Lewis Acid Stabilized Diatomic Molecules of Group 14: A Computational Study on [(CO)4Fe]2E2 (E = C, Si, Ge, Sn, Pb)

The Heaviest Bottleable Metallylone: Synthesis of a Monatomic, Zero‐Valent Lead Complex (“Plumbylone”)

(2022) Jian Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isolation and Reactivity of Tetrylene‐Tetrylone‐Iron Complexes Supported by Bis(N‐Heterocyclic Imine) Ligands

(2022) Xuan-Xuan Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Genuine Stannylone with a Monoatomic Two‐Coordinate Tin(0) Atom Supported by a Bis(silylene) Ligand

(2021) Jian Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mono- and Dicoordinate Germanium(0) as a Four-Electron Donor

(2018) Debdeep Mandal et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cyclic Alkyl(amino) Carbene Stabilized Complexes with Low Coordinate Metals of Enduring Nature

(2016) Sudipta Roy et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Bis(silylenyl)pyridine Zero-Valent Germanium Complex and Its Remarkable Reactivity

(2016) Yu-Peng Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Molecular Precursor to Phosphaethyne and Its Application in Synthesis of the Aromatic 1,2,3,4-Phosphatriazolate Anion

(2016) Wesley J. Transue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organometallic chemistry: Heavyweight isomer brings stability

(2016) David Scheschkewitz   Nature Chemistry

A stable heavier group 14 analogue of vinylidene

(2016) Arnab Rit et al.   Nature Chemistry

Novel silicon phases and nanostructures for solar energy conversion

(2016) Stefan Wippermann et al.   Applied Physics Reviews

Electron Flow in Reaction Mechanisms-Revealed from First Principles

(2015) Gerald Knizia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stabilization of Heterodiatomic SiC Through Ligand Donation: Theoretical Investigation of SiC(L)2(L=NHCMe, CAACMe, PMe3)

(2015) Diego M. Andrada et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Mediated Cleavage of a SiSi Double Bond

(2015) Hunter P. Hickox et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

SiSi Double Bonds: Synthesis of an NHC-Stabilized Disilavinylidene

(2015) Priyabrata Ghana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise

(2014) Michèle Soleilhavoup et al.   ACCOUNTS OF CHEMICAL RESEARCH

N-Heterocyclic Carbene Coordinated Neutral and Cationic Heavier Cyclopropylidenes

(2014) Anukul Jana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An N-Heterocyclic Silylene-Stabilized Digermanium(0) Complex

(2014) Yu-Liang Shan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silavinylidene Stabilized by an N-Heterocyclic Carbene: A Theoretically Predicted Stable Molecule

(2014) Jing Xu et al.   CHEMISTRY-A EUROPEAN JOURNAL

NHC-coordinated silagermenylidene functionalized in allylic position and its behaviour as a ligand

(2014) Anukul Jana et al.   DALTON TRANSACTIONS

Application of the Donor–Acceptor Concept to Intercept Low Oxidation State Group 14 Element Hydrides using a Wittig Reagent as a Lewis Base

(2014) Anindya K. Swarnakar et al.   INORGANIC CHEMISTRY

Direct Band Gap Silicon Allotropes

(2014) Qianqian Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Molecular Complex with a Formally Neutral Iron Germanide Motif (Fe2Ge2)

(2014) Anukul Jana et al.   ORGANOMETALLICS

NHC-Stabilized Silagermenylidene: A Heavier Analogue of Vinylidene

(2013) Anukul Jana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Cyclic Silylone (“Siladicarbene”) with an Electron-Rich Silicon(0) Atom

(2013) Yun Xiong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Stable Singlet Biradicaloid Siladicarbene: (L:)2Si

(2013) Kartik Chandra Mondal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Mössbauer Spectroscopy of Formal Tin(II) Dichloride and Dihydride Species Supported by Lewis Acids and Bases

(2013) S. M. Ibrahim Al-Rafia et al.   INORGANIC CHEMISTRY

Intrinsic Atomic Orbitals: An Unbiased Bridge between Quantum Theory and Chemical Concepts

(2013) Gerald Knizia   Journal of Chemical Theory and Computation

NBO 6.0: Natural bond orbital analysis program

(2013) Eric D. Glendening et al.   JOURNAL OF COMPUTATIONAL CHEMISTRY

Acyclic Germylones: Congeners of Allenes with a Central Germanium Atom

(2013) Yan Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Cyclic Germadicarbene (“Germylone”) from Germyliumylidene

(2013) Yun Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stable Complexes of Parent Digermene: An Inorganic Analogue of Ethylene

(2013) S. M. Ibrahim Al-Rafia et al.   ORGANOMETALLICS

Lewis Base Stabilized Dicarbon: Predictions from Theory

(2012) Jason L. Dutton et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An N-heterocyclic carbene adduct of diatomic tin, :SnSn:

(2012) Cameron Jones et al.   CHEMICAL COMMUNICATIONS

Natural bond orbital analysis: A critical overview of relationships to alternative bonding perspectives

(2012) Frank Weinhold   JOURNAL OF COMPUTATIONAL CHEMISTRY

Tetragonal Allotrope of Group 14 Elements

(2012) Zhisheng Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trapping the Parent Inorganic Ethylenes H2SiGeH2 and H2SiSnH2 in the Form of Stable Adducts at Ambient Temperature

(2011) S. M. Ibrahim Al-Rafia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intercepting low oxidation state main group hydrides with a nucleophilic N-heterocyclic olefin

(2011) S. M. Ibrahim Al-Rafia et al.   CHEMICAL COMMUNICATIONS

Efficient generation of stable adducts of Si(ii) dihydride using a donor–acceptor approach

(2011) S. M. Ibrahim Al-Rafia et al.   CHEMICAL COMMUNICATIONS

A stable silicon(ii) monohydride

(2011) Anukul Jana et al.   DALTON TRANSACTIONS

Stabilization of Low Valent Silicon Fluorides in the Coordination Sphere of Transition Metals

(2011) Ramachandran Azhakar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Overcoming lability of extremely long alkane carbon–carbon bonds through dispersion forces

(2011) Peter R. Schreiner et al.   NATURE

Hydrosilylation of a Silicon(II) Hydride: Synthesis and Characterization of a Remarkable Silylsilylene

(2010) Shu-Hua Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Preparation of iron carbonyl complexes of germanium(II) and tin(II) each with a terminal fluorine atom

(2010) Anukul Jana et al.   JOURNAL OF FLUORINE CHEMISTRY

Steering S−H and N−H Bond Activation by a Stable N-Heterocyclic Silylene: Different Addition of H2S, NH3, and Organoamines on a Silicon(II) Ligand versus Its Si(II)→Ni(CO)3Complex

(2010) Antje Meltzer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stabilization of the Heavy Methylene Analogues, GeH2and SnH2, within the Coordination Sphere of a Transition Metal

(2010) S. M. Ibrahim Al-Rafia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

SiBr2(Idipp): A Stable N-Heterocyclic Carbene Adduct of Dibromosilylene

(2009) Alexander C. Filippou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis Base Stabilized Dichlorosilylene

(2009) Rajendra S. Ghadwal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Stabilized Digermanium(0)

(2009) Anastas Sidiropoulos et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Donor/acceptor stabilization of Ge(ii) dihydride

(2009) Kelsey C. Thimer et al.   CHEMICAL COMMUNICATIONS

A rational design for an efficient synthesis of a monomeric tin(ii) hydroxide

(2009) Anukul Jana et al.   CHEMICAL COMMUNICATIONS

Transition-Metal Complexes [(PMe3)2Cl2M(E)] and [(PMe3)2(CO)2M(E)] with Naked Group 14 Atoms (E=C-Sn) as Ligands; Part 2: Complexation with W(CO)5

(2009) Pattiyil Parameswaran et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transition-Metal Complexes [(PMe3)2Cl2M(E)] and [(PMe3)2(CO)2M(E)] with Naked Group 14 Atoms (E=C-Sn) as Ligands; Part 1: Parent Compounds

(2009) Pattiyil Parameswaran et al.   CHEMISTRY-A EUROPEAN JOURNAL

Divalent Silicon(0) Compounds

(2009) Nozomi Takagi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Divalent E(0) Compounds (E=Si-Sn)

(2009) Nozomi Takagi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Diketiminate Silicon(II) and Related NHSi Ligands Generated in the Coordination Sphere of Nickel(0)

(2009) Antje Meltzer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of an Extremely Bent Acyclic Allene (A “Carbodicarbene”): A Strong Donor Ligand

(2008) C. Adam Dyker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Stable Silicon(0) Compound with a Si=Si Double Bond

(2008) Y. Wang et al.   SCIENCE