Enantioselective fluorination of α-branched aldehydes and subsequent conversion to α-hydroxyacetals via stereospecific C–F bond cleavage

Williamson Ether Synthesis with Phenols at a Tertiary Stereogenic Carbon: Formal Enantioselective Phenoxylation of β-Keto Esters

(2015) Kazutaka Shibatomi et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Simple Primary Amine Catalyst for Enantioselective α-Hydroxylations and α-Fluorinations of Branched Aldehydes

(2015) Michael R. Witten et al.   ORGANIC LETTERS

Organocatalytic asymmetric fluorination of α-chloroaldehydes involving kinetic resolution

(2014) Kazutaka Shibatomi et al.   Beilstein Journal of Organic Chemistry

Functionalization of Fluorinated Molecules by Transition-Metal-Mediated C–F Bond Activation To Access Fluorinated Building Blocks

(2014) Theresia Ahrens et al.   CHEMICAL REVIEWS

Recent Progress in Asymmetric Fluorination and Trifluoromethylation Reactions

(2014) Vincent Bizet et al.   CURRENT TOPICS IN MEDICINAL CHEMISTRY

Enantioselective Nucleophile-Catalyzed Synthesis of Tertiary Alkyl Fluorides via the α-Fluorination of Ketenes: Synthetic and Mechanistic Studies

(2014) Sarah Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Fluorination of α-Branched Cyclohexanones Enabled by a Combination of Chiral Anion Phase-Transfer Catalysis and Enamine Catalysis using Protected Amino Acids

(2014) Xiaoyu Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Synthesis of Tertiary Alkyl Fluorides: Negishi Cross-Couplings of Racemic α,α-Dihaloketones

(2014) Yufan Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective CF Bond Activation: Substitution of Unactivated Alkyl Fluorides using YbI3

(2013) Annika M. Träff et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Fluoroamination: 1,4-Addition to Conjugated Dienes Using Anionic Phase-Transfer Catalysis

(2013) Hunter P. Shunatona et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Anion Phase-Transfer Catalysis Applied to the Direct Enantioselective Fluorinative Dearomatization of Phenols

(2013) Robert J. Phipps et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enabling Nucleophilic Substitution Reactions of Activated Alkyl Fluorides through Hydrogen Bonding

(2013) Pier Alexandre Champagne et al.   ORGANIC LETTERS

A combination of directing groups and chiral anion phase-transfer catalysis for enantioselective fluorination of alkenes

(2013) Jeffrey Wu et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

β-tert-Butyl aspartate as an organocatalyst for the asymmetric α-amination of α,α-disubstituted aldehydes

(2013) Alexis Theodorou et al.   TETRAHEDRON

Highly Enantioselective Chlorination of β-Keto Esters and Subsequent SN2 Displacement of Tertiary Chlorides: A Flexible Method for the Construction of Quaternary Stereogenic Centers

(2012) Kazutaka Shibatomi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Fluorination of Enamides: Access to α-Fluoroimines Using an Anionic Chiral Phase-Transfer Catalyst

(2012) Robert J. Phipps et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic asymmetric α-benzoyloxylation of α-branched aldehydes and enals: a useful approach to oxygenated quaternary stereocenters

(2012) Nicolas Demoulin et al.   TETRAHEDRON

Direct Asymmetric α Benzoyloxylation of Cyclic Ketones

(2011) Olga Lifchits et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Inhibition of Amyloidogenesis by Nonsteroidal Anti-inflammatory Drugs and Their Hybrid Nitrates

(2011) Isaac T. Schiefer et al.   JOURNAL OF MEDICINAL CHEMISTRY

Enantioselectivegem-Chlorofluorination of Active Methylene Compounds Using a Chiral Spiro Oxazoline Ligand

(2011) Kazutaka Shibatomi et al.   ORGANIC LETTERS

Primary Amine/CSA Ion Pair: A Powerful Catalytic System for the Asymmetric Enamine Catalysis

(2011) Chen Liu et al.   ORGANIC LETTERS

Primary amine catalyzed electrophilic amination of α,α-disubstituted aldehydes

(2011) Alaric Desmarchelier et al.   TETRAHEDRON LETTERS

C−F Bond Activation in Organic Synthesis

(2009) Hideki Amii et al.   CHEMICAL REVIEWS

C−F Bond Cleavage by Intramolecular SN2 Reaction of Alkyl Fluorides with O- and N-Nucleophiles

(2009) Laijun Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Development of a New Chiral Spiro Oxazolinylpyridine Ligand (Spymox) for Asymmetric Catalysis

(2009) Kazutaka Shibatomi et al.   SYNLETT

Stereoselective Synthesis of α,α‐Chlorofluoro Carbonyl Compounds Leading to the Construction of Fluorinated Chiral Quaternary Carbon Centers

(2008) Kazutaka Shibatomi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION