Tuning the redox non-innocence of a phenalenyl ligand toward efficient nickel-assisted catalytic hydrosilylation

A new face of phenalenyl-based radicals in the transition metal-free C–H arylation of heteroarenes at room temperature: trapping the radical initiator via C–C σ-bond formation

(2017) Jasimuddin Ahmed et al.   Chemical Science

Highly Efficient Olefin Hydrosilylation Catalyzed by Iron Complexes with Iminobipyridine Ligand

(2016) Kazumasa Hayasaka et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Mn-, Fe-, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins

(2016) Steven W. M. Crossley et al.   CHEMICAL REVIEWS

Open-Shell Phenalenyl in Transition Metal-Free Catalytic C–H Functionalization

(2016) Rupankar Paira et al.   JOURNAL OF ORGANIC CHEMISTRY

Bis(acetylacetonato)Ni(II)/NaBHEt3-catalyzed hydrosilylation of 1,3-dienes, alkenes and alkynes

(2016) Venu Srinivas et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Alkoxy Hydrosilanes As Surrogates of Gaseous Silanes for Hydrosilylation of Alkenes

(2016) Ivan Buslov et al.   ORGANIC LETTERS

Alkene Hydrosilylation Using Tertiary Silanes with α-Diimine Nickel Catalysts. Redox-Active Ligands Promote a Distinct Mechanistic Pathway from Platinum Catalysts

(2016) Iraklis Pappas et al.   ACS Catalysis

Platinum nanoparticles in suspension are as efficient as Karstedt's complex for alkene hydrosilylation

(2015) Thomas Galeandro-Diamant et al.   CHEMICAL COMMUNICATIONS

Switching Closed-Shell to Open-Shell Phenalenyl: Toward Designing Electroactive Materials

(2015) Anand Pariyar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible Substrate Activation and Catalysis at an Intact Metal–Metal Bond Using a Redox-Active Supporting Ligand

(2015) Talia J. Steiman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalysed Chemo-, Regio-, and Stereoselective Hydrosilylation of Alkenes and Alkynes using a Bench-Stable Iron(II) Pre-Catalyst

(2014) Mark D. Greenhalgh et al.   ADVANCED SYNTHESIS & CATALYSIS

Redox-Active Ligand-Induced Homolytic Bond Activation

(2014) Daniël L. J. Broere et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Titanium and zirconium complexes of the N,N′-bis(2,6-diisopropylphenyl)-1,4-diaza-butadiene ligand: syntheses, structures and uses in catalytic hydrosilylation reactions

(2014) Srinivas Anga et al.   DALTON TRANSACTIONS

Illuminating Silicon Surface Hydrosilylation: An Unexpected Plurality of Mechanisms

(2013) Jillian M. Buriak   CHEMISTRY OF MATERIALS

Surface Reaction of Acetylene with H-Terminated Silicon Surfaces. A Theoretical Study from Hybrid DFT-D2 Periodic Simulations

(2013) Javier Navarro-Ruiz et al.   Journal of Physical Chemistry C

Surface-Induced Alkene Oligomerization: Does Thermal Hydrosilylation Really Lead to Monolayer Protected Silicon Nanocrystals?

(2013) Zhenyu Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Interface-engineered templates for molecular spin memory devices

(2013) Karthik V. Raman et al.   NATURE

Substitution effect on phenalenyl backbone in the rate of organozinc catalyzed ROP of cyclic esters

(2012) Tamal K. Sen et al.   DALTON TRANSACTIONS

Cooperative & Redox Non-Innocent Ligands in Directing Organometallic Reactivity (Eur. J. Inorg. Chem. 3/2012)

(2012) Karen Hindson et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

The Shrinking World of Innocent Ligands: Conventionaland Non-Conventional Redox-Active Ligands

(2012) Wolfgang Kaim   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Catalytic Hydrosilylation of Alkenes by Iron Complexes Containing Terpyridine Derivatives as Ancillary Ligands

(2012) Kouji Kamata et al.   ORGANOMETALLICS

Iron Catalysts for Selective Anti-Markovnikov Alkene Hydrosilylation Using Tertiary Silanes

(2012) A. M. Tondreau et al.   SCIENCE

Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions

(2012) Volodymyr Lyaskovskyy et al.   ACS Catalysis

Ligands that Store and Release Electrons during Catalysis

(2011) Wojciech I. Dzik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phenalenyl-Based Molecules: Tuning the Lowest Unoccupied Molecular Orbital to Design a Catalyst

(2011) Tamal K. Sen et al.   CHEMISTRY-A EUROPEAN JOURNAL

A new spin on bistability

(2011) Robin G. Hicks   Nature Chemistry

Synthetic organic spin chemistry for structurally well-defined open-shell graphene fragments

(2011) Yasushi Morita et al.   Nature Chemistry

Redox-Active Ligand-Mediated Oxidative Addition and Reductive Elimination at Square Planar Cobalt(III): Multielectron Reactions for Cross-Coupling

(2010) Aubrey L. Smith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Radical Ligands Confer Nobility on Base-Metal Catalysts

(2010) P. J. Chirik et al.   SCIENCE

Ligand Reactivity in Diarylamido/Bis(Phosphine) PNP Complexes of Mn(CO)3and Re(CO)3

(2009) Alexander T. Radosevich et al.   INORGANIC CHEMISTRY

OLEX2: a complete structure solution, refinement and analysis program

(2009) Oleg V. Dolomanov et al.   JOURNAL OF APPLIED CRYSTALLOGRAPHY

Sequential C−Si Bond Formations from Diphenylsilane: Application to Silanediol Peptide Isostere Precursors

(2008) Lone Nielsen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Neutral Bis(α-iminopyridine)metal Complexes of the First-Row Transition Ions (Cr, Mn, Fe, Co, Ni, Zn) and Their Monocationic Analogues:  Mixed Valency Involving a Redox Noninnocent Ligand System

(2008) Connie C. Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY