Copper N-heterocyclic carbene complexes in catalysis

Formation of Quaternary Stereogenic Centers by NHC-Cu-Catalyzed Asymmetric Conjugate Addition Reactions with Grignard Reagents on Polyconjugated Cyclic Enones

(2012) Matthieu Tissot et al.   CHEMISTRY-A EUROPEAN JOURNAL

Polynuclear Copper(I) Complexes with Chelating Bis- and Tris-N-Heterocyclic Carbene Ligands: Catalytic Activity in Nitrene and Carbene Transfer Reactions

(2012) Cristina Tubaro et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Chiral NHC Ligands for the Copper-Catalyzed Asymmetric Conjugate Addition of Grignard Reagents

(2012) Nicolas Germain et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Conjugate Addition of Alkylboranes Catalyzed by a Copper–N-Heterocyclic Carbene Complex

(2012) Mika Yoshida et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site- and Enantioselective Formation of Allene-Bearing Tertiary or Quaternary Carbon Stereogenic Centers through NHC–Cu-Catalyzed Allylic Substitution

(2012) Byunghyuck Jung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heteroleptic Bis(N-heterocyclic carbene)Copper(I) Complexes: Highly Efficient Systems for the [3+2] Cycloaddition of Azides and Alkynes

(2012) Faïma Lazreg et al.   ORGANOMETALLICS

Allyl-, Allenyl-, and Propargyl-Transfer Reactions through Cleavage of CC Bonds Catalyzed by an N-Heterocyclic Carbene/Copper Complex: Synthesis of Multisubstituted Pyrroles

(2011) Masahiro Sai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylation of Alkylboranes by N-Heterocyclic Carbene Copper Catalysts: Synthesis of Carboxylic Acids from Terminal Alkenes and Carbon Dioxide

(2011) Takeshi Ohishi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Aryl- and Alkenylboronates

(2011) Ryo Shintani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unprecedented Copper(I) Bifluoride Complexes: Synthesis, Characterization and Reactivity

(2011) Thomas Vergote et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chiral N-Heterocyclic Carbene−Copper(I)-Catalyzed Asymmetric Allylic Arylation of Aliphatic Allylic Bromides: Steric and Electronic Effects on γ-Selectivity

(2011) Khalid B. Selim et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Selective Methods for Synthesis of Internal (α-) Vinylboronates through Efficient NHC–Cu-Catalyzed Hydroboration of Terminal Alkynes. Utility in Chemical Synthesis and Mechanistic Basis for Selectivity

(2011) Hwanjong Jang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoconvergent Synthesis of Chiral Allylboronates from anE/ZMixture of Allylic Aryl Ethers Using a 6-NHC−Cu(I) Catalyst

(2011) Jin Kyoon Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective and Regioselective Copper-Catalyzed 1,4 Addition of Grignard Reagents to Cyclic Enynones

(2011) Matthieu Tissot et al.   ORGANIC LETTERS

Asymmetric Synthesis of Trisubstituted Allenes: Copper-Catalyzed Alkylation and Arylation of Propargylic Phosphates

(2011) Mycah R. Uehling et al.   ORGANIC LETTERS

Theoretical investigation on copper hydrides catalyzed hydrosilylation reaction of 3-methylcyclohex-2-enone: mechanism and ligands' effect

(2011) Liang Dong et al.   Catalysis Science & Technology

Copper-Catalyzed Hydrocarboxylation of Alkynes Using Carbon Dioxide and Hydrosilanes

(2010) Tetsuaki Fujihara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylation of NH/CH Bonds Using N-Heterocyclic Carbene Copper(I) Complexes

(2010) Ine I. F. Boogaerts et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper N-heterocyclic carbene (NHC) complexes as carbene transfer reagents

(2010) Marc R. L. Furst et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed asymmetric addition of arylboronates to isatins: a catalytic cycle involving alkoxocopper intermediates

(2010) Ryo Shintani et al.   CHEMICAL COMMUNICATIONS

[(NHC)CuX] complexes: Synthesis, characterization and catalytic activities in reduction reactions and Click Chemistry. On the advantage of using well-defined catalytic systems

(2010) Silvia Díez-González et al.   DALTON TRANSACTIONS

Aromatic Nitrogen Donors for Efficient Copper(I)-NHC CuAAC under Reductant-Free Conditions

(2010) Marie-Laure Teyssot et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Decarboxylative trifluoromethylation of aryl halides using well-defined copper–trifluoroacetate and –chlorodifluoroacetate precursors

(2010) Kristen A. McReynolds et al.   JOURNAL OF FLUORINE CHEMISTRY

Enantioselective Conjugate Silyl Additions to Cyclic and Acyclic Unsaturated Carbonyls Catalyzed by Cu Complexes of Chiral N-Heterocyclic Carbenes

(2010) Kang-sang Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Boron-Substituted Quaternary Carbons by NHC−Cu-Catalyzed Boronate Conjugate Additions to Unsaturated Carboxylic Esters, Ketones, or Thioesters

(2010) Jeannette M. O’Brien et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Allylboronates Bearing a Tertiary or Quaternary B-Substituted Stereogenic Carbon by NHC-Cu-Catalyzed Substitution Reactions

(2010) Aikomari Guzman-Martinez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Quaternary Carbon Stereogenic Centers through Enantioselective Cu-Catalyzed Allylic Substitutions with Vinylaluminum Reagents

(2010) Fang Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formation of Vinyl-, Vinylhalide- or Acyl-Substituted Quaternary Carbon Stereogenic Centers through NHC−Cu-Catalyzed Enantioselective Conjugate Additions of Si-Containing Vinylaluminums to β-Substituted Cyclic Enones

(2010) Tricia L. May et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Diboration of Ketones: Facile Synthesis of Tertiary α-Hydroxyboronate Esters

(2010) Melissa L. McIntosh et al.   ORGANIC LETTERS

Cu(I)-Catalyzed Carboxylative Coupling of Terminal Alkynes, Allylic Chlorides, and CO2

(2010) Wen-Zhen Zhang et al.   ORGANIC LETTERS

Tripodal N-Heterocyclic Carbene Complexes of Palladium and Copper: Syntheses, Characterization, and Catalytic Activity

(2010) Charles E. Ellul et al.   ORGANOMETALLICS

A Versatile Cuprous Synthon: [Cu(IPr)(OH)] (IPr = 1,3 bis(diisopropylphenyl)imidazol-2-ylidene)

(2010) George C. Fortman et al.   ORGANOMETALLICS

Copper- and copper-N-heterocyclic carbene-catalyzed CboxhH activating carboxylation of terminal alkynes with CO2 at ambient conditions

(2010) D. Yu et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Metal-Catalyzed Carboxylation of Organometallic Reagents with Carbon Dioxide

(2009) Arkaitz Correa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Chiral N-Heterocyclic Carbene/Copper(I)-Catalyzed Asymmetric Allylic Arylation with Aryl Grignard Reagents

(2009) Khalid B. Selim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbenes in Late Transition Metal Catalysis

(2009) Silvia Díez-González et al.   CHEMICAL REVIEWS

Improved Copper(I)-NHC Catalytic Efficiency on Huisgen Reaction by Addition of Aromatic Nitrogen Donors

(2009) Marie-Laure Teyssot et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Organocopper Chemistry from Organosiloxane Reagents

(2009) Jessica R. Herron et al.   CHEMISTRY-A EUROPEAN JOURNAL

Trinuclear copper(I) complexes with triscarbene ligands: catalysis of C–N and C–C coupling reactions

(2009) Andrea Biffis et al.   DALTON TRANSACTIONS

Monodentate Non-C2-symmetric ChiralN-Heterocyclic Carbene Complexes for Enantioselective Synthesis. Cu-Catalyzed Conjugate Additions of Aryl- and Alkenylsilylfluorides to Cyclic Enones

(2009) Kang-sang Lee et al.   JOURNAL OF ORGANIC CHEMISTRY

Efficient Boron−Copper Additions to Aryl-Substituted Alkenes Promoted by NHC−Based Catalysts. Enantioselective Cu-Catalyzed Hydroboration Reactions

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Vicinal Diboronates in High Enantiomeric Purity through Tandem Site-Selective NHC−Cu-Catalyzed Boron−Copper Additions to Terminal Alkynes

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The selective catalytic formation of β-boryl aldehydes through a base-free approach

(2009) Amadeu Bonet et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A General and Efficient Copper Catalyst for the Double Carbonylation Reaction

(2009) Jianming Liu et al.   ORGANIC LETTERS

Allylcopper Intermediates with N-Heterocyclic Carbene Ligands: Synthesis, Structure, and Catalysis

(2009) Vincenzo Russo et al.   ORGANIC LETTERS

[(NHC)2Cu]X Complexes as Efficient Catalysts for Azide-Alkyne Click Chemistry at Low Catalyst Loadings

(2008) Silvia Díez-González et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers by Catalytic Asymmetric Conjugate Additions of Alkyl and Aryl Aluminum Reagents to Five-, Six-, and Seven-Membered-Ring β-Substituted Cyclic Enones

(2008) Tricia L. May et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regiodivergent 1,4 versus 1,6 Asymmetric Copper-Catalyzed Conjugate Addition

(2008) Hélène Hénon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylation of Organoboronic Esters Catalyzed by N‐Heterocyclic Carbene Copper(I) Complexes

(2008) Takeshi Ohishi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A [(NHC)CuCl] complex as a latent Click catalyst

(2008) Silvia Díez-González et al.   CHEMICAL COMMUNICATIONS

C2Symmetric Chiral NHC Ligand for Asymmetric Quaternary Carbon Constructing Copper-Catalyzed Conjugate Addition of Grignard Reagents to 3-Substituted Cyclohexenones

(2008) Yasumasa Matsumoto et al.   JOURNAL OF ORGANIC CHEMISTRY

Active Trifluoromethylating Agents from Well-Defined Copper(I)−CF3Complexes

(2008) Galyna G. Dubinina et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Reactivity of Functionalized Arylcopper Compounds by Transmetalation of Organosilanes

(2008) Jessica R. Herron et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aziridination of Aliphatic Alkenes Catalyzed byN-Heterocyclic Carbene Copper Complexes

(2008) Qun Xu et al.   ORGANIC LETTERS

Copper(I)-Catalyzed Carboxylation of Aryl- and Alkenylboronic Esters

(2008) Jun Takaya et al.   ORGANIC LETTERS

Asymmetric β-Boration of α,β-Unsaturated Esters with Chiral (NHC)Cu Catalysts

(2008) Vanesa Lillo et al.   ORGANOMETALLICS

Efficient catalysis of Ullmann-type arylation reactions by a novel trinuclear copper(I) complex with a chelating tricarbene ligand

(2008) Cristina Tubaro et al.   TETRAHEDRON

Anti-Markovnikov hydroamination and hydrothiolation of electron-deficient vinylarenes catalyzed by well-defined monomeric copper(i) amido and thiolate complexes

(2007) Colleen Munro-Leighton et al.   CHEMICAL COMMUNICATIONS

Highly Site- and Enantioselective Cu-Catalyzed Allylic Alkylation Reactions with Easily Accessible Vinylaluminum Reagents

(2007) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY