Taming the Chlorine Radical: Enforcing Steric Control over Chlorine-Radical-Mediated C–H Activation

Practical and Selective sp3 C–H Bond Chlorination via Aminium Radicals

(2021) Alastair J. McMillan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthetic and Mechanistic Implications of Chlorine Photoelimination in Nickel/Photoredox C(sp3)–H Cross-Coupling

(2021) Stavros K. Kariofillis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Visible‐Light‐Induced Homolysis of Earth‐Abundant Metal‐Substrate Complexes: A Complementary Activation Strategy in Photoredox Catalysis

(2021) Youssef Abderrazak et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper Catalyzed C(sp3)–H Bond Alkylation via Photoinduced Ligand-to-Metal Charge Transfer

(2021) Sean M. Treacy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Capturing the Complete Reaction Profile of a C–H Bond Activation

(2021) David Gygi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photocatalytic C–H activation and the subtle role of chlorine radical complexation in reactivity

(2021) Qiaomu Yang et al.   SCIENCE

Iron-Catalyzed Photoinduced LMCT: A 1° C–H Abstraction Enables Skeletal Rearrangements and C(sp3)–H Alkylation

(2021) Yi Cheng Kang et al.   ACS Catalysis

Photoredox-Catalyzed C–H Functionalization Reactions

(2021) Natalie Holmberg-Douglas et al.   CHEMICAL REVIEWS

Determining the Inherent Selectivity for Carbon Radical Hydroxylation versus Halogenation with FeIII(OH)(X) Complexes: Relevance to the Rebound Step in Non-heme Iron Halogenases

(2020) Vishal Yadav et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Evidence of Visible Light-Induced Homolysis in Chlorobis(2,9-dimethyl-1,10-phenanthroline)copper(II)

(2020) Remi Fayad et al.   Journal of Physical Chemistry Letters

Halide Photoredox Chemistry

(2019) Ludovic Troian-Gautier et al.   CHEMICAL REVIEWS

Copper-Catalyzed C(sp3 )−H Amidation: Sterically Driven Primary and Secondary C−H Site-Selectivity

(2019) Abolghasem Gus Bakhoda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Alkylation and Reduction of Heteroarenes with Alcohols Using Photoredox Catalyzed Hydrogen Atom Transfer via Chlorine Atom Generation

(2019) Montserrat Zidan et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Identifying Amidyl Radicals for Intermolecular C–H Functionalizations

(2019) Matthew M. Tierney et al.   JOURNAL OF ORGANIC CHEMISTRY

Reagent-dictated site selectivity in intermolecular aliphatic C–H functionalizations using nitrogen-centered radicals

(2018) Anthony M. Carestia et al.   Chemical Science

Microtubing-Reactor-Assisted Aliphatic C−H Functionalization with HCl as a Hydrogen-Atom-Transfer Catalyst Precursor in Conjunction with an Organic Photoredox Catalyst

(2018) Hong-Ping Deng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aliphatic C—H Oxidations for Late-Stage Functionalization

(2018) M. Christina White et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective functionalization of methane, ethane, and higher alkanes by cerium photocatalysis

(2018) Anhua Hu et al.   SCIENCE

Hydrogen Atom Transfer Reactions via Photoredox Catalyzed Chlorine Atom Generation

(2018) Samantha Rohe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct C–C Bond Formation from Alkanes Using Ni-Photoredox Catalysis

(2018) Laura K. G. Ackerman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoinduced Nickel-Catalyzed Chemo- and Regioselective Hydroalkylation of Internal Alkynes with Ether and Amide α-Hetero C(sp3)–H Bonds

(2017) Hong-Ping Deng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Transformations of Alkyl C–H Bonds

(2016) Jian He et al.   CHEMICAL REVIEWS

The medicinal chemist's toolbox for late stage functionalization of drug-like molecules

(2016) Tim Cernak et al.   CHEMICAL SOCIETY REVIEWS

Site-Selective Aliphatic C–H Chlorination Using N-Chloroamides Enables a Synthesis of Chlorolissoclimide

(2016) Ryan K. Quinn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct C(sp3)–H Cross Coupling Enabled by Catalytic Generation of Chlorine Radicals

(2016) Benjamin J. Shields et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Discovery and Development of Pyridine-bis(imine) and Related Catalysts for Olefin Polymerization and Oligomerization

(2015) Brooke L. Small   ACCOUNTS OF CHEMICAL RESEARCH

Manganese Catalyzed C–H Halogenation

(2015) Wei Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Trap-Free Halogen Photoelimination from Mononuclear Ni(III) Complexes

(2015) Seung Jun Hwang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Halogen Photoelimination from Monomeric Nickel(III) Complexes Enabled by the Secondary Coordination Sphere

(2015) Seung Jun Hwang et al.   ORGANOMETALLICS

Photochemistry of copper(II) chlorocomplexes in acetonitrile: Trapping the ligand-to-metal charge transfer excited state relaxations pathways

(2014) Andrey S. Mereshchenko et al.   CHEMICAL PHYSICS LETTERS

Oxidative Aliphatic C-H Fluorination with Fluoride Ion Catalyzed by a Manganese Porphyrin

(2012) W. Liu et al.   SCIENCE

Adding Aliphatic C-H Bond Oxidations to Synthesis

(2012) M. C. White   SCIENCE

C−H Bond Activations by Metal Oxo Compounds

(2010) Ahmet Gunay et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Manganese Porphyrins Catalyze Selective C−H Bond Halogenations

(2010) Wei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation

(2010) M. S. Chen et al.   SCIENCE