Copper Catalyzed C(sp3)–H Bond Alkylation via Photoinduced Ligand-to-Metal Charge Transfer

Cerium-Catalyzed C–H Functionalizations of Alkanes Utilizing Alcohols as Hydrogen Atom Transfer Agents

(2020) Qing An et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C(sp3)–H functionalizations of light hydrocarbons using decatungstate photocatalysis in flow

(2020) Gabriele Laudadio et al.   SCIENCE

Visible‐Light‐Induced Vicinal Dichlorination of Alkenes through LMCT Excitation of CuCl2

(2020) Xiaobing Wan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible Light Uranyl Photocatalysis: Direct C–H to C–C Bond Conversion

(2019) Luca Capaldo et al.   ACS Catalysis

Synergistic Photoredox/Transition-Metal Catalysis for Carbon-Carbon Bond Formation Reactions

(2019) Maxime De Abreu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Activation and Deactivation Strategies Promoted by Medium Effects for Selective Aliphatic C-H Bond Functionalization

(2018) Massimo Bietti   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sulfonamides as new hydrogen atom transfer (HAT) catalysts for photoredox allylic and benzylic C–H arylations

(2018) Hirotaka Tanaka et al.   CHEMICAL COMMUNICATIONS

A General Strategy for Aliphatic C–H Functionalization Enabled by Organic Photoredox Catalysis

(2018) Kaila A. Margrey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

δ-Selective Functionalization of Alkanols Enabled by Visible-Light-Induced Ligand-to-Metal Charge Transfer

(2018) Anhua Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Modular radical cross-coupling with sulfones enables access to sp3-rich (fluoro)alkylated scaffolds

(2018) Rohan R. Merchant et al.   SCIENCE

Microtubing-Reactor-Assisted Aliphatic C−H Functionalization with HCl as a Hydrogen-Atom-Transfer Catalyst Precursor in Conjunction with an Organic Photoredox Catalyst

(2018) Hong-Ping Deng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

sp3 C–H Arylation and Alkylation Enabled by the Synergy of Triplet Excited Ketones and Nickel Catalysts

(2018) Yangyang Shen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct arylation of strong aliphatic C–H bonds

(2018) Ian B. Perry et al.   NATURE

Catalytic dehydrogenative decarboxyolefination of carboxylic acids

(2018) Xiang Sun et al.   Nature Chemistry

Selective functionalization of methane, ethane, and higher alkanes by cerium photocatalysis

(2018) Anhua Hu et al.   SCIENCE

Hydrogen Atom Transfer Reactions via Photoredox Catalyzed Chlorine Atom Generation

(2018) Samantha Rohe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct C–C Bond Formation from Alkanes Using Ni-Photoredox Catalysis

(2018) Laura K. G. Ackerman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoinduced Ligand-to-Metal Charge Transfer Enables Photocatalyst-Independent Light-Gated Activation of Co(II)

(2018) Benjamin D. Ravetz et al.   ACS Catalysis

Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis

(2017) Luca Capaldo et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Photoinduced Nickel-Catalyzed Chemo- and Regioselective Hydroalkylation of Internal Alkynes with Ether and Amide α-Hetero C(sp3)–H Bonds

(2017) Hong-Ping Deng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Directed γ-C(sp3)–H Alkylation of Carboxylic Acid Derivatives through Visible Light Photoredox Catalysis

(2017) Dian-Feng Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective sp3 C–H alkylation via polarity-match-based cross-coupling

(2017) Chip Le et al.   NATURE

The merger of transition metal and photocatalysis

(2017) Jack Twilton et al.   Nature Reviews Chemistry

Organic Photoredox Catalysis

(2016) Nathan A. Romero et al.   CHEMICAL REVIEWS

Expanding the Potential of Heteroaryl Vinyl Sulfones

(2016) Eduardo Rodrigo et al.   JOURNAL OF ORGANIC CHEMISTRY

Visible-Light-Promoted Activation of Unactivated C(sp3)–H Bonds and Their Selective Trifluoromethylthiolation

(2016) Satobhisha Mukherjee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct C(sp3)–H Cross Coupling Enabled by Catalytic Generation of Chlorine Radicals

(2016) Benjamin J. Shields et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Amide-directed photoredox-catalysed C–C bond formation at unactivated sp3 C–H bonds

(2016) John C. K. Chu et al.   NATURE

Metallaphotoredox-catalysed sp3–sp3 cross-coupling of carboxylic acids with alkyl halides

(2016) Craig P. Johnston et al.   NATURE

Catalytic alkylation of remote C–H bonds enabled by proton-coupled electron transfer

(2016) Gilbert J. Choi et al.   NATURE

Asymmetric copper-catalyzed C-N cross-couplings induced by visible light

(2016) Q. M. Kainz et al.   SCIENCE

Undirected, Homogeneous C–H Bond Functionalization: Challenges and Opportunities

(2016) John F. Hartwig et al.   ACS Central Science

Getting Down to Earth: The Renaissance of Catalysis with Abundant Metals

(2015) Paul Chirik et al.   ACCOUNTS OF CHEMICAL RESEARCH

Photocatalytic CH Activation by Hydrogen-Atom Transfer in Synthesis

(2015) Stefano Protti et al.   ChemCatChem

Hydrodecarboxylation of Carboxylic and Malonic Acid Derivatives via Organic Photoredox Catalysis: Substrate Scope and Mechanistic Insight

(2015) Jeremy D. Griffin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The direct arylation of allylic sp3 C–H bonds via organic and photoredox catalysis

(2015) James D. Cuthbertson et al.   NATURE

O-H hydrogen bonding promotes H-atom transfer from   C-H bonds for C-alkylation of alcohols

(2015) J. L. Jeffrey et al.   SCIENCE

Experimental and Calculated Electrochemical Potentials of Common Organic Molecules for Applications to Single-Electron Redox Chemistry

(2015) David Nicewicz et al.   SYNLETT

Photochemistry of copper(II) chlorocomplexes in acetonitrile: Trapping the ligand-to-metal charge transfer excited state relaxations pathways

(2014) Andrey S. Mereshchenko et al.   CHEMICAL PHYSICS LETTERS

Site-Selective Aliphatic C–H Bromination Using N-Bromoamides and Visible Light

(2014) Valerie A. Schmidt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoinduced, Copper-Catalyzed Alkylation of Amides with Unactivated Secondary Alkyl Halides at Room Temperature

(2014) Hien-Quang Do et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carboxylic Acids as A Traceless Activation Group for Conjugate Additions: A Three-Step Synthesis of (±)-Pregabalin

(2014) Lingling Chu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis

(2014) J. C. Tellis et al.   SCIENCE

Merging photoredox with nickel catalysis: Coupling of  -carboxyl sp3-carbons with aryl halides

(2014) Z. Zuo et al.   SCIENCE

Sunlight photocatalyzed regioselective β-alkylation and acylation of cyclopentanones

(2014) Megumi Okada et al.   Chemical Science

Decatungstate Photocatalyzed Benzylation of Alkenes with Alkylaromatics

(2013) Hisham Qrareya et al.   ADVANCED SYNTHESIS & CATALYSIS

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

Mechanism and Selectivity in Nickel-Catalyzed Cross-Electrophile Coupling of Aryl Halides with Alkyl Halides

(2013) Soumik Biswas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxygenation and chlorination of aromatic hydrocarbons with hydrochloric acid photosensitized by 9-mesityl-10-methylacridinium under visible light irradiation

(2012) Kei Ohkubo et al.   RESEARCH ON CHEMICAL INTERMEDIATES

If CH Bonds Could Talk: Selective CH Bond Oxidation

(2011) Timothy Newhouse et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free oxygenation of cyclohexane with oxygen catalyzed by 9-mesityl-10-methylacridinium and hydrogen chloride under visible light irradiation

(2011) Kei Ohkubo et al.   CHEMICAL COMMUNICATIONS

Enantioselective organocatalytic formal allylation of α-branched aldehydes

(2011) Eduardo Rodrigo et al.   CHEMICAL COMMUNICATIONS

Understanding Hydrogen Atom Transfer: From Bond Strengths to Marcus Theory

(2010) James M. Mayer   ACCOUNTS OF CHEMICAL RESEARCH

Visible light photoredox catalysis: applications in organic synthesis

(2010) Jagan M. R. Narayanam et al.   CHEMICAL SOCIETY REVIEWS

Mechanistic Manifold and New Developments of the Julia-Kocienski Reaction

(2009) Christophe Aïssa   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY