The Intrinsic Barrier Width and Its Role in Chemical Reactivity

Solvation Effects on Quantum Tunneling Reactions

(2022) Tim Schleif et al.   ACCOUNTS OF CHEMICAL RESEARCH

Hydrogen Tunneling in Catalytic Hydrolysis and Alcoholysis of Silanes

(2022) Naroa Almenara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Portable Models for Entropy Effects on Kinetic Selectivity

(2022) Dean J. Tantillo   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Halogen-atom and group transfer reactivity enabled by hydrogen tunneling

(2022) Timothée Constantin et al.   SCIENCE

Large Isotope Effects in Organometallic Chemistry

(2021) Phan T. Truong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chemistry under Vibrational Strong Coupling

(2021) Kalaivanan Nagarajan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heavy-Atom Tunneling in Organic Reactions

(2020) Claire Castro et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heavy Atom Tunneling in Semibullvalenes: How Driving Force, Substituents, and Environment Influence the Tunneling Rates

(2020) Tim Schleif et al.   CHEMISTRY-A EUROPEAN JOURNAL

Electric-Field Mediated Chemistry: Uncovering and Exploiting the Potential of (Oriented) Electric Fields to Exert Chemical Catalysis and Reaction Control

(2020) Sason Shaik et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Mystery of the Benzene‐Oxide/Oxepin Equilibrium—Heavy‐Atom Tunneling Reversed by Solvent Interactions

(2020) Tim Schleif et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rate-Driving Force Relationships in the Multisite-PCET Activation of Ketones

(2019) Guanqi Qiu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tunneling Controls the Reaction Pathway in the Deformylation of Aldehydes by a Nonheme Iron(III)–Hydroperoxo Complex: Hydrogen Atom Abstraction versus Nucleophilic Addition

(2019) Seong Hee Bae et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen Abstraction/Addition Tunneling Reactions Elucidate the Interstellar H2NCHO/HNCO Ratio and H2 Formation

(2019) Karolina A. Haupa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structure and reactivity/selectivity control by oriented-external electric fields

(2018) Sason Shaik et al.   CHEMICAL SOCIETY REVIEWS

Harnessing electrostatic catalysis in single molecule, electrochemical and chemical systems: a rapidly growing experimental tool box

(2018) Simone Ciampi et al.   CHEMICAL SOCIETY REVIEWS

Elucidating the Roles of Electric Fields in Catalysis: A Perspective

(2018) Fanglin Che et al.   ACS Catalysis

Origins of Enzyme Catalysis: Experimental Findings for C–H Activation, New Models, and Their Relevance to Prevailing Theoretical Constructs

(2017) Judith P. Klinman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Privileged Role of Thiolate as the Axial Ligand in Hydrogen Atom Transfer Reactions by Oxoiron(IV) Complexes in Shaping the Potential Energy Surface and Inducing Significant H-Atom Tunneling

(2017) Johannes E. M. N. Klein et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen Tunneling above Room Temperature Evidenced by Infrared Ion Spectroscopy

(2017) Mathias Schäfer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tunneling Control of Chemical Reactions: The Third Reactivity Paradigm

(2017) Peter R. Schreiner   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Why Are Vinyl Cations Sluggish Electrophiles?

(2017) Peter A. Byrne et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Failure and Redemption of Statistical and Nonstatistical Rate Theories in the Hydroboration of Alkenes

(2017) Johnathan O. Bailey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimodal Evans–Polanyi Relationships in Dioxirane Oxidations of sp3 C–H: Non-perfect Synchronization in Generation of Delocalized Radical Intermediates

(2017) Fengjiao Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hybrid Light–Matter States in a Molecular and Material Science Perspective

(2016) Thomas W. Ebbesen   ACCOUNTS OF CHEMICAL RESEARCH

Interplay of Tunneling, Two-State Reactivity, and Bell–Evans–Polanyi Effects in C–H Activation by Nonheme Fe(IV)O Oxidants

(2016) Debasish Mandal et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Thermally activated tunneling in organic reactions

(2016) Edyta M. Greer et al.   TETRAHEDRON

Chemistry in motion—off the MEP

(2015) Julia Rehbein et al.   TETRAHEDRON LETTERS

Energy Disposition in Reactive Intermediates

(2013) Barry K. Carpenter   CHEMICAL REVIEWS

Tunnelling control of chemical reactions – the organic chemist's perspective

(2012) David Ley et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Farewell to the HSAB Treatment of Ambident Reactivity

(2011) Herbert Mayr et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Biomolecules under mechanical stress: A simple mechanism of complex behavior

(2011) Yohichi Suzuki et al.   JOURNAL OF CHEMICAL PHYSICS

Cyclopropylhydroxycarbene

(2011) David Ley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Methylhydroxycarbene: Tunneling Control of a Chemical Reaction

(2011) P. R. Schreiner et al.   SCIENCE

Understanding Hydrogen Atom Transfer: From Bond Strengths to Marcus Theory

(2010) James M. Mayer   ACCOUNTS OF CHEMICAL RESEARCH

Marcus Analysis of Ambident Reactivity

(2010) Martin Breugst et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electronic Effects on Atom Tunneling: Conformational Isomerization of MonomericPara-Substituted Benzoic Acid Derivatives

(2010) Shadi Amiri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Calculations Predict That Carbon Tunneling Allows the Degenerate Cope Rearrangement of Semibullvalene to Occur Rapidly at Cryogenic Temperatures

(2010) Xue Zhang et al.   ORGANIC LETTERS

Dynamics and the Failure of Transition State Theory in Alkene Hydroboration

(2009) Yatsandra Oyola et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen Bonding Lowers Intrinsic Nucleophilicity of Solvated Nucleophiles

(2008) Xin Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY