期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 33, 页码 11574-11577出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja502164f
关键词
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资金
- European Research Council (ERC) [279097]
- NWO
Coordination of the redox-active tridentate NNO ligand L-H2 to Pd-II yields the paramagnetic iminobenzosemiquinonato complex 3. Single-electron reduction of 3 yields diamagnetic amidophenolato complex 4, capable of activating aliphatic azide 5. Experimental and computational studies suggest a redox-noninnocent pathway wherein the redox-active ligand facilitates intramolecular ligand-to-substrate single-electron transfer to generate an open-shell singlet nitrene-substrate radical, ligand radical, enabling subsequent radical-type C-H amination reactivity with Pd-II.
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