New avenues for ligand-mediated processes – expanding metal reactivity by the use of redox-active catechol, o-aminophenol and o-phenylenediamine ligands

Exploiting Metal–Ligand Bifunctional Reactions in the Design of Iron Asymmetric Hydrogenation Catalysts

(2015) Robert H. Morris   ACCOUNTS OF CHEMICAL RESEARCH

Dynamic Ligand Reactivity in a Rhodium Pincer Complex

(2015) Zhou Tang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Dinuclear Palladium Complexes with Two Ligand-Centered Radicals and a Single Bridging Ligand: Subtle Tuning of Magnetic Properties

(2015) Daniël L. J. Broere et al.   CHEMISTRY-A EUROPEAN JOURNAL

On the Radical Nature of Iron-Catalyzed Cross-Coupling Reactions

(2015) Anna Hedström et al.   CHEMISTRY-A EUROPEAN JOURNAL

Facile Synthesis and Versatile Reactivity of an Unusual Cyclometalated Rhodium(I) Pincer Complex

(2015) Linda S. Jongbloed et al.   CHEMISTRY-A EUROPEAN JOURNAL

A new class of PN3-pincer ligands for metal–ligand cooperative catalysis

(2015) Huaifeng Li et al.   COORDINATION CHEMISTRY REVIEWS

Palladium(II) Complex of a Redox-Active Amidophenolate-Based O,N,S,N Ligand: Its Monocation and Dication and Reactivity with PPh3

(2015) Akram Ali et al.   INORGANIC CHEMISTRY

Formation and Site-Selective Reactivity of a Nonsymmetric Dinuclear Iridium BisMETAMORPhos Complex

(2015) Sander Oldenhof et al.   ORGANOMETALLICS

Revealing the thermodynamic driving force for ligand-based reductions in quinoids; conceptual rules for designing redox active and non-innocent ligands

(2015) G. Skara et al.   Chemical Science

Redox-Active Ligand-Induced Homolytic Bond Activation

(2014) Daniël L. J. Broere et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

(Electro)catalytic C–C bond formation reaction with a redox-active cobalt complex

(2014) Margarethe van der Meer et al.   CHEMICAL COMMUNICATIONS

Influence of redox non-innocent phenylenediamido ligands on chromium imido hydrogen-atom abstraction reactivity

(2014) Wen Zhou et al.   CHEMICAL COMMUNICATIONS

Iminosemiquinone radical ligands enable access to a well-defined redox-active CuII–CF3 complex

(2014) Jérémy Jacquet et al.   CHEMICAL COMMUNICATIONS

Metal–ligand bifunctional reactivity and catalysis of protic N-heterocyclic carbene and pyrazole complexes featuring β-NH units

(2014) Shigeki Kuwata et al.   CHEMICAL COMMUNICATIONS

Bond Activation and Catalysis by Ruthenium Pincer Complexes

(2014) Chidambaram Gunanathan et al.   CHEMICAL REVIEWS

Correlated Coordination and Redox Activity of a Hemilabile Noninnocent Ligand in Nickel Complexes

(2014) Alexa Paretzki et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Novel Pentadentate Redox-Active Ligand and Its Iron(III) Complexes: Electronic Structures and O2Reactivity

(2014) Ramona Metzinger et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanism of Redox-Active Ligand-Assisted Nitrene-Group Transfer in a ZrIVComplex: Direct Ligand-to-Ligand Charge Transfer Preferred

(2014) Soumya Ghosh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ruthenium pincer complexes: Ligand design and complex synthesis

(2014) Hussein A. Younus et al.   COORDINATION CHEMISTRY REVIEWS

Iron(iii) complexes of tripodal tetradentate 4N ligands as functional models for catechol dioxygenases: the electronic vs. steric effect on extradiol cleavage

(2014) Mani Balamurugan et al.   DALTON TRANSACTIONS

Metal effects on ligand non-innocence in Group 5 complexes of the redox-active [ONO] pincer ligand

(2014) Steven Hananouchi et al.   DALTON TRANSACTIONS

Biomimetic iron(iii) complexes of facially and meridionally coordinating tridentate 3N ligands: tuning of regioselective extradiol dioxygenase activity in organized assemblies

(2014) Muniyandi Sankaralingam et al.   DALTON TRANSACTIONS

A Copper Complex of a Noninnocent Iminophenol-Amidopyridine Hybrid Ligand: Synthesis, Characterization, and Aerobic Alcohol Oxidation

(2014) Zahra Alaji et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Dioxygen Reactivity of Biomimetic Fe(II) Complexes with Noninnocent Catecholate, o-Aminophenolate, and o-Phenylenediamine Ligands

(2014) Michael M. Bittner et al.   INORGANIC CHEMISTRY

Water Oxidation Chemistry of a Synthetic Dinuclear Ruthenium Complex Containing Redox-Active Quinone Ligands

(2014) Hiroshi Isobe et al.   INORGANIC CHEMISTRY

Mechanism and Selectivity of Methyl and Phenyl Migrations in Hypervalent Silylated Iminoquinones

(2014) Sukesh Shekar et al.   JOURNAL OF ORGANIC CHEMISTRY

Intramolecular Redox-Active Ligand-to-Substrate Single-Electron Transfer: Radical Reactivity with a Palladium(II) Complex

(2014) Daniël L. J. Broere et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Radical Reductive Elimination from Tetrabenzyluranium Mediated by an Iminoquinone Ligand

(2014) Ellen M. Matson et al.   ORGANOMETALLICS

Structure and Spectroelectrochemical Response of Arene–Ruthenium and Arene–Osmium Complexes with Potentially Hemilabile Noninnocent Ligands

(2014) Martina Bubrin et al.   ORGANOMETALLICS

Iron-mediated intermolecular N-group transfer chemistry with olefinic substrates

(2014) Elisabeth T. Hennessy et al.   Chemical Science

The NH Functional Group in Organometallic Catalysis

(2013) Baoguo Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbene Radicals in Cobalt(II)-Porphyrin-Catalysed Carbene Carbonylation Reactions; A Catalytic Approach to Ketenes

(2013) Nanda D. Paul et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis, characterization and catalytic activity of copper(ii) complexes containing a redox-active benzoxazole iminosemiquinone ligand

(2013) S. Esmael Balaghi et al.   DALTON TRANSACTIONS

The new C–C bond formation in the reaction of o-amidophenolate indium(iii) complex with alkyl iodides

(2013) Alexandr V. Piskunov et al.   DALTON TRANSACTIONS

Group transfer reactions of d0 transition metal complexes: redox-active ligands provide a mechanism for expanded reactivity

(2013) Rui F. Munhá et al.   DALTON TRANSACTIONS

Synthesis, Coordination Chemistry, and Cooperative Activation of H2with Ruthenium Complexes of Proton-Responsive METAMORPhos Ligands

(2013) Frédéric G. Terrade et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Tris(3,5-di-tert-butylcatecholato)molybdenum(VI): Lewis Acidity and Nonclassical Oxygen Atom Transfer Reactions

(2013) Amanda H. Randolph et al.   INORGANIC CHEMISTRY

Tuning the Electronic and Steric Parameters of a Redox-Active Tris(amido) Ligand

(2013) Rui F. Munhá et al.   INORGANIC CHEMISTRY

“Oxidative Addition” of Halogens to Uranium(IV) Bis(amidophenolate) Complexes

(2013) Ellen M. Matson et al.   INORGANIC CHEMISTRY

Nonclassical Oxygen Atom Transfer as a Synthetic Strategy: Preparation of an Oxorhenium(V) Complex of the Bis(3,5-di-tert-butyl-2-phenoxo)amide Ligand

(2013) Daniel D. Wright et al.   INORGANIC CHEMISTRY

Reactivity of a Mononuclear Iridium(I) Species Bearing a Terminal Phosphido Fragment Embedded in a Triphosphorus Ligand

(2013) Yann Gloaguen et al.   INORGANIC CHEMISTRY

Addition of allyl halides to the new bis-o-amidophenolate gallium(III) complex

(2013) Alexandr V. Piskunov et al.   INORGANIC CHEMISTRY COMMUNICATIONS

Nonprecious-Metal-Assisted Photochemical Hydrogen Production from ortho-Phenylenediamine

(2013) Takeshi Matsumoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metalloradical Approach to 2H-Chromenes

(2013) Nanda D. Paul et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroxy-substituted pyridine-like N-heterocycles: versatile ligands in organometallic catalysis

(2013) Wan-Hui Wang et al.   NEW JOURNAL OF CHEMISTRY

Reductive Elimination at an Ortho-Metalated Iridium(III) Hydride Bearing a Tripodal Tetraphosphorus Ligand

(2013) Yann Gloaguen et al.   ORGANOMETALLICS

Migrations of Alkyl and Aryl Groups from Silicon to Nitrogen in Silylated Aryloxyiminoquinones

(2013) Sukesh Shekar et al.   ORGANOMETALLICS

Complex N-Heterocycle Synthesis via Iron-Catalyzed, Direct C-H Bond Amination

(2013) E. T. Hennessy et al.   SCIENCE

Disulfide reductive elimination from an iron(iii) complex

(2013) Janice L. Wong et al.   Chemical Science

Aromatic Ring Cleavage of 2-Amino-4-tert-butylphenol by a Nonheme Iron(II) Complex: Functional Model of 2-Aminophenol Dioxygenases

(2012) Biswarup Chakraborty et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox-Active Ligands in Catalysis

(2012) Vijayendran K. K. Praneeth et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Cross-Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize

(2012) Carin C. C. Johansson Seechurn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ring-Cleaving Dioxygenases with a Cupin Fold

(2012) Susanne Fetzner   APPLIED AND ENVIRONMENTAL MICROBIOLOGY

Nonclassical oxygen atom transfer reactions of oxomolybdenum(vi) bis(catecholate)

(2012) Travis Marshall-Roth et al.   CHEMICAL COMMUNICATIONS

Redox-active ligands in catalysis

(2012) Oana R. Luca et al.   CHEMICAL SOCIETY REVIEWS

Reversible Binding of Molecular Oxygen to Catecholate and Amidophenolate Complexes of SbV: Electronic and Steric Factors

(2012) Georgy K. Fukin et al.   CHEMPHYSCHEM

N–H bond activation by palladium(ii) and copper(i) complexes featuring a reactive bidentate PN-ligand

(2012) Sandra Y. de Boer et al.   DALTON TRANSACTIONS

Metrical Oxidation States of 2-Amidophenoxide and Catecholate Ligands: Structural Signatures of Metal–Ligand π Bonding in Potentially Noninnocent Ligands

(2012) Seth N. Brown   INORGANIC CHEMISTRY

Catalytic Carbon–Carbon σ-Bond Hydrogenation with Water Catalyzed by Rhodium Porphyrins

(2012) Ching Tat To et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Coordination Versatility of sp3-Hybridized Pincer Ligands toward Ligand–Metal Cooperative Catalysis

(2012) Dmitri Gelman et al.   ACS Catalysis

Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions

(2012) Volodymyr Lyaskovskyy et al.   ACS Catalysis

Metal–Ligand Cooperation by Aromatization–Dearomatization: A New Paradigm in Bond Activation and “Green” Catalysis

(2011) Chidambaram Gunanathan et al.   ACCOUNTS OF CHEMICAL RESEARCH

Ligands that Store and Release Electrons during Catalysis

(2011) Wojciech I. Dzik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Donor–acceptor systems of Pt(ii) and redox-induced reactivity towards small molecules

(2011) Naina Deibel et al.   CHEMICAL COMMUNICATIONS

Dinuclear Copper(I) Thiolate Complexes with a Bridging Noninnocent PNP Ligand

(2011) Jarl Ivar van der Vlugt et al.   CHEMISTRY-A EUROPEAN JOURNAL

Pincer ligands with an all-phosphorus donor set: subtle differences between rhodium and palladium

(2011) Richard C. Bauer et al.   DALTON TRANSACTIONS

A Redox-Active Ligand as a Reservoir for Protons and Electrons: O2 Reduction at Zirconium(IV)

(2011) Feng Lu et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Aerobic Alcohol Oxidations Catalyzed by Oxorhenium Complexes Containing Redox-Active Ligands

(2011) Cameron A. Lippert et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cooperative Aliphatic PNP Amido Pincer Ligands - Versatile Building Blocks for Coordination Chemistry and Catalysis

(2011) Sven Schneider et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cooperative Catalysis with First-Row Late Transition Metals

(2011) Jarl Ivar van der Vlugt   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Harnessing Redox-Active Ligands for Low-Barrier Radical Addition at Oxorhenium Complexes

(2011) Cameron A. Lippert et al.   INORGANIC CHEMISTRY

Redox Properties of Tanaka’s Water Oxidation Catalyst: Redox Noninnocent Ligands Dominate the Electronic Structure and Reactivity

(2011) Soumya Ghosh et al.   INORGANIC CHEMISTRY

Designing Catalysts for Nitrene Transfer Using Early Transition Metals and Redox-Active Ligands

(2011) Alan F. Heyduk et al.   INORGANIC CHEMISTRY

Redox Noninnocence of Carbene Ligands: Carbene Radicals in (Catalytic) C−C Bond Formation

(2011) Wojciech I. Dzik et al.   INORGANIC CHEMISTRY

Ligand Redox Activity and Mixed Valency in First-Row Transition-Metal Complexes Containing Tetrachlorocatecholate and Radical Tetrachlorosemiquinonate Ligands

(2011) Cortlandt G. Pierpont   INORGANIC CHEMISTRY

Preface: Forum on Redox-Active Ligands

(2011) Paul J. Chirik   INORGANIC CHEMISTRY

Manifestations of Noninnocent Ligand Behavior

(2011) Wolfgang Kaim   INORGANIC CHEMISTRY

Noninnocence in Metal Complexes: A Dithiolene Dawn

(2011) Richard Eisenberg et al.   INORGANIC CHEMISTRY

CuI click catalysis with cooperative noninnocent pyridylphosphine ligands

(2011) Sandra Y. de Boer et al.   INORGANICA CHIMICA ACTA

Microbial degradation of aromatic compounds — from one strategy to four

(2011) Georg Fuchs et al.   NATURE REVIEWS MICROBIOLOGY

Reactivity of Organometallic Tantalum Complexes Containing a Bis(phenoxy)amide (ONO)3–Ligand with Aryl Azides and 1,2-Diphenylhydrazine

(2011) Ryan A. Zarkesh et al.   ORGANOMETALLICS

Reversible Intramolecular Single-Electron Oxidative Addition Involving a Hemilabile Noninnocent Ligand

(2011) Ralph Hübner et al.   ORGANOMETALLICS

Tunable Hemilabile Ligands for Adaptive Transition Metal Complexes

(2011) Ronald Lindner et al.   ORGANOMETALLICS

Understanding Hydrogen Atom Transfer: From Bond Strengths to Marcus Theory

(2010) James M. Mayer   ACCOUNTS OF CHEMICAL RESEARCH

Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications

(2010) Jeffrey J. Warren et al.   CHEMICAL REVIEWS

Non-innocent ligands in bioinorganic chemistry—An overview

(2010) Wolfgang Kaim et al.   COORDINATION CHEMISTRY REVIEWS

o-Dithiolene and o-aminothiolate chemistry of iron: Synthesis, structure and reactivity

(2010) Stephen Sproules et al.   COORDINATION CHEMISTRY REVIEWS

Dithiolene radicals: Sulfur K-edge X-ray absorption spectroscopy and Harry's intuition

(2010) Stephen Sproules et al.   COORDINATION CHEMISTRY REVIEWS

Deoxygenation of Nitroxyl Radicals by Oxorhenium(V) Complexes with Redox-Active Ligands

(2010) Cameron A. Lippert et al.   INORGANIC CHEMISTRY

Steric and Electronic Consequences of Flexibility in a Tetradentate Redox-Active Ligand: Ti(IV) and Zr(IV) Complexes

(2010) Géza Szigethy et al.   INORGANIC CHEMISTRY

A new type of electrochemical oxidation of alcohols mediated with a ruthenium–dioxolene–amine complex in neutral water

(2010) Hironobu Ozawa et al.   INORGANICA CHIMICA ACTA

Redox-Active Ligands Facilitate Bimetallic O2Homolysis at Five-Coordinate Oxorhenium(V) Centers

(2010) Cameron A. Lippert et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Active Ligand-Mediated Oxidative Addition and Reductive Elimination at Square Planar Cobalt(III): Multielectron Reactions for Cross-Coupling

(2010) Aubrey L. Smith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidation of Dihydrogen by Iridium Complexes of Redox-Active Ligands

(2010) Mark R. Ringenberg et al.   ORGANOMETALLICS

Radical Ligands Confer Nobility on Base-Metal Catalysts

(2010) P. J. Chirik et al.   SCIENCE

Discovery of Environmentally Benign Catalytic Reactions of Alcohols Catalyzed by Pyridine-Based Pincer Ru Complexes, Based on Metal–Ligand Cooperation

(2010) David Milstein   TOPICS IN CATALYSIS

Catalytic nitrene transfer by a zirconium(iv) redox-active ligand complex

(2010) Andy I. Nguyen et al.   Chemical Science

Neutral Tridentate PNP Ligands and Their Hybrid Analogues: Versatile Non-Innocent Scaffolds for Homogeneous Catalysis

(2009) Jarl Ivar van der Vlugt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereospecific Living Radical Polymerization: Dual Control of Chain Length and Tacticity for Precision Polymer Synthesis

(2009) Kotaro Satoh et al.   CHEMICAL REVIEWS

Hydrogen-Atom Transfer in Reactions of Organic Radicals with [CoII(por)].(por=Porphyrinato) and in Subsequent Addition of [Co(H)(por)] to Olefins

(2009) Bas de Bruin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ruthenium complexes with non-innocent ligands: Electron distribution and implications for catalysis

(2009) Julie L. Boyer et al.   COORDINATION CHEMISTRY REVIEWS

Group IV Coordination Chemistry of a Tetradentate Redox-Active Ligand in Two Oxidation States

(2009) Karen J. Blackmore et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Iron(III) Complexes of Tripodal Monophenolate Ligands as Models for Non-Heme Catechol Dioxygenase Enzymes: Correlation of Dioxygenase Activity with Ligand Stereoelectronic Properties

(2009) Ramasamy Mayilmurugan et al.   INORGANIC CHEMISTRY

One- and Two-Electron Reactivity of a Tantalum(V) Complex with a Redox-Active Tris(amido) Ligand

(2009) Andy I. Nguyen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactivity of Diazoalkanes with Tantalum(V) Complexes of a Tridentate Amido-Bis(phenolate) Ligand

(2009) Ryan A. Zarkesh et al.   ORGANOMETALLICS

A Cationic AgI(PNPtBu) Species Acting as PNP Transfer Agent: Facile Synthesis of Pd(PNPtBu)(alkyl) Complexes and Their Reactivity Compared to PCPtBuAnalogues

(2009) Jarl Ivar van der Vlugt et al.   ORGANOMETALLICS

Modularly Designed Transition Metal PNP and PCP Pincer Complexes based on Aminophosphines: Synthesis and Catalytic Applications

(2008) David Benito-Garagorri et al.   ACCOUNTS OF CHEMICAL RESEARCH

Four-Electron Oxidative Formation of Aryl Diazenes Using a Tantalum Redox-Active Ligand Complex

(2008) Ryan A. Zarkesh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition metal complexes with bulky 4,6-di-tert-butyl-N-aryl(alkyl)-o-iminobenzoquinonato ligands: Structure, EPR and magnetism

(2008) Andrey I. Poddel'sky et al.   COORDINATION CHEMISTRY REVIEWS

Mechanism of extradiol aromatic ring-cleaving dioxygenases

(2008) John D Lipscomb   CURRENT OPINION IN STRUCTURAL BIOLOGY

Cationic and neutral NiIIcomplexes containing a non-innocent PNP ligand: formation of alkyl and thiolate species

(2008) Jarl Ivar van der Vlugt et al.   DALTON TRANSACTIONS

Oxidation of ano-Iminobenzosemiquinone Radical Ligand by Molecular Bromine: Structural, Spectroscopic, and Reactivity Studies of a Copper(II)o-Iminobenzoquinone Complex

(2008) Chandan Mukherjee et al.   INORGANIC CHEMISTRY

Water Oxidation by a Ruthenium Complex with Noninnocent Quinone Ligands: Possible Formation of an O−O Bond at a Low Oxidation State of the Metal

(2008) James T. Muckerman et al.   INORGANIC CHEMISTRY

Redox Activation of Alkene Ligands in Platinum Complexes with Non-innocent Ligands

(2008) Julie L. Boyer et al.   INORGANIC CHEMISTRY

π•−π•Bonding Interactions Generated by Halogen Oxidation of Zirconium(IV) Redox-Active Ligand Complexes

(2008) Nicole A. Ketterer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Reactivity of a Zirconium(IV) Redox-Active Ligand Complex with 1,2-Diphenylhydrazine

(2008) Karen J. Blackmore et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Switched Oxidation of Dihydrogen Using a Non-Innocent Ligand

(2007) Mark R. Ringenberg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY