A Comparison of the Stability and Reactivity of Diamido- and Diaminocarbene Copper Alkoxide and Hydride Complexes

Ammonia Activation by a Nickel NCN-Pincer Complex featuring a Non-Innocent N-Heterocyclic Carbene: Ammine and Amido Complexes in Equilibrium

(2015) Rudy M. Brown et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

“Decarbonization” of an imino-N-heterocyclic carbene ligand via triple benzyl migration from hafnium

(2015) Dipesh Prema et al.   CHEMICAL COMMUNICATIONS

Unexpected Migratory Insertion Reactions of M(alkyl)2(M=Zn, Cd) and Diamidocarbenes

(2015) Lee R. Collins et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper–NHC complexes in catalysis

(2015) Faïma Lazreg et al.   COORDINATION CHEMISTRY REVIEWS

Effects of the electronic structure of five-membered N-heterocyclic carbenes on insertion of silanes and boranes into the NHC C–N bond

(2015) Kalon J. Iversen et al.   DALTON TRANSACTIONS

Determining the Ligand Properties of N-Heterocyclic Carbenes from77Se NMR Parameters

(2015) Kathrin Verlinden et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Activation of N-Heterocyclic Carbenes by {BeH2} and {Be(H)(Me)} Fragments

(2015) Merle Arrowsmith et al.   ORGANOMETALLICS

What can NMR spectroscopy of selenoureas and phosphinidenes teach us about the π-accepting abilities of N-heterocyclic carbenes?

(2015) Sai V. C. Vummaleti et al.   Chemical Science

Intramolecular CN Bond Activation and Ring-Expansion Reactions of N-Heterocyclic Carbenes

(2014) Patrick Hemberger et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carbene-9-BBN Ring Expansions as a Route to Intramolecular Frustrated Lewis Pairs for CO2Reduction

(2014) Tongen Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Expanded-Ring N-Heterocyclic Carbenes for the Stabilization of Highly Electrophilic Gold(I) Cations

(2014) Nicholas Phillips et al.   CHEMISTRY-A EUROPEAN JOURNAL

Systematic Investigation of the Ring-Expansion Reaction of N-Heterocyclic Carbenes with an Iminoborane Dihydride

(2014) Daniel Franz et al.   Chemistry-An Asian Journal

Recent Advances in Carbon Dioxide Capture, Fixation, and Activation by using N-Heterocyclic Carbenes

(2014) Longhua Yang et al.   ChemSusChem

Activation of the C–N bond of N-heterocyclic carbenes by inorganic elements

(2014) Kalon J. Iversen et al.   DALTON TRANSACTIONS

Copper Diamidocarbene Complexes: Characterization of Monomeric to Tetrameric Species

(2014) Lee R. Collins et al.   INORGANIC CHEMISTRY

Stereoelectronic Effects in C–H Bond Oxidation Reactions of Ni(I) N-Heterocyclic Carbene Complexes

(2014) Rebecca C. Poulten et al.   INORGANIC CHEMISTRY

Exploring the Chemistry of N,N′-Diamidocarbenes with Organophosphorus Compounds

(2014) Daniel T. Chase et al.   ORGANIC LETTERS

A New Type of Palladium-Pincer Complexes Generated via Hydrolytic Ring-Opening of Imidazole-2-ylidenes

(2014) Suraj K. Gupta et al.   ORGANOMETALLICS

Use of Ring-Expanded Diamino- and Diamidocarbene Ligands in Copper Catalyzed Azide–Alkyne “Click” Reactions

(2014) Lee R. Collins et al.   ORGANOMETALLICS

Copper-catalyzed Z-selective semihydrogenation of alkynes with hydrosilane: a convenient approach to cis-alkenes

(2014) Guang-Hui Wang et al.   TETRAHEDRON

NHC–copper hydrides as chemoselective reducing agents: catalytic reduction of alkynes, alkyl triflates, and alkyl halides

(2014) Nick Cox et al.   TETRAHEDRON

Imidazolinium salts derived from amino[2.2]paracyclophane compounds: synthesis and hydrolytic ring-opening

(2014) Kerry-Ann Green et al.   TETRAHEDRON LETTERS

An Abnormal N-Heterocyclic Carbene-Copper(I) Complex in Click Chemistry

(2013) Samaresh Chandra Sau et al.   ADVANCED SYNTHESIS & CATALYSIS

Isolation of a Neutral P8Cluster by [2+2] Cycloaddition of a Diphosphene Facilitated by Carbene Activation of White Phosphorus

(2013) Christopher L. Dorsey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

31P NMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the π-Accepting Properties of Carbenes

(2013) Olivier Back et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Insights into the Reduction of Carbon Dioxide with Silanes over N-Heterocyclic Carbene Catalysts

(2013) Siti Nurhanna Riduan et al.   ChemCatChem

Heterocoupling of 2-naphthols enabled by a copper–N-heterocyclic carbene complex

(2013) Michael Holtz-Mulholland et al.   CHEMICAL COMMUNICATIONS

Highly efficient catalytic hydrosilylation of carbon dioxide by an N-heterocyclic carbene copper catalyst

(2013) Liang Zhang et al.   CHEMICAL COMMUNICATIONS

Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P4 cage and P8 clusters

(2013) Caleb D. Martin et al.   CHEMICAL COMMUNICATIONS

From Diphosphino-Functionalized 1,3-Dialkylimidazolium Cations to Imidazolones through Dehydrogenative CN Coupling

(2013) Javier Ruiz et al.   CHEMISTRY-A EUROPEAN JOURNAL

N,N′-Diamidocarbenes Facilitate Selective CH Insertions and Transfer Hydrogenations

(2013) Jonathan P. Moerdyk et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Ambivalent Chemistry of a Free Anionic N-Heterocyclic Carbene Decorated with a Malonate Backbone: The Plus of a Negative Charge

(2013) Vincent César et al.   CHEMISTRY-A EUROPEAN JOURNAL

Three-Coordinate Nickel(I) Complexes Stabilised by Six-, Seven- and Eight-Membered Ring N-Heterocyclic Carbenes: Synthesis, EPR/DFT Studies and Catalytic Activity

(2013) Michael J. Page et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stoichiometric sensitivity and structural diversity in click-active copper(i) N,S-heterocyclic carbene complexes

(2013) Xiaoyan Han et al.   DALTON TRANSACTIONS

Activating Azides and Alkynes for the Click Reaction with [Cu(aNHC)2I] or [Cu(aNHC)2]+(aNHC = Triazole-Derived Abnormal Carbenes): Structural Characterization and Catalytic Properties

(2013) Stephan Hohloch et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

1,6-Enyne Cyclizations Catalyzed by N-Heterocyclic Carbene Supported Gold Complexes: Deconvoluting Sterics and Electronics

(2013) Kuppuswamy Arumugam et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Elucidation of Carbene Ambiphilicity Leading to the Discovery of Reversible Ammonia Activation

(2013) Jonathan P. Moerdyk et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Electronic Structure, and Magnetism of [Ni(6-Mes)2]+: A Two-Coordinate Nickel(I) Complex Stabilized by Bulky N-Heterocyclic Carbenes

(2013) Rebecca C. Poulten et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Monophasic Catalytic System for the Selective Semireduction of Alkynes

(2013) Aaron M Whittaker et al.   ORGANIC LETTERS

Ligand Properties of Boron-Substituted Five-, Six-, and Seven-Membered Heterocyclic Carbenes: A Theoretical Study

(2013) Ashwini K. Phukan et al.   ORGANOMETALLICS

Copper(I) Heteroleptic Bis(NHC) and Mixed NHC/Phosphine Complexes: Syntheses and Catalytic Activities in the One-Pot Sequential CuAAC Reaction of Aromatic Amines

(2013) Shuai Guo et al.   ORGANOMETALLICS

Copper-Catalyzed Hydroboration of Carbon Dioxide

(2013) Ryo Shintani et al.   ORGANOMETALLICS

Comparison of the Mechanism of Borane, Silane, and Beryllium Hydride Ring Insertion into N-Heterocyclic Carbene C–N Bonds: A Computational Study

(2013) Kalon J. Iversen et al.   ORGANOMETALLICS

Are Cu(I)-mesoionic NHC carbenes associated with nitrogen additives the best Cu-carbene catalysts for the azide–alkyne click reaction in solution? A case study

(2013) Stephan Hohloch et al.   TETRAHEDRON LETTERS

N-heterocyclic carbene copper(I) complex-catalyzed direct C–H thiolation of benzothiazoles

(2013) Hiroshi Inomata et al.   TETRAHEDRON LETTERS

N-Heterocyclic carbene (NHC)–copper-catalysed transformations of carbon dioxide

(2013) Liang Zhang et al.   Chemical Science

Copper N-heterocyclic carbene complexes in catalysis

(2013) Jonathan D. Egbert et al.   Catalysis Science & Technology

Highly Active Dinuclear Copper Catalysts for Homogeneous Azide-Alkyne Cycloadditions

(2012) Regina Berg et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-Catalyzed Highly Selective Semihydrogenation of Non-Polar Carbon-Carbon Multiple Bonds using a Silane and an Alcohol

(2012) Kazuhiko Semba et al.   ADVANCED SYNTHESIS & CATALYSIS

Unconventional Reactivity of Imidazolylidene Pyridylidene Ligands in Iridium(III) and Rhodium(III) Complexes

(2012) Candela Segarra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CN Bond Cleavage and Ring Expansion of N-Heterocyclic Carbenes using Hydrosilanes

(2012) David Schmidt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beryllium-Induced CN Bond Activation and Ring Opening of an N-Heterocyclic Carbene

(2012) Merle Arrowsmith et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Preparation of Stable Low-Oxidation-State Group 14 Element Amidohydrides and Hydride-Mediated Ring-Expansion Chemistry of N-Heterocyclic Carbenes

(2012) S. M. Ibrahim Al-Rafia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Developments of Expanded Ring N-Heterocyclic Carbenes

(2012) Jie Li et al.   CURRENT ORGANIC CHEMISTRY

Formation of stable iron/cobalt NHC complexes via unexpected ring opening and in situ generation of a tridentate ligand

(2012) Gao-Feng Wang et al.   DALTON TRANSACTIONS

N-alkyl functionalised expanded ring N-heterocyclic carbene complexes of rhodium(i) and iridium(i): structural investigations and preliminary catalytic evaluation

(2012) Jay J. Dunsford et al.   DALTON TRANSACTIONS

Reactivity of a cationic N-heterocyclic carbene and its corresponding dicationic precursor

(2012) Björn Hildebrandt et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Alkyne and Reversible Nitrile Activation: N,N′-Diamidocarbene-Facilitated Synthesis of Cyclopropenes, Cyclopropenones, and Azirines

(2012) Jonathan P. Moerdyk et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Boracarboxylation of Alkynes with Diborane and Carbon Dioxide by an N-Heterocyclic Carbene Copper Catalyst

(2012) Liang Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diamidocarbenes as versatile and reversible [2 + 1] cycloaddition reagents

(2012) Jonathan P. Moerdyk et al.   Nature Chemistry

Sterically Encumbered Iridium Bis(N-heterocyclic carbene) Complexes: Air-Stable 14-Electron Cations and Facile Degenerate C–H Activation

(2012) Nicholas Phillips et al.   ORGANOMETALLICS

Dihydroperimidine-Derived N-Heterocyclic Pincer Carbene Complexes via Double C–H Activation

(2012) Anthony F. Hill et al.   ORGANOMETALLICS

Mesitylcopper – A Powerful Tool in Synthetic Chemistry

(2012) Michael Stollenz et al.   ORGANOMETALLICS

Heteroleptic Bis(N-heterocyclic carbene)Copper(I) Complexes: Highly Efficient Systems for the [3+2] Cycloaddition of Azides and Alkynes

(2012) Faïma Lazreg et al.   ORGANOMETALLICS

Gold(I) Complexes Bearing Sterically Imposing, Saturated Six- and Seven-Membered Expanded Ring N-Heterocyclic Carbene Ligands

(2012) Jay J. Dunsford et al.   ORGANOMETALLICS

Ring-Expanded N-Heterocyclic Carbene Complexes of Rhodium with Bifluoride, Fluoride, and Fluoroaryl Ligands

(2012) Candela Segarra et al.   ORGANOMETALLICS

Oxygen-Bound Trifluoromethoxide Complexes of Copper and Gold

(2012) Cheng-Pan Zhang et al.   ORGANOMETALLICS

Carboxylation of Alkylboranes by N-Heterocyclic Carbene Copper Catalysts: Synthesis of Carboxylic Acids from Terminal Alkenes and Carbon Dioxide

(2011) Takeshi Ohishi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unprecedented Copper(I) Bifluoride Complexes: Synthesis, Characterization and Reactivity

(2011) Thomas Vergote et al.   CHEMISTRY-A EUROPEAN JOURNAL

Dual reactivity of N-heterocyclic carbenes towards copper(ii) salts

(2011) Eugene L. Kolychev et al.   DALTON TRANSACTIONS

Stepwise synthesis of a hydrido, N-heterocyclic dicarbene iridium(iii) pincer complex featuring mixed NHC/abnormal NHC ligands

(2011) Weiwei Zuo et al.   DALTON TRANSACTIONS

Copper(I) Complexes of Normal and Abnormal Carbenes and Their Use as Catalysts for the Huisgen [3+2] Cycloaddition between Azides and Alkynes

(2011) Stephan Hohloch et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Copper(I) 1,2,3-Triazol-5-ylidene Complexes as Efficient Catalysts for Click Reactions of Azides with Alkynes

(2011) Tatsuhito Nakamura et al.   ORGANIC LETTERS

Olefin Metathesis Catalysts ContainingN,N′-Diamidocarbenes

(2011) Jonathan P. Moerdyk et al.   ORGANOMETALLICS

First Examples of Structurally Imposing Eight-Membered-Ring (Diazocanylidene) N-Heterocyclic Carbenes: Salts, Free Carbenes, and Metal Complexes

(2011) Wei Y. Lu et al.   ORGANOMETALLICS

DFT Studies on the Carboxylation of the C–H Bond of Heteroarenes by Copper(I) Complexes

(2011) Alireza Ariafard et al.   ORGANOMETALLICS

Well-defined copper(i) complexes for Click azide–alkyne cycloaddition reactions: one Click beyond

(2011) Silvia Díez-González   Catalysis Science & Technology

Non-Innocent Behavior of a Tridentate NHC Chelating Ligand Coordinated onto a Zirconium(IV) Center

(2010) Charles Romain et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Hydrocarboxylation of Alkynes Using Carbon Dioxide and Hydrosilanes

(2010) Tetsuaki Fujihara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Direct Carboxylation of CH Bonds with Carbon Dioxide

(2010) Liang Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylation of NH/CH Bonds Using N-Heterocyclic Carbene Copper(I) Complexes

(2010) Ine I. F. Boogaerts et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of SiH, BH, and PH Bonds at a Single Nonmetal Center

(2010) Guido D. Frey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ammonia N–H activation by a N,N′-diamidocarbene

(2010) Todd W. Hudnall et al.   CHEMICAL COMMUNICATIONS

Ni(i) and Ni(ii) ring-expanded N-heterocyclic carbene complexes: C–H activation, indole elimination and catalytic hydrodehalogenation

(2010) Caroline J. E. Davies et al.   CHEMICAL COMMUNICATIONS

Synthesis of a Room-Temperature-Stable Dimeric Copper(I) Hydride

(2010) Guido D. Frey et al.   Chemistry-An Asian Journal

[(NHC)CuX] complexes: Synthesis, characterization and catalytic activities in reduction reactions and Click Chemistry. On the advantage of using well-defined catalytic systems

(2010) Silvia Díez-González et al.   DALTON TRANSACTIONS

Aromatic Nitrogen Donors for Efficient Copper(I)-NHC CuAAC under Reductant-Free Conditions

(2010) Marie-Laure Teyssot et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

N,N′-Diamidoketenimines via Coupling of Isocyanides to an N-Heterocyclic Carbene

(2010) Todd W. Hudnall et al.   JOURNAL OF ORGANIC CHEMISTRY

Expanded ring N-heterocyclic carbene complexes of zero valent platinum dvtms (divinyltetramethyldisiloxane): Highly efficient hydrosilylation catalysts

(2010) Jay J. Dunsford et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

A Seven-MemberedN,N′-Diamidocarbene

(2010) Todd W. Hudnall et al.   ORGANOMETALLICS

A Versatile Cuprous Synthon: [Cu(IPr)(OH)] (IPr = 1,3 bis(diisopropylphenyl)imidazol-2-ylidene)

(2010) George C. Fortman et al.   ORGANOMETALLICS

Copper- and copper-N-heterocyclic carbene-catalyzed CboxhH activating carboxylation of terminal alkynes with CO2 at ambient conditions

(2010) D. Yu et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

13C NMR Spectroscopy of “Arduengo-type” Carbenes and Their Derivatives

(2009) Daniela Tapu et al.   CHEMICAL REVIEWS

N-Heterocyclic Carbenes in Late Transition Metal Catalysis

(2009) Silvia Díez-González et al.   CHEMICAL REVIEWS

Coinage Metal−N-Heterocyclic Carbene Complexes

(2009) Joseph C. Y. Lin et al.   CHEMICAL REVIEWS

Improved Copper(I)-NHC Catalytic Efficiency on Huisgen Reaction by Addition of Aromatic Nitrogen Donors

(2009) Marie-Laure Teyssot et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis ofC1-Symmetric BINOLs Employing N-Heterocyclic Carbene-Copper Complexes

(2009) Alain Grandbois et al.   CHEMISTRY-A EUROPEAN JOURNAL

Expanded ring and functionalised expanded ring N-heterocyclic carbenes as ligands in catalysis

(2009) Abeer Binobaid et al.   DALTON TRANSACTIONS

Synthesis and Structural Features of Rhodium Complexes of Expanded Ring N-Heterocyclic Carbenes

(2009) Manuel Iglesias et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

The influence of moisture on deprotonation mode of imidazolinium chlorides with palladacycle acetate dimer

(2009) M. Emin Günay et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Six- and seven-membered ring carbenes: Rational synthesis of amidinium salts, generation of carbenes, synthesis of Ag(I) and Cu(I) complexes

(2009) Eugene L. Kolychev et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Noninnocent Behavior of Ancillary Ligands: Apparent Trans Coupling of a Saturated N-Heterocyclic Carbene Unit with an Ethyl Ligand Mediated by Nickel

(2009) Tobias Steinke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

AnN,N′-Diamidocarbene: Studies in C−H Insertion, Reversible Carbonylation, and Transition-Metal Coordination Chemistry

(2009) Todd W. Hudnall et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bis(2-phenylethyl)-nacnac: A Chiral Diketiminate Ligand and Its Copper Complexes

(2009) Paul O. Oguadinma et al.   ORGANOMETALLICS

Sterically Encumbered Iridium Bis(N-heterocyclic carbene) Systems: Multiple C−H Activation Processes and Isomeric Normal/Abnormal Carbene Complexes

(2009) Christina Y. Tang et al.   ORGANOMETALLICS

[(NHC)2Cu]X Complexes as Efficient Catalysts for Azide-Alkyne Click Chemistry at Low Catalyst Loadings

(2008) Silvia Díez-González et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylation of Organoboronic Esters Catalyzed by N‐Heterocyclic Carbene Copper(I) Complexes

(2008) Takeshi Ohishi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A [(NHC)CuCl] complex as a latent Click catalyst

(2008) Silvia Díez-González et al.   CHEMICAL COMMUNICATIONS

Active Trifluoromethylating Agents from Well-Defined Copper(I)−CF3Complexes

(2008) Galyna G. Dubinina et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Novel Expanded Ring N-Heterocyclic Carbenes: Free Carbenes, Silver Complexes, And Structures

(2008) Manuel Iglesias et al.   ORGANOMETALLICS

Practical One-Pot, Three-Component Synthesis of N-Heterocyclic Carbene (NHC) Ligated Palladacycles Derived fromN,N-Dimethylbenzylamine

(2008) Eric Assen B. Kantchev et al.   ORGANOMETALLICS

Anti-Markovnikov hydroamination and hydrothiolation of electron-deficient vinylarenes catalyzed by well-defined monomeric copper(i) amido and thiolate complexes

(2007) Colleen Munro-Leighton et al.   CHEMICAL COMMUNICATIONS