Intramolecularly Stabilized Heavier Tetrylenes: From Monodentate to Bidentate ­Ligands

Chemistry of Stannylene-Based Lewis Pairs: Dynamic Tin Coordination Switching Between Donor and Acceptor Character

(2015) Kilian M. Krebs et al.   CHEMISTRY-A EUROPEAN JOURNAL

The transition-metal chemistry of amidinatosilylenes, -germylenes and -stannylenes

(2015) Lucía Álvarez-Rodríguez et al.   COORDINATION CHEMISTRY REVIEWS

Accessible Syntheses of Late Transition Metal (Pre)Catalysts Bearing N-Heterocyclic Carbene Ligands

(2015) David J. Nelson   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Amidinatogermylene Derivatives of Ruthenium Carbonyl: New Insights into the Reactivity of [Ru3(CO)12] with Two-Electron-Donor Reagents of High Basicity

(2015) Lucía Álvarez-Rodríguez et al.   INORGANIC CHEMISTRY

Reactivity Studies on a Binuclear Ruthenium(0) Complex Equipped with a Bridging κ2N,Ge-Amidinatogermylene Ligand

(2015) Javier A. Cabeza et al.   INORGANIC CHEMISTRY

Synthesis of Mixed Silylene-Carbene Chelate Ligands from N-Heterocyclic Silylcarbenes Mediated by Nickel

(2014) Gengwen Tan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Novel zwitterionic complexes arising from the coordination of an ambiphilic phosphorus–aluminum ligand to gold

(2014) Marc Devillard et al.   CHEMICAL COMMUNICATIONS

Ring Opening and Bidentate Coordination of Amidinate Germylenes and Silylenes on Carbonyl Dicobalt Complexes: The Importance of a Slight Difference in Ligand Volume

(2014) Javier A. Cabeza et al.   CHEMISTRY-A EUROPEAN JOURNAL

Novel Transition-Metal (M=Cr, Mo, W, Fe) Carbonyl Complexes with Bis(guanidinato)silicon(II) Ligands

(2014) Felix M. Mück et al.   CHEMISTRY-A EUROPEAN JOURNAL

Conversion of a Monodentate Amidinate–Germylene Ligand into Chelating Imine–Germanate Ligands (on Mononuclear Manganese Complexes)

(2014) Javier A. Cabeza et al.   INORGANIC CHEMISTRY

Highly Electron-Rich Pincer-Type Iron Complexes Bearing Innocent Bis(metallylene)pyridine Ligands: Syntheses, Structures, and Catalytic Activity

(2014) Daniel Gallego et al.   ORGANOMETALLICS

Steric effects in the reactions of amidinate germylenes with ruthenium carbonyl: isolation of a coordinatively unsaturated diruthenium(0) derivative

(2014) Javier A. Cabeza et al.   RSC Advances

N-heterocyclic silylene complexes in catalysis: new frontiers in an emerging field

(2014) Burgert Blom et al.   Inorganic Chemistry Frontiers

Phosphastannirane: A Phosphorus/Tin(II) Lewis Pair that Undergoes Alkyne and Alkene Addition

(2013) Sarah Freitag et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Application of a Bis(silylene) Nickel Complex as Precatalyst in C–C Bond Formation Reactions

(2013) Chika I. Someya et al.   CHEMISTRY LETTERS

Donor-Stabilized Silylenes with Guanidinato Ligands

(2013) Felix M. Mück et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Five-Coordinate Silicon(II) Compounds with Si–M Bonds (M = Cr, Mo, W, Fe): Bis[N,N′-diisopropylbenzamidinato(−)]silicon(II) as a Ligand in Transition-Metal Complexes

(2013) Konstantin Junold et al.   INORGANIC CHEMISTRY

From Bis(silylene) and Bis(germylene) Pincer-Type Nickel(II) Complexes to Isolable Intermediates of the Nickel-Catalyzed Sonogashira Cross-Coupling Reaction

(2013) Daniel Gallego et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electron-Rich N-Heterocyclic Silylene (NHSi)–Iron Complexes: Synthesis, Structures, and Catalytic Ability of an Isolable Hydridosilylene–Iron Complex

(2013) Burgert Blom et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nature of M–Ge Bonds in the Metallogermylene Complexes of Chromium, Molybdenum, and Tungsten [(η5-C5H5)(CO)3M{GeN(SiMe3)R}] and [(η5-C5H5)(CO)3M{GeN(Ph)R}] (R = Ph, Mesityl (Mes)): A Theoretical Study

(2013) Krishna K. Pandey et al.   ORGANOMETALLICS

Stannylene-Based Lewis Pairs

(2013) Sarah Freitag et al.   ORGANOMETALLICS

Dichlorosilylene: A High Temperature Transient Species to an Indispensable Building Block

(2012) Rajendra S. Ghadwal et al.   ACCOUNTS OF CHEMICAL RESEARCH

Bis[N,N′-diisopropylbenzamidinato(−)]silicon(II): A Silicon(II) Compound with Both a Bidentate and a Monodentate Amidinato Ligand

(2012) Konstantin Junold et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pushing the σ-Donor Strength in Iridium Pincer Complexes: Bis(silylene) and Bis(germylene) Ligands Are Stronger Donors than Bis(phosphorus(III)) Ligands

(2012) Andreas Brück et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bis(silylenyl)- and Bis(germylenyl)-Substituted Ferrocenes: Synthesis, Structure, and Catalytic Applications of Bidentate Silicon(II)-Cobalt Complexes

(2012) Wenyuan Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal Complexes of Tetrylones [(CO)5W-E(PPh3)2] and Tetrylenes [(CO)5W-NHE] (E=C-Pb): A Theoretical Study

(2012) Thi Ai Nhung Nguyen et al.   CHEMISTRY-A EUROPEAN JOURNAL

New Vistas in N-Heterocyclic Silylene (NHSi) Transition-Metal Coordination Chemistry: Syntheses, Structures and Reactivity towards Activation of Small Molecules

(2012) Burgert Blom et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Amidinate-Stabilized Germatrisilacyclobutadiene Ylide

(2012) Hui-Xian Yeong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Facile Access to Transition-Metal-Carbonyl Complexes with an Amidinate-Stabilized Chlorosilylene Ligand

(2012) Ramachandran Azhakar et al.   Chemistry-An Asian Journal

The group 7 metal carbonyl complexes from a stable heteroleptic silylene PhC(NtBu)2SiNPh2

(2012) Ramachandran Azhakar et al.   DALTON TRANSACTIONS

Expanding the coordination chemistry of donor-stabilized group-14 metalenes

(2012) Javier A. Cabeza et al.   DALTON TRANSACTIONS

Diaminogermylene and Diaminostannylene Derivatives of Gold(I): Novel AuM and AuM2 (M = Ge, Sn) Complexes

(2012) Javier A. Cabeza et al.   INORGANIC CHEMISTRY

Synthesis and Characterization of Rhodium Complexes with Phosphine-Stabilized Germylenes

(2012) Juan M. García et al.   INORGANIC CHEMISTRY

Synthesis of Mixed Tin–Ruthenium and Tin–Germanium–Ruthenium Carbonyl Clusters from [Ru3(CO)12] and Diaminometalenes (M = Sn, Ge)

(2012) Javier A. Cabeza et al.   INORGANIC CHEMISTRY

Bis(amidinato)germylenerhodium Complexes: Synthesis, Structure, and Density Functional Theory Calculations

(2012) Dimitri Matioszek et al.   INORGANIC CHEMISTRY

Chemistry of low valent silicon

(2012) Herbert W. Roesky   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Coordination Chemistry of Cyclic Disilylated Stannylenes and Plumbylenes to Group 4 Metallocenes

(2012) Henning Arp et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Geminal Phosphorus/Aluminum-Based Frustrated Lewis Pairs: CH versus CC Activation and CO2Fixation

(2011) Christian Appelt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthetic Routes to N-Heterocyclic Carbene Precursors

(2011) Laure Benhamou et al.   CHEMICAL REVIEWS

The N-heterocyclic carbene chemistry of transition-metal carbonyl clusters

(2011) Javier A. Cabeza et al.   CHEMICAL SOCIETY REVIEWS

Syntheses of Group 7 Metal Carbonyl Complexes with a Stable N-Heterocyclic Chlorosilylene

(2011) Ramachandran Azhakar et al.   INORGANIC CHEMISTRY

Tetrylenes Chelated by Hybrid Amido–Amino Ligand: Derivatives of 2-[(N,N-Dimethylamino)methyl]aniline

(2011) Hana Vaňkátová et al.   INORGANIC CHEMISTRY

Synthesis and Reactivity of a Phosphine-Stabilized Monogermanium Analogue of Alkynes

(2011) Juliette Berthe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules

(2011) Shenglai Yao et al.   ORGANOMETALLICS

Synthesis, Characterization, and CO Elimination of Ferrio-Substituted Two-Coordinate Germylenes and Stannylenes

(2011) Hao Lei et al.   ORGANOMETALLICS

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An isolable dialkylsilylene and its derivatives. A step toward comprehension of heavy unsaturated bonds

(2010) Mitsuo Kira   CHEMICAL COMMUNICATIONS

Interstellar molecules: guides for new chemistry

(2010) Swadhin K. Mandal et al.   CHEMICAL COMMUNICATIONS

σ-Acceptor, Z-type ligands for transition metals

(2010) Abderrahmane Amgoune et al.   CHEMICAL COMMUNICATIONS

N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands†

(2010) Matthew Asay et al.   CHEMICAL REVIEWS

Transition metals as Lewis bases: “Z-type” boron ligands and metal-to-boron dative bonding

(2010) Holger Braunschweig et al.   DALTON TRANSACTIONS

Synthesis of Monomeric Divalent Tin(II) Compounds with Terminal Chloride, Amide, and Triflate Substituents

(2010) Sakya S. Sen et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Routes to Ruthenium-Fluoro Cations of the Type [RuL2(CO)nF]+ (n = 2,3; L = PR3, NHC): A Play-Off between Solvent, L and Weakly Coordinating Anion

(2010) Karl S. Coleman et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Rhodium−Germanium Carbonyl Complexes

(2010) Richard D. Adams et al.   INORGANIC CHEMISTRY

Iridium−Germanium and −Tin Carbonyl Complexes

(2010) Richard D. Adams et al.   ORGANOMETALLICS

Halogermanium(II) Complexes Having Phenylamidinate As Supporting Ligands: Syntheses, Characterizations, and Reactivities

(2010) Dimitri Matioszek et al.   ORGANOMETALLICS

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Complexes with Poly(N-heterocyclic carbene) Ligands: Structural Features and Catalytic Applications

(2009) Macarena Poyatos et al.   CHEMICAL REVIEWS

N-Heterocyclic Carbenes in Late Transition Metal Catalysis

(2009) Silvia Díez-González et al.   CHEMICAL REVIEWS

Beyond ConventionalN-Heterocyclic Carbenes: Abnormal, Remote, and Other Classes of NHC Ligands with Reduced Heteroatom Stabilization

(2009) Oliver Schuster et al.   CHEMICAL REVIEWS

A Base-Stabilized Silylene with a Tricoordinate Silicon Atom as a Ligand for a Metal Complex

(2009) Wei Yang et al.   INORGANIC CHEMISTRY

Dynamic Behavior of Intramolecularly Base-Stabilized Phosphatetrylenes. Insights into the Inversion Processes of Trigonal Pyramidal Geramanium(II) and Tin(II) Centers

(2009) Keith Izod et al.   ORGANOMETALLICS

Isolable Metallo-Germylene and Metallo-Stannylene σ-Complexes with Iron

(2009) Shigeyoshi Inoue et al.   ORGANOMETALLICS

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

(2008) F. Ekkehardt Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis, characterisation and reactivity of germanium(ii) amidinate and guanidinate complexes

(2008) Cameron Jones et al.   DALTON TRANSACTIONS

Mono- and Bidentate Benzannulated N-Heterocyclic Germylenes, Stannylenes and Plumbylenes

(2008) Alexander V. Zabula et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Alkene Hydrosilation by a Cationic Hydrogen-Substituted Iridium Silylene Complex

(2008) Elisa Calimano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Homoleptic Complexes of Bisstannylenes with Nickel(0): Synthesis, X-Ray Diffraction Studies, and119Sn NMR Investigations

(2008) Alexander V. Zabula et al.   ORGANOMETALLICS

The Chemistry of Aluminum(I), Silicon(II), and Germanium(II)

(2008) Selvarajan Nagendran et al.   ORGANOMETALLICS

The Synthesis of (η3-C3H5)Pd{Si[N(tBu)CH]2}Cl and the Catalytic Property for Heck Reaction

(2008) Ming Zhang et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE