A Cyclic Silylone (“Siladicarbene”) with an Electron-Rich Silicon(0) Atom

A Stable Singlet Biradicaloid Siladicarbene: (L:)2Si

(2013) Kartik Chandra Mondal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Cyclic Germadicarbene (“Germylone”) from Germyliumylidene

(2013) Yun Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Generic One-Pot Route to Acyclic Two-Coordinate Silylenes from Silicon(IV) Precursors: Synthesis and Structural Characterization of a Silylsilylene

(2012) Andrey V. Protchenko et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Acyclic Imino-Substituted Silylene: Synthesis, Isolation, and its Facile Conversion into a Zwitterionic Silaimine

(2012) Shigeyoshi Inoue et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Elusive Silyliumylidene [ClSi:]+and Silathionium [ClSiS]+Cations Stabilized by Bis(Iminophosphorane) Chelate Ligand

(2012) Yun Xiong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Conversion of a Singlet Silylene to a stable Biradical

(2012) Kartik Chandra Mondal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbodiphosphorane Analogues E(PPh3)2 with E=C-Pb: A Theoretical Study with Implications for Ligand Design

(2012) Nozomi Takagi et al.   CHEMISTRY-A EUROPEAN JOURNAL

New Isolable Dialkylsilylene and Its Isolable Dimer That Equilibrate in Solution

(2012) Takashi Abe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Stable Two-Coordinate Acyclic Silylene

(2012) Andrey V. Protchenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation of a Stable, Acyclic, Two-Coordinate Silylene

(2012) Brian D. Rekken et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Two-armed silicon

(2012) Robert West   NATURE

Breaking the limits with silylenes

(2012) Matthias Driess   Nature Chemistry

Aromatic Ylide-Stabilized Carbocyclic Silylene

(2011) Matthew Asay et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemistry of functionalized silylenes

(2011) Sakya S. Sen et al.   Chemical Science

An isolable dialkylsilylene and its derivatives. A step toward comprehension of heavy unsaturated bonds

(2010) Mitsuo Kira   CHEMICAL COMMUNICATIONS

Stable N-Heterocyclic Carbene Adducts of Arylchlorosilylenes and Their Germanium Homologues

(2010) Alexander C. Filippou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Lewis Base Stabilized Dichlorosilylene

(2009) Rajendra S. Ghadwal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Striking Reactivity of a Stable, Zwitterionic Silylene Towards Substituted Diazomethanes, Azides, and Isocyanides

(2009) Yun Xiong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Versatile Reactivity of a Zwitterionic Isolable Silylene toward Ketones: Silicon-Mediated, Regio- and Stereoselective CH Activation

(2009) Yun Xiong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Divalent Silicon(0) Compounds

(2009) Nozomi Takagi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Divalent E(0) Compounds (E=Si-Sn)

(2009) Nozomi Takagi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Unusual Bonding in Trisilaallene and Related Heavy Allenes

(2009) Mitsuo Kira et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactivity of a Zwitterionic Stable Silylene toward Halosilanes and Haloalkanes

(2009) Yun Xiong et al.   ORGANOMETALLICS

Divalent Carbon(0) Chemistry, Part 1: Parent Compounds

(2008) Ralf Tonner et al.   CHEMISTRY-A EUROPEAN JOURNAL

Divalent Carbon(0) Chemistry, Part 2: Protonation and Complexes with Main Group and Transition Metal Lewis Acids

(2008) Ralf Tonner et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Stable Silicon(0) Compound with a Si=Si Double Bond

(2008) Y. Wang et al.   SCIENCE