Tuning Redox States of Phenalenyl-Based Molecules by Consecutive Reduction toward Transition Metal-Free Heck-Type C–C Cross-Coupling

Transition‐metal‐free Matsuda‐Heck type cross‐coupling and mechanistic evidence for a radical mechanism.

(2021) Julien Bergès et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Reduced Phenalenyl in Catalytic Dehalogenative Deuteration and Hydrodehalogenation of Aryl Halides

(2021) Bhagat Singh et al.   JOURNAL OF ORGANIC CHEMISTRY

How Radical Are “Radical” Photocatalysts? A Closed-Shell Meisenheimer Complex Is Identified as a Super-Reducing Photoreagent

(2021) Adam J. Rieth et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reductive Electrophotocatalysis: Merging Electricity and Light To Achieve Extreme Reduction Potentials

(2020) Hyunwoo Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Progress in the Construction of C−N Bonds via Metal‐Free Radical C( sp 3 )−H Functionalization

(2020) Si‐Zhe Song et al.   ADVANCED SYNTHESIS & CATALYSIS

Solvent Effects on the Stability and Delocalization of Aryl Dicyanomethyl Radicals: The Captodative Effect Revisited

(2019) Joshua P. Peterson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrochemical Arylation of Electron-Deficient Arenes through Reductive Activation

(2019) Pan Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Accessing Heterobiaryls through Transition-Metal-Free C–H Functionalization

(2018) Ananya Banik et al.   JOURNAL OF ORGANIC CHEMISTRY

Integrating Organic Lewis Acid and Redox Catalysis: The Phenalenyl Cation in Dual Role

(2018) Jasimuddin Ahmed et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct synthesis of N -arylamides via the coupling of aryl diazonium tetrafluoroborates and nitriles under transition-metal-free conditions

(2018) Biquan Xiong et al.   TETRAHEDRON LETTERS

Tuning the redox non-innocence of a phenalenyl ligand toward efficient nickel-assisted catalytic hydrosilylation

(2018) Gonela Vijaykumar et al.   Chemical Science

Tuning radical reactivity for selective radical/radical cross-coupling

(2018) Shengchun Wang et al.   Science Bulletin

A new face of phenalenyl-based radicals in the transition metal-free C–H arylation of heteroarenes at room temperature: trapping the radical initiator via C–C σ-bond formation

(2017) Jasimuddin Ahmed et al.   Chemical Science

Heck Reaction—State of the Art

(2017) Sangeeta Jagtap   Catalysts

Open-Shell Phenalenyl in Transition Metal-Free Catalytic C–H Functionalization

(2016) Rupankar Paira et al.   JOURNAL OF ORGANIC CHEMISTRY

Recent Advances in the Chemistry of Phenalenyl

(2016) Kazuyuki Uchida et al.   JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN

Fluxional σ-Bonds of the 2,5,8-Trimethylphenalenyl Dimer: Direct Observation of the Sixfold σ-Bond Shift via a π-Dimer

(2016) Kazuyuki Uchida et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Switching Closed-Shell to Open-Shell Phenalenyl: Toward Designing Electroactive Materials

(2015) Anand Pariyar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electron Transfer-Induced Coupling of Haloarenes to Styrenes and 1,1-Diphenylethenes Triggered by Diketopiperazines and Potassium tert-Butoxide

(2015) Eswararao Doni et al.   MOLECULES

Room-Temperature and Transition-Metal-Free Mizoroki–Heck-type Reaction. Synthesis of E-Stilbenes by Photoinduced C–H Functionalization

(2014) Javier F. Guastavino et al.   JOURNAL OF ORGANIC CHEMISTRY

Evidence of σ- and π-Dimerization in a Series of Phenalenyls

(2014) Zhongyu Mou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reduction of aryl halides by consecutive visible light-induced electron transfer processes

(2014) I. Ghosh et al.   SCIENCE

Phenalenyl in a Different Role: Catalytic Activation through the Nonbonding Molecular Orbital

(2014) Sudipta Raha Roy et al.   ACS Catalysis

Hexamethoxyphenalenyl as a Possible Quantum Spin Simulator: An Electronically Stabilized Neutral π Radical with Novel Quantum Coherence Owing to Extremely High Nuclear Spin Degeneracy

(2013) Akira Ueda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Photoredox-Catalyzed Meerwein Addition Reaction: Intermolecular Amino-Arylation of Alkenes

(2013) Durga Prasad Hari et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Design, Synthesis, and Evaluation of Multitarget-Directed Resveratrol Derivatives for the Treatment of Alzheimer’s Disease

(2013) Chuanjun Lu et al.   JOURNAL OF MEDICINAL CHEMISTRY

Interface-engineered templates for molecular spin memory devices

(2013) Karthik V. Raman et al.   NATURE

Photocatalytic Arylation of Alkenes, Alkynes and Enones with Diazonium Salts

(2012) Peter Schroll et al.   ChemistryOpen

Mizoroki-Heck-Type Reaction Mediated by Potassium tert-Butoxide

(2011) Eiji Shirakawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Potassium tert-butoxide mediated Heck-type cyclization/isomerization–benzofurans from organocatalytic radical cross-coupling reactions

(2011) Magnus Rueping et al.   CHEMICAL COMMUNICATIONS

A new spin on bistability

(2011) Robin G. Hicks   Nature Chemistry

Synthetic organic spin chemistry for structurally well-defined open-shell graphene fragments

(2011) Yasushi Morita et al.   Nature Chemistry

Organic tailored batteries materials using stable open-shell molecules with degenerate frontier orbitals

(2011) Yasushi Morita et al.   NATURE MATERIALS

Iron-Catalyzed Mizoroki-Heck Cross-Coupling Reaction with Styrenes

(2008) Rafal Loska et al.   ADVANCED SYNTHESIS & CATALYSIS

The synthesis and structure–activity relationship of substituted N-phenyl anthranilic acid analogs as amyloid aggregation inhibitors

(2008) Lloyd J. Simons et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS