Transition metals as Lewis bases: “Z-type” boron ligands and metal-to-boron dative bonding

Electron-Precise Coordination Modes of Boron-Centered Ligands

(2010) Holger Braunschweig et al.   CHEMICAL REVIEWS

Neutral and Anionic Transition-Metal-Base-Stabilized Metalloborylene Complexes

(2010) Holger Braunschweig et al.   CHEMISTRY-A EUROPEAN JOURNAL

Late-Transition-Metal Complexes as Tunable Lewis Bases

(2010) Jürgen Bauer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ni→B Interactions in Nickel Phosphino-Alkynyl-Borane Complexes

(2010) Xiaoxi Zhao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Fluxional rhodium scorpionate complexes of the hydrotris(methimazolyl)borate (Tm) ligand and their static boratrane derivatives

(2010) María J. López-Gómez et al.   DALTON TRANSACTIONS

Complexes with Dative Bonds between d- and s-Block Metals: Synthesis and Structure of [(Cy3P)2PtBe(Cl)X] (X=Cl, Me)

(2009) Holger Braunschweig et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A new family of metallaboratrane complexes based on 7-azaindole: B–H activation mediated by carbon monoxide

(2009) Nikolaos Tsoureas et al.   CHEMICAL COMMUNICATIONS

Transition metal borylene complexes: boron analogues of classical organometallic systems

(2009) Dragoslav Vidovic et al.   CHEMICAL COMMUNICATIONS

An early–late heterobimetallic complex with an unsupported dative bond: synthesis and structure of [(Cy3P)2Pt–ZrCl4]

(2009) Holger Braunschweig et al.   CHEMICAL COMMUNICATIONS

Unexpected pincer-type coordination (κ3-SBS) within a zerovalent platinum metallaboratrane complex

(2009) Gareth R. Owen et al.   DALTON TRANSACTIONS

Copper(I) Complexes derived from Mono- and Diphosphino-Boranes: Cu→B Interactions Supported by Arene Coordination

(2009) M. Sircoglou et al.   INORGANIC CHEMISTRY

Chemical Bonding in Transition Metal Complexes with Beryllium Ligands [(PMe3)2M−BeCl2], [(PMe3)2M−BeClMe], and [(PMe3)2M−BeMe2] (M = Ni, Pd, Pt)†

(2009) Pattiyil Parameswaran et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Further Exploring the “Sting of the Scorpion”: Hydride Migration and Subsequent Rearrangement of Norbornadiene to Nortricyclyl on Rhodium(I)

(2009) Nikolaos Tsoureas et al.   ORGANOMETALLICS

Metallaboratranes: Bis- and Tris(methimazolyl)borane Complexes of Group 9 Metal Carbonyls and Thiocarbonyls

(2009) Ian R. Crossley et al.   ORGANOMETALLICS

Metallaboratranes Derived from a Triphosphanyl–Borane: IntrinsicC3 Symmetry Supported by a Z-Type Ligand

(2008) Sébastien Bontemps et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactivity of the Ni→B dative σ-bond in the nickel boratrane compounds [κ4-B(mimBut)3]NiX (X = Cl, OAc, NCS, N3): synthesis of a series of B-functionalized tris(2-mercapto-1-tert-butylimidazolyl)borato complexes, [YTmBut]NiZ

(2008) Keliang Pang et al.   CHEMICAL COMMUNICATIONS

Reactivity of Pt0Complexes toward Gallium(III) Halides: Synthesis of a Platinum Gallane Complex and Oxidative Addition of Gallium Halides to Pt0

(2008) Holger Braunschweig et al.   INORGANIC CHEMISTRY

Group 10 and 11 Metal Boratranes (Ni, Pd, Pt, CuCl, AgCl, AuCl, and Au+) Derived from a Triphosphine−Borane

(2008) Marie Sircoglou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of the Ruthenaboratranes [Ru(CS)(PPh3){B(mt)3}](Ru→B)8and [Ru(CO)(CNR){B(mt)3}](Ru→B)8(mt = methimazolyl, R =tBu, C6H3Me2-2,6, C6H2Me3-2,4,6)

(2008) Ian R. Crossley et al.   ORGANOMETALLICS

Borylene Transfer from Transition Metal Borylene Complexes

(2008) Carly E. Anderson et al.   ORGANOMETALLICS

Retention of Pt→B Bonding in Oxidative Addition Reactions of the Platinaboratrane [Pt(PPh3){B(mt)3}](Pt→B)10(mt = Methimazolyl)

(2008) Ian R. Crossley et al.   ORGANOMETALLICS

Dimanganese Bridging Borylene Complexes and their Reactions with Unsaturated Palladium(0) Complexes - Syntheses, Structures and Calculated Properties

(2008) Holger Braunschweig et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Ambiphilic Diphosphine–Borane Ligands: Metal→Borane Interactions within Isoelectronic Complexes of Rhodium, Platinum and Palladium

(2007) Sébastien Bontemps et al.   CHEMISTRY-A EUROPEAN JOURNAL

Unlocking the metallaboratrane cage: reversible B–H activation in platinaboratranes

(2007) Ian R. Crossley et al.   DALTON TRANSACTIONS