期刊
GREEN CHEMISTRY
卷 18, 期 15, 页码 4181-4184出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6gc01346e
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资金
- National Natural Science Foundation of China [21172026]
- Fundamental Research Funds for the Central Universities [DUT15LAB21]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT13008]
Carbon dioxide is a green carboxylative reagent due to its nontoxic and renewable properties. Described herein is a carboxylative cyclization of substituted 1-propenyl ketones via gamma-carboxylation using CO2, which provides an efficient, transition-metal-free and straightforward access to important alpha-pyrone compounds from easily available substrates and CO2.
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