Bonds with CO2

(2013) Kota Sasano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of 2(1H)-Quinolinones via Pd-Catalyzed Oxidative Cyclocarbonylation of 2-Vinylanilines

(2013) Jamie Ferguson et al.   ORGANIC LETTERS

Palladium-Catalyzed Oxidative Insertion of Carbon Monoxide to N-Sulfonyl-2-aminobiaryls through C–H Bond Activation: Access to Bioactive Phenanthridinone Derivatives in One Pot

(2013) Venkatachalam Rajeshkumar et al.   ORGANIC LETTERS

Direct Carboxylative Reactions for the Transformation of Carbon Dioxide into Carboxylic Acids and Derivatives

(2013) Xiaohua Cai et al.   SYNTHESIS-STUTTGART

Ionic Liquid Co-catalyzed Artificial Photosynthesis of CO

(2013) Jinliang Lin et al.   Scientific Reports

CC Bond Formation with Carbon Dioxide Promoted by a Silver Catalyst

(2012) Satoshi Kikuchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photochemical and Photoelectrochemical Reduction of CO2

(2012) Bhupendra Kumar et al.   Annual Review of Physical Chemistry

Synthesis of phenanthridinones viapalladium-catalyzed C(sp2)–H aminocarbonylation of unprotected o-arylanilines

(2012) Dongdong Liang et al.   CHEMICAL COMMUNICATIONS

Recent developments in carbon dioxide utilization for the production of organic chemicals

(2012) Iwao Omae   COORDINATION CHEMISTRY REVIEWS

Synthesis of Arylglycine and Mandelic Acid Derivatives through Carboxylations of α-Amido and α-Acetoxy Stannanes with Carbon Dioxide

(2012) Tsuyoshi Mita et al.   JOURNAL OF ORGANIC CHEMISTRY

In Situ Spectroscopic Examination of a Low Overpotential Pathway for Carbon Dioxide Conversion to Carbon Monoxide

(2012) Brian A. Rosen et al.   Journal of Physical Chemistry C

Sequential Protocol for C(sp3)–H Carboxylation with CO2: Transition-Metal-Catalyzed Benzylic C–H Silylation and Fluoride-Mediated Carboxylation

(2012) Tsuyoshi Mita et al.   ORGANIC LETTERS

Base-Mediated Carboxylation of Unprotected Indole Derivatives with Carbon Dioxide

(2012) Woo-Jin Yoo et al.   ORGANIC LETTERS

Direct C–H Carboxylation with Carbon Dioxide Using 1,2,3-Triazol-5-ylidene Copper(I) Complexes

(2012) Hiroshi Inomata et al.   ORGANIC LETTERS

Catalytic Hydrocarboxylation of Alkenes and Alkynes with CO2

(2011) Yugen Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylation of Alkylboranes by N-Heterocyclic Carbene Copper Catalysts: Synthesis of Carboxylic Acids from Terminal Alkenes and Carbon Dioxide

(2011) Takeshi Ohishi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Catalyzed Carboxylation of CH Bonds

(2011) Lutz Ackermann   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Influence of reactor geometry on the yield of CO2 photocatalytic reduction

(2011) Kamila Kočí et al.   CATALYSIS TODAY

Thermodynamics and kinetics of CO2, CO, and H+ binding to the metal centre of CO2reductioncatalysts

(2011) Jacob Schneider et al.   CHEMICAL SOCIETY REVIEWS

Ambient carboxylation on a supported reversible CO2 carrier: ketone to β-keto ester

(2011) Eric J. Beckman et al.   GREEN CHEMISTRY

Imidazolidene Carboxylate Bound MBPh4Complexes (M = Li, Na) and Their Relevance in Transcarboxylation Reactions

(2011) Bret R. Van Ausdall et al.   JOURNAL OF ORGANIC CHEMISTRY

Visible Light Photocatalytic H2-Production Activity of CuS/ZnS Porous Nanosheets Based on Photoinduced Interfacial Charge Transfer

(2011) Jun Zhang et al.   NANO LETTERS

Copper-Catalyzed Carboxylation of Alkylboranes with Carbon Dioxide: Formal Reductive Carboxylation of Terminal Alkenes

(2011) Hirohisa Ohmiya et al.   ORGANIC LETTERS

Efficient One-to-One Coupling of Easily Available 1,3-Dienes with Carbon Dioxide

(2011) Jun Takaya et al.   ORGANIC LETTERS

Ionic Liquid-Mediated Selective Conversion of CO2 to CO at Low Overpotentials

(2011) B. A. Rosen et al.   SCIENCE

Synthesis of Propiolic Acids via Copper-Catalyzed Insertion of Carbon Dioxide into the CH Bond of Terminal Alkynes

(2010) Lukas J. Gooßen et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-Catalyzed Direct Carboxylation of CH Bonds with Carbon Dioxide

(2010) Liang Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylation of NH/CH Bonds Using N-Heterocyclic Carbene Copper(I) Complexes

(2010) Ine I. F. Boogaerts et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct C–H carboxylation with complexes of the coinage metals

(2010) Ine I. F. Boogaerts et al.   CHEMICAL COMMUNICATIONS

Palladium catalyzed carboxylation of allylstannanes and boranes using CO2

(2010) Jianguo Wu et al.   CHEMICAL COMMUNICATIONS

Gold(I)-Mediated C−H Activation of Arenes

(2010) Pengfei Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carboxylation of C−H Bonds UsingN-Heterocyclic Carbene Gold(I) Complexes

(2010) Ine I. F. Boogaerts et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(I)-Catalyzed Direct Carboxylation of Arenes with CO2via Chelation-Assisted C−H Bond Activation

(2010) Hajime Mizuno et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H carboxylation takes gold

(2010) Derek M Dalton et al.   Nature Chemistry

Carbon Dioxide as the C1 Source for Direct C−H Functionalization of Aromatic Heterocycles

(2010) Oleg Vechorkin et al.   ORGANIC LETTERS

DFT Studies on the Carboxylation of Arylboronate Esters with CO2Catalyzed by Copper(I) Complexes

(2010) Li Dang et al.   ORGANOMETALLICS

Synthesis of β,γ-Unsaturated Acids from Allenes and Carbon Dioxide

(2009) Michael North   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Catalyzed Carboxylation of Organometallic Reagents with Carbon Dioxide

(2009) Arkaitz Correa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Biocatalytic carboxylation

(2009) Silvia M. Glueck et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of (E)-3-(Isobenzofuran-3(1H)-ylidene)indolin-2-ones by the Palladium-Catalyzed Intramolecular C−H Functionalization Process

(2009) Peng Peng et al.   JOURNAL OF ORGANIC CHEMISTRY

A Systematic Investigation of Factors Influencing the Decarboxylation of Imidazolium Carboxylates

(2009) Bret R. Van Ausdall et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Direct Carboxylation of Aryl Bromides with Carbon Dioxide

(2009) Arkaitz Correa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

β-Hydroxycarboxylic Acids from Simple Ketones by Carboxylation and Asymmetric Hydrogenation

(2008) Brendan J. Flowers et al.   ADVANCED SYNTHESIS & CATALYSIS

Carboxylation of Organoboronic Esters Catalyzed by N‐Heterocyclic Carbene Copper(I) Complexes

(2008) Takeshi Ohishi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylic Acids as Substrates in Homogeneous Catalysis

(2008) Lukas J. Gooßen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mixed Alkylamido Aluminate as a Kinetically Controlled Base

(2008) Hiroshi Naka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Reductive Carboxylation of Styrenes Using CO2

(2008) Catherine M. Williams et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Beyond Aresta’s Complex: Ni- and Pd-Catalyzed Organozinc Coupling with CO2

(2008) Charles S. Yeung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrocarboxylation of Allenes with CO2Catalyzed by Silyl Pincer-Type Palladium Complex

(2008) Jun Takaya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Carboxylation of Organozinc Reagents with CO2

(2008) Hidenori Ochiai et al.   ORGANIC LETTERS

Copper(I)-Catalyzed Carboxylation of Aryl- and Alkenylboronic Esters

(2008) Jun Takaya et al.   ORGANIC LETTERS

1,3-Dialkylimidazolium-2-carboxylates as versatile N-heterocyclic carbene–CO2 adducts employed in the synthesis of carboxylates and α-alkylidene cyclic carbonates

(2008) Immacolata Tommasi et al.   TETRAHEDRON LETTERS

Direct utilization of carbon dioxide in chemical synthesis: Vinyl acetate via methane carboxylation

(2007) James J. Spivey et al.   CATALYSIS COMMUNICATIONS