N,N′-Diamidocarbenes Facilitate Selective CH Insertions and Transfer Hydrogenations

Isolation of a Neutral P8Cluster by [2+2] Cycloaddition of a Diphosphene Facilitated by Carbene Activation of White Phosphorus

(2013) Christopher L. Dorsey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sequential C–H Functionalization Reactions for the Enantioselective Synthesis of Highly Functionalized 2,3-Dihydrobenzofurans

(2013) Hengbin Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

(2012) Percia Beatrice Arockiam et al.   CHEMICAL REVIEWS

Alkyne and Reversible Nitrile Activation: N,N′-Diamidocarbene-Facilitated Synthesis of Cyclopropenes, Cyclopropenones, and Azirines

(2012) Jonathan P. Moerdyk et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Directed Metal (Oxo) Aliphatic C–H Hydroxylations: Overriding Substrate Bias

(2012) Marinus A. Bigi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Functionalization of Unactivated sp3 C–H Bonds via exo-Directing Groups: Synthesis of Chemically Differentiated 1,2-Diols

(2012) Zhi Ren et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic functionalization of unactivated primary C–H bonds directed by an alcohol

(2012) Eric M. Simmons et al.   NATURE

Diamidocarbenes as versatile and reversible [2 + 1] cycloaddition reagents

(2012) Jonathan P. Moerdyk et al.   Nature Chemistry

“Frustrated Lewis pair” hydrogenations

(2012) Douglas W. Stephan   ORGANIC & BIOMOLECULAR CHEMISTRY

Tuning the Electronic Properties of Carbenes: A Systematic Comparison of Neighboring Amino versus Amido Groups

(2012) Garrett A. Blake et al.   ORGANOMETALLICS

Adding Aliphatic C-H Bond Oxidations to Synthesis

(2012) M. C. White   SCIENCE

Computationally Guided Stereocontrol of the Combined CH Functionalization/Cope Rearrangement

(2011) Yajing Lian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–H functionalization logic in total synthesis

(2011) Will R. Gutekunst et al.   CHEMICAL SOCIETY REVIEWS

Recent developments in natural product synthesis using metal-catalysed C–H bond functionalisation

(2011) Lindsay McMurray et al.   CHEMICAL SOCIETY REVIEWS

Guiding principles for site selective and stereoselective intermolecular C–H functionalization by donor/acceptor rhodium carbenes

(2011) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

Regioselectivity of the borylation of alkanes and arenes

(2011) John F. Hartwig   CHEMICAL SOCIETY REVIEWS

Catalytic Asymmetric C–H Insertions of Rhodium(II) Azavinyl Carbenes

(2011) Stepan Chuprakov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combined C–H Functionalization/Cope Rearrangement with Vinyl Ethers as a Surrogate for the Vinylogous Mukaiyama Aldol Reaction

(2011) Yajing Lian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Diruthenium Catalyst for Selective, Intramolecular Allylic C–H Amination: Reaction Development and Mechanistic Insight Gained through Experiment and Theory

(2011) Mark Edwin Harvey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Measure of All Rings-N-Heterocyclic Carbenes

(2010) Thomas Dröge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ammonia N–H activation by a N,N′-diamidocarbene

(2010) Todd W. Hudnall et al.   CHEMICAL COMMUNICATIONS

The influence of electron delocalization upon the stability and structure of potential N-heterocyclic carbene precursors with 1,3-diaryl-imidazolidine-4,5-dione skeletons

(2010) Matthew G. Hobbs et al.   NEW JOURNAL OF CHEMISTRY

An N-Heterocyclic Carbene Ligand with an Oxalamide Backbone

(2010) Markus Braun et al.   ORGANOMETALLICS

A Seven-MemberedN,N′-Diamidocarbene

(2010) Todd W. Hudnall et al.   ORGANOMETALLICS

Stable singlet carbenes as mimics for transition metal centers

(2010) David Martin et al.   Chemical Science

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stable Noncyclic Singlet Carbenes

(2009) Joan Vignolle et al.   CHEMICAL REVIEWS

AnN,N′-Diamidocarbene: Studies in C−H Insertion, Reversible Carbonylation, and Transition-Metal Coordination Chemistry

(2009) Todd W. Hudnall et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular C–H insertion in ring-expanded N-heterocyclic carbenes

(2009) Robert S. Holdroyd et al.   TETRAHEDRON LETTERS

A persistent P,N-heterocyclic carbene

(2008) Guido D. Frey et al.   CHEMICAL COMMUNICATIONS

Rearrangement of Biaryl Monoaminocarbenes via Concerted Asynchronous Insertion into Aromatic C−H Bonds

(2008) Joan Vignolle et al.   ORGANIC LETTERS