期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 59, 期 22, 页码 8355-8366出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201914943
关键词
annulenes; quantum chemistry; reaction mechanisms; tunneling
资金
- National Science Foundation [CHE-1565793]
In the past few years, numerous investigations have been reported on the role of heavy-atom tunneling in the area of pericyclic reactions, pi-bond-shifting, and other processes. These studies illustrate unique strategies for the experimental detection of heavy-atom tunneling and the increased use of calculations to predict it. This Minireview focuses primarily on carbon tunneling in ground-state processes but also highlights nitrogen tunneling and the first example of excited-state heavy-atom tunneling. Salient features of these reactions along with potential limitations are discussed, as well as challenges and directions for future investigation.
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