Advancements in the Synthesis and Applications of CationicN-Heterocycles through Transition Metal-Catalyzed C−H Activation

Bidentate, Monoanionic Auxiliary-Directed Functionalization of Carbon–Hydrogen Bonds

(2015) Olafs Daugulis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes

(2015) Guoyong Song et al.   ACCOUNTS OF CHEMICAL RESEARCH

Chiral Cyclopentadienyls: Enabling Ligands for Asymmetric Rh(III)-Catalyzed C–H Functionalizations

(2015) Baihua Ye et al.   ACCOUNTS OF CHEMICAL RESEARCH

Transition-Metal-Catalyzed C–N Bond Forming Reactions Using Organic Azides as the Nitrogen Source: A Journey for the Mild and Versatile C–H Amination

(2015) Kwangmin Shin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Recent Advances in Transition Metal-Catalyzed Methylation Reactions

(2015) Guobing Yan et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthesis of Heterocycle-fused PyridineN-Oxides from Oximes and Diazo CompoundsviaRhIII-Catalyzed CH Activation and Annulation

(2015) Peng Sun et al.   ADVANCED SYNTHESIS & CATALYSIS

Construction of N-containing heterocycles via oxidative intramolecular N–H/X–H coupling

(2015) Jiwen Yuan et al.   CHEMICAL COMMUNICATIONS

Catalytic Silylation of Unactivated C–H Bonds

(2015) Chen Cheng et al.   CHEMICAL REVIEWS

Transition-Metal-Catalyzed Direct Addition of Unactivated C–H Bonds to Polar Unsaturated Bonds

(2015) Lei Yang et al.   CHEMICAL REVIEWS

Recent advances in C–S bond formation via C–H bond functionalization and decarboxylation

(2015) Chao Shen et al.   CHEMICAL SOCIETY REVIEWS

Transition-Metal-Catalyzed π-Bond-Assisted CH Bond Functionalization: An Emerging Trend in Organic Synthesis

(2015) Parthasarathy Gandeepan et al.   Chemistry-An Asian Journal

Rh(III)-Catalyzed Oxidative Annulation of 2-Phenylimidazo[1,2-a]pyridines with Alkynes: Mono versus Double C–H Activation

(2015) Zisong Qi et al.   JOURNAL OF ORGANIC CHEMISTRY

Experimental and DFT Studies Explain Solvent Control of C–H Activation and Product Selectivity in the Rh(III)-Catalyzed Formation of Neutral and Cationic Heterocycles

(2015) David L. Davies et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(iii)-catalyzed cascade oxidative annulation reactions of aryl imidazolium salts with alkynes involving multiple C–H bond activation

(2015) Qingmei Ge et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Efficient Approach to Mesoionic Triazolo[5,1-a]isoquinolium through Rhodium-Catalyzed Annulation of Triazoles and Internal Alkynes

(2015) Shixian Zhao et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Vinylic C–H Activation: A Direct Route toward Pyridinium Salts

(2015) Ching-Zong Luo et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Activation and Functionalization of Pyridine C–H Bond by Exploring a Unique Double Role of “N-Heterocyclic Carbene–Pyridyl” Ligand Platform

(2015) Ranjeesh Thenarukandiyil et al.   ORGANOMETALLICS

Transition-metal-catalyzed etherification of unactivated CH bonds

(2015) Bin Liu et al.   TETRAHEDRON LETTERS

Recent Advances on Ester Synthesis via Transition-Metal Catalyzed C–H Functionalization

(2015) Bin Liu et al.   ACS Catalysis

Rhodium(III)–N-Heterocyclic Carbene-Driven Cascade C–H Activation Catalysis

(2015) Debasish Ghorai et al.   ACS Catalysis

Cooperative C(sp3)–H and C(sp2)–H Activation of 2-Ethylpyridines by Copper and Rhodium: A Route toward Quinolizinium Salts

(2015) Ching-Zong Luo et al.   ACS Catalysis

Formal SN-Type Reactions in Rhodium(III)-Catalyzed CH Bond Activation

(2014) Nadine Kuhl et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthesis of Extended π-Systems through C-H Activation

(2014) Yasutomo Segawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rh(iii)-catalyzed synthesis of 1-substituted isoquinolinium salts via a C–H bond activation reaction of ketimines with alkynes

(2014) Natarajan Senthilkumar et al.   CHEMICAL COMMUNICATIONS

Exploring a unique reactivity of N-heterocyclic carbenes (NHC) in rhodium(iii)-catalyzed intermolecular C–H activation/annulation

(2014) Debasish Ghorai et al.   CHEMICAL COMMUNICATIONS

C–H Functionalization in the Synthesis of Amino Acids and Peptides

(2014) Anaïs F. M. Noisier et al.   CHEMICAL REVIEWS

Functional group directed C–H borylation

(2014) A. Ros et al.   CHEMICAL SOCIETY REVIEWS

Convergent Synthesis of Diverse Tetrahydropyridines via Rh(I)-Catalyzed C–H Functionalization Sequences

(2014) Tehetena Mesganaw et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Synthesis and Alkyne Insertion Reactions of NHC-Based Cyclometalated Ruthenium(II) Complexes

(2014) Chong Ma et al.   ORGANOMETALLICS

Chelation-Assisted Regioselective Catalytic Functionalization of C–H, C–O, C–N and C–F Bonds

(2014) Fumitoshi Kakiuchi et al.   SYNLETT

Transition metal-catalyzed direct nucleophilic addition of C–H bonds to carbon–heteroatom double bonds

(2014) Xi-Sha Zhang et al.   Chemical Science

A convenient synthesis of quinolizinium salts through Rh(iii) or Ru(ii)-catalyzed C–H bond activation of 2-alkenylpyridines

(2013) Ching-Zong Luo et al.   CHEMICAL COMMUNICATIONS

C–H nitrogenation and oxygenation by ruthenium catalysis

(2013) Vedhagiri S. Thirunavukkarasu et al.   CHEMICAL COMMUNICATIONS

Oxidative C–H amination reactions

(2013) Marie-Laure Louillat et al.   CHEMICAL SOCIETY REVIEWS

A General Method to Diverse Cinnolines and Cinnolinium Salts

(2013) Dongbing Zhao et al.   CHEMISTRY-A EUROPEAN JOURNAL

RhIII-Catalyzed CH Activation: A Versatile Route towards Various Polycyclic Pyridinium Salts

(2013) Ching-Zong Luo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(III)-Catalyzed Synthesis of Cinnolinium Salts from Azobenzenes and Alkynes: Application to the Synthesis of Indoles and Cinnolines

(2013) Krishnamoorthy Muralirajan et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Efficient Rh/O2 Catalytic System for Oxidative C–H Activation/Annulation: Evidence for Rh(I) to Rh(III) Oxidation by Molecular Oxygen

(2013) Guoying Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Synthesis of Multisubstituted Isoquinoline and Pyridine N-Oxides from Oximes and Diazo Compounds

(2013) Zhuangzhi Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed CH Functionalization

(2013) Naohiko Yoshikai et al.   Asian Journal of Organic Chemistry

Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

(2012) Nadine Kuhl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nukuhivensiums, Indolo[2,3-a]quinoliziniums from the Marquesan Plant Rauvolfia nukuhivensis

(2012) Nicolas Martin et al.   MOLECULES

Ru(II)-Catalyzed C–H Bond Activation for the Synthesis of Substituted Isoquinolinium Salts from Benzaldehydes, Amines, and Alkynes

(2012) Kanniyappan Parthasarathy et al.   ORGANIC LETTERS

One-Pot Synthesis of Isoquinolinium Salts by Rhodium-Catalyzed CH Bond Activation: Application to the Total Synthesis of Oxychelerythrine

(2011) Jayachandran Jayakumar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-catalyzed Cycloaddition of Aromatic (O-Benzyl)ketoximes with Alkynes to Produce Isoquinoline and IsoquinolineN-Oxide Derivatives

(2011) Yuji Yoshida et al.   CHEMISTRY LETTERS

Nickel-Catalyzed Cyclization of ortho-Iodoketoximes and ortho-Iodoketimines with Alkynes: Synthesis of Highly Substituted Isoquinolines and Isoquinolinium Salts

(2011) Wei-Chun Shih et al.   Chemistry-An Asian Journal

Aerobic Pd-Catalyzed sp3C−H Olefination: A Route to Both N-Heterocyclic Scaffolds and Alkenes

(2011) Kara J. Stowers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dyes, trypanosomiasis and DNA: a historical and critical review

(2010) M Wainwright   BIOTECHNIC & HISTOCHEMISTRY

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Discovery and SAR of cinnolines/quinolines as liver X receptor (LXR) agonists with binding selectivity for LXRβ

(2009) Baihua Hu et al.   BIOORGANIC & MEDICINAL CHEMISTRY

Dehydrogenation as a Substrate-Activating Strategy in Homogeneous Transition-Metal Catalysis

(2009) Graham E. Dobereiner et al.   CHEMICAL REVIEWS

Isoquinolinium Salts fromo-Halobenzaldehydes, Amines, and Alkynes Catalyzed by Nickel Complexes: Synthesis and Applications

(2009) Rajendra Prasad Korivi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Protecting-Group-Free Total Synthesis of Isoquinoline Alkaloids by Nickel-Catalyzed Annulation ofo-Halobenzaldimine with an Alkyne as the Key Step

(2009) Rajendra Prasad Korivi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Molecular recognition of a DNA:RNA hybrid: Sub-nanomolar binding by a neomycin–methidium conjugate

(2008) Nicholas N. Shaw et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Bioactive Pyridine-N-oxide Disulfides fromAllium stipitatum¶

(2008) Gemma O’Donnell et al.   JOURNAL OF NATURAL PRODUCTS

An Efficient Low-Temperature Route to Polycyclic Isoquinoline Salt Synthesis via C−H Activation with [Cp*MCl2]2(M = Rh, Ir)

(2008) Ling Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY