Review
Chemistry, Applied
Shutao Li, Yihe Zhang, Hongwei Huang
Summary: This review introduces the development and applications of black phosphorus (BP)-based heterostructures. BP exhibits excellent physical and chemical properties, making it suitable for photocatalytic and photoelectrochemical reactions. Different dimensions of BP can be used to prepare various types of heterostructures, which are widely used in water splitting, CO2 reduction, pollutant degradation, and other fields. However, further development of BP-based heterostructures faces challenges and opportunities.
JOURNAL OF ENERGY CHEMISTRY
(2022)
Article
Nanoscience & Nanotechnology
Byung Keun Kim, Myung Jun Kim, Jae Jeong Kim
Summary: This study found that increasing the hydrophilicity of the electrocatalyst surface helps reduce the size of gas bubbles and shorten their duration, promoting the hydrogen evolution reaction and lowering the overpotential at a given current density.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Materials Science, Multidisciplinary
Yuanmei Xu, Xiaoqin Zhang, Zhihong Chen, Krzysztof Kempa, Xin Wang, Lingling Shui
Summary: The amorphous molybdenum sulphide layer composed of black phosphorus and molybdenum sulphide significantly enhances the performance of photoelectrochemical water splitting on the bismuth vanadate film; inserting a layer of black phosphorus between molybdenum sulphide and bismuth vanadate can improve the photoelectrochemical performance and stability of the electrodes; the molybdenum sulphide/black phosphorus/bismuth vanadate electrode exhibits excellent current density, twice as high as that of the pure bismuth vanadate electrode.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2021)
Article
Chemistry, Multidisciplinary
Menglong Wang, Shuai Xu, Zhaohui Zhou, Chung-Li Dong, Xu Guo, Jeng-Lung Chen, Yu-Cheng Huang, Shaohua Shen, Yubin Chen, Liejin Guo, Clemens Burda
Summary: Single-atom nickel catalysts prepared on red phosphorus using a reactive-group guided strategy exhibit elevated hydrogen evolution rate under visible-light irradiation due to their specific Janus structure.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Multidisciplinary Sciences
Yukun Zhao, Mengyu Duan, Chaoyuan Deng, Jie Yang, Sipeng Yang, Yuchao Zhang, Hua Sheng, Youji Li, Chuncheng Chen, Jincai Zhao
Summary: In this study, a photoelectrochemical Br-/BrO- mediated system on alpha-Fe2O3 is developed for efficient epoxidation reactions. The system achieves high selectivity (>99%) and faradaic efficiency (82% +/- 4%) for a wide range of alkenes, surpassing the reported electrochemical and photoelectrochemical methods.
NATURE COMMUNICATIONS
(2023)
Article
Materials Science, Multidisciplinary
Yao Liu, Ning Jiang, Mingjie Lyu, Jinwei Wei, Gongxiang Wei, Xin Han, Qiaoyan Shang, Qian Zhang, Yunyan Liu, Huiqiang Liu, Xifeng Shi
Summary: By assembling black phosphorus nanosheets on the surface of TiO2 nanorods arrays through electrostatic attraction, TiO2/BP heterojunction material was formed. Meanwhile, Ag nanoparticles were loaded on the material's surface to create Ag nanoparticles modified TiO2/BP heterojunction composite material. The modified heterojunction exhibited remarkable enhancement in photoelectrochemical water splitting compared to pristine TiO2.
MATERIALS CHEMISTRY AND PHYSICS
(2023)
Review
Chemistry, Physical
Mohsin Ali Marwat, Muhammad Humayun, Muhammad Waqas Afridi, Haibo Zhang, Muhammad Ramzan Abdul Karim, Malik Ashtar, Muhammad Usman, Saad Waqar, Habib Ullah, Chundong Wang, Wei Luo
Summary: This review provides a detailed explanation of the basic mechanism of PEC water splitting using electrocatalysts, and highlights recent advancements in the design, fabrication, and modification of high-efficiency electrocatalysts for energy conversion.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Chemistry, Physical
Renzheng Jiang, Danqi Zhao, Huaning Fan, Yingpeng Xie, Mengjiang Li, Hu Lin, Zhong-Shuai Wu
Summary: The study presents a three-dimensional phosphorus-doped nickel molybdate/nickel molybdate hydrate @phosphates core-shell nanorod clusters on nickel foam self-supported electrode, demonstrating high activity for hydrogen and oxygen evolution reactions and excellent durability.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Review
Energy & Fuels
Jun Zhang, Tao Li, Jili Zheng, Yanqiu Xiao, Xiaotian Li, Jun Song, Chuanxiao Cheng, Wei Yang, Gang Chen
Summary: This article discusses the principles of photoelectrochemical water splitting and the development of hole transport layers, emphasizing the importance of photogenerated carriers and holes. It concludes with future strategies for improving the hole transport layer.
Article
Chemistry, Physical
Xiaodong Wang, Xiaoqing Liu, Yu Wu, Yaling Fu, Huijuan Zhang, Miao Zhou, Yu Wang
Summary: Researchers have reported the synthesis of the thinnest SnS homojunction regulated by Sb doping and Sn vacancies. This structure enhances the separation and transport efficiency of carriers and shows superior photoelectrochemical water splitting performance.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2023)
Article
Chemistry, Multidisciplinary
Lei Chen, Jin-Tao Ren, Zhong-Yong Yuan
Summary: The review focuses on the recent progress of P-containing catalysts in water splitting and their design strategies to enhance catalytic activity. It delves into the theory-structure-property relationship and discusses research directions and challenges in the field.
Article
Chemistry, Multidisciplinary
Tianying Liu, Wei Li, David Z. Wang, Tongtong Luo, Muchun Fei, Dongyoon Shin, Matthias M. Waegele, Dunwei Wang
Summary: Solar water oxidation is a crucial step in artificial photosynthesis, and its success relies on the accumulation of charges at the active site. Little is known about the impact of catalyst density on the reaction rate. This study investigates the interplay between catalyst density and surface hole concentration and reveals the unexpected benefits of low-density catalyst loading in facilitating forward charge transfer.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Physical
Gihun Jung, Choongman Moon, Filipe Martinho, Yonghoon Jung, Jinwoo Chu, Hyewon Park, Alireza Hajijafarassar, Rasmus Nielsen, Jorgen Schou, Jeongyoung Park, Peter Christian Kjaergaard Vesborg, Ole Hansen, Yunseog Lee, Stela Canulescu, Byungha Shin
Summary: A photoelectrochemical water splitting device based on a dual-junction monolithic tandem cell with high performance was developed. The device achieved the highest photocurrent density and solar-to-hydrogen conversion efficiency among dual-junction monolithic photoelectrochemical cells, except for III-V materials. The use of TOPCon Si, TTO and SnO2 in the device contributed to its stability and high efficiency.
ADVANCED ENERGY MATERIALS
(2023)
Article
Chemistry, Physical
Lei Jin, Haiguang Zhao, Zhiming M. Wang, Federico Rosei
Summary: This article summarizes the latest progress in tailoring the materials, structure, and performance of QDs-based PEC H-2 generation, and discusses the impact of specific features of QDs and charge generation and transfer on the performance of PEC devices. Future challenges and opportunities for high-efficiency and stable QDs-based PEC applications are also discussed.
ADVANCED ENERGY MATERIALS
(2021)
Review
Chemistry, Multidisciplinary
Runyu Chen, Linxing Meng, Weiwei Xu, Liang Li
Summary: Sluggish oxygen evolution reactions on photoanode surfaces significantly limit the utilization of photoelectrochemical (PEC) water splitting. Loading cocatalysts onto photoanodes has been recognized as the simplest and most efficient optimization strategy, which can decrease the surface barrier, provide more active sites, and enhance the surface catalytic reaction kinetics. However, the introduction of cocatalysts inevitably creates interfaces between photoanodes and oxygen evolution cocatalysts (Ph/OEC), resulting in severe interfacial recombination and hindered charge transfer.
Letter
Anesthesiology
Chia-Yu Lin, Mei-Chun Chen, Kuang-I Cheng, Zhi-Fu Wu
MINERVA ANESTESIOLOGICA
(2022)
Article
Nanoscience & Nanotechnology
Yi-Ching Wang, Jia-Hui Yen, Chi-Wei Huang, Tzu-En Chang, You-Liang Chen, Yu-Hsiu Chen, Chia-Yu Lin, Chung-Wei Kung
Summary: This study demonstrates the successful use of nanoporous and electrically conductive MOF-derived materials as electrocatalysts for the electrochemical conversion of AN to ADN. The synthesized MOF-derived materials composed of Pb, PbO, and carbon exhibit high electrical conductivity and electrochemically active surface area. Electrolytic experiments show that the optimal MOF-derived electrocatalyst can significantly reduce the overpotential required for the production of ADN, achieving a high Faradaic efficiency. These findings highlight the potential of advanced electrocatalysts in enhancing the electrosynthesis of ADN.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Electrochemistry
Tzu-Hsuan Wang, Chia-Yu Lin, Yu-Cheng Huang, Chia-Ying Li
Summary: In this work, a facile and scalable electrosynthetic approach was developed to prepare core-shell-structured polyaniline|gold nanoparticles nanofiber (nanoPANI|Au) as an efficient electrocatalyst for electrochemical CO2 reduction (e-CO2RR). Under optimal conditions, the prepared nanoPANI|Au exhibited high turnover frequency of 0.40 s-1 and CO-mass activity of 5.67 A g-1 with satisfactory selectivity (Faradaic efficiency: 70.0 +/- 2.1%) for CO generation in 0.1M NaHCO3 at a moderate over-potential of 0.59 V. This work opens a new avenue for the preparation of core-shell-structured conducting polymer|metal nanoparticles as electrocatalysts for e-CO2RR.
ELECTROCHIMICA ACTA
(2023)
Article
Cardiac & Cardiovascular Systems
Yu-Tsung Shih, Shu-Yi Wei, Jin-Hua Chen, Wei-Li Wang, Hsin-Yi Wu, Mei-Cun Wang, Chia-Yu Lin, Pei-Lin Lee, Chih-Yuan Lin, Hung-Che Chiang, Yu-Ju Chen, Shu Chien, Jeng-Jiann Chiu
Summary: This study reveals the regulation of vascular endothelial phosphoproteins induced by disturbed flow and their contribution to atherogenesis. The phosphorylation of vinculin at serine 721 induced by disturbed flow promotes endothelial permeability and atherosclerosis. The level of endothelial VCLS721p is a clinicopathological biomarker for atherosclerosis progression.
EUROPEAN HEART JOURNAL
(2023)
Article
Polymer Science
Ping-Jui Yu, Yan-Cheng Lin, Chia-Yu Lin, Wen-Chang Chen
Summary: Diverse approaches have been presented to synthesize intrinsically stretchable conjugated polymers, but compromise in charge carrier mobility is often observed. This study engineered polythiophenes with flexible or rigid backbones and different side chains to improve their mechanical tolerance and amorphous content. The best mobility-stretchability properties were observed in polythiophene with a quaterthiophene backbone and thienyl-ester-substituted side chains. The jointed design of biaxial extension and ester functional groups proved to be efficacious in improving the mobility-stretchability properties of polythiophenes.
Article
Polymer Science
Chih-Yuan Sung, Chia-Yu Lin, Chu-Chen Chueh, Yan-Cheng Lin, Wen-Chang Chen
Summary: Until now, the study of the mobility-stretchability of semiconducting polymers has received extensive attention, but little focus has been placed on their morphology and field-effect transistor characteristics under compressive strains, which are equally important in wearable electronic applications. This research applies a contact film transfer method to evaluate the mobility-compressibility properties of conjugated polymers. Various isoindigo-bithiophene conjugated polymers with different side chains are investigated, and it is found that P(SiO-Si) outperforms other symmetric polymers in dissipating strain and enhancing mechanical durability. The contact film transfer technique is also demonstrated to be applicable for studying the compressibility of different semiconducting polymers. These results provide a comprehensive understanding of the mobility-compressibility properties of semiconducting polymers under tensile and compressive strains.
MACROMOLECULAR RAPID COMMUNICATIONS
(2023)
Article
Polymer Science
Megumi Matsuda, Chia -Yu Lin, Kazushi Enomoto, Yan-Cheng Lin, Wen-Chang Chen, Tomoya Higashihara
Summary: In this study, the development of stretchable semiconducting polymers through statistical terpolymerization with conjugation break spacers (CBSs) was investigated. The inclusion of thioether units into naphthalenediimide (NDI)-based semiconducting polymers was found to significantly affect their semiconductivity and stretchability, compared to alkyl- and ether-based CBSs.
Article
Multidisciplinary Sciences
Fu-Xiang Rikudo Chen, Chia-Yu Lin, Hui-Ying Siao, Cheng-Yuan Jian, Yong-Cheng Yang, Chun-Liang Lin
Summary: In this study, a deep learning-based atomic defect detection framework (DL-ADD) is proposed to efficiently detect atomic defects in molybdenum disulfide (MoS2) and generalize the model for defect detection in other TMD materials.
Article
Health Care Sciences & Services
Yi-Huei Chang, Szu-Ying Pan, Chia-Yu Lin, Chi-Ping Huang, Chi-Jung Chung, Yung-Hsiang Chen, Wen-Chi Chen
Summary: Prostate abscess (PA) is a potentially life-threatening condition that requires prompt treatment. However, the declining incidence of PA in developing countries and high-risk patients can hinder early diagnosis. This study aimed to review the etiology, pathophysiology, diagnosis, and treatment options for PA, as well as analyze the characteristics and clinical course of patients. The findings can guide the development of a personalized treatment strategy for patients with PA.
JOURNAL OF PERSONALIZED MEDICINE
(2023)
Article
Health Care Sciences & Services
Chia-Hui Chen, Chia-Yu Lin, Chiao-Ling Chen, Kuan-Ting Chen, Cho Lee, Ya-Hsin Yu, Chiao-Yu Shih
Summary: This study investigated the effectiveness of regular physical exercise-based swallowing intervention for reducing coughing and choking in older adults with dementia. The findings suggest that such intervention can effectively alleviate coughing and choking problems and its effectiveness is long-lasting. However, individuals with more advanced age and higher dementia levels may experience shorter-term effectiveness from the intervention.
Article
Chemistry, Physical
Yun-Ju Liao, Shih-Ching Huang, Chia-Yu Lin
Summary: This study explores the electrosynthesis of 6-hydroxyhexanoic acid and adipic acid from the electrochemical oxidation of hexanediol at a nanoporous nickel oxyhydroxide modified electrode as an environmentally-friendly alternative to their fossil fuel-based industrial syntheses. The effects of electrolysis conditions on faradaic efficiency and product distribution were examined, and a scale-up electrosynthesis using a flow-type electrolyzer was demonstrated.
FARADAY DISCUSSIONS
(2023)
Article
Education & Educational Research
Hui-Tzu Chang, Chia-Yu Lin, Wei-Bin Jheng, Shih-Hsu Chen, Hsien-Hua Wu, Fang-Ching Tseng, Li-Chun Wang
Summary: The research aims to develop a personalized hybrid course recommendation system (PHCRS) based on human-centered AI in education, which assists students in selecting courses from different departments. The system integrates three recommendation methods, item-based, user-based, and content-based filtering, and optimizes the parameter weights using a genetic algorithm to improve prediction accuracy. The study collects course syllabi, tags courses from twelve departments, and trains the recommendation model using course tags, student records, and grades. Experimental results on 1490 courses selected by 5662 students show that item-based filtering has a higher influence on course recommendations. A genetic algorithm successfully finds the optimal solution and parameter settings. A questionnaire survey with 61 undergraduate students reveals that 83.60% of them are more interested in courses recommended at the top of the list, indicating autonomous motivation across the hybrid recommendation method. In conclusion, PHCRS can benefit all students by tuning optimal weights for course selection factors in each department, providing the best course combinations for reference.
EDUCATIONAL TECHNOLOGY & SOCIETY
(2023)
Article
Computer Science, Information Systems
YungYu Zhuang, Jui-Hsiang Kao, Kuan-Shang Liu, Chia-Yu Lin
Summary: This article proposes a method for customizing a user-defined domain-specific visual language (DSVL) to represent different experimental workflows and follows Dijkstra's sequencing discipline to develop a proof-of-concept framework. A comparison with existing visual frameworks demonstrates its advantages in experimental program construction.
JOURNAL OF INFORMATION SCIENCE AND ENGINEERING
(2022)
Proceedings Paper
Computer Science, Information Systems
Josh Jia-Ching Ying, Wan-Ju Yang, Ji Zhang, Yu-Ching Ni, Chia-Yu Lin, Fan-Pin Tseng, Xiaohui Tao
Summary: This paper presents a method using principal component analysis combined with biomedical image segmentation convolutional neural network to extract major feature weights in image data and remove unwanted features, thus improving disease classification accuracy.
ADVANCED DATA MINING AND APPLICATIONS (ADMA 2022), PT I
(2022)
Article
Sport Sciences
Carol A. DeMatteo, Josephine Jakubowski, Sarah Randall, Kathy Stazyk, Chia-Yu Lin, Rebecca Yakubov
Summary: This study aimed to identify school problems and levels of cognitive activity in youths aged 5-18 years with a concussion during the recovery stages of return to school (RTS). The study found that 50% of youth experienced school problems at the First Visit Post-injury, whereas only 18% reported school problems at the Follow-Up Visit. There is a significant difference in the perception of school problems reported by youth and their parents at different stages of recovery. The amount and complexity of cognitive activity increased with decreasing symptoms and increasing RTS stage.
FRONTIERS IN SPORTS AND ACTIVE LIVING
(2022)
Article
Chemistry, Physical
Bolun Yu, Denan Li, Qianqian Zhu, Shufan Yao, Lifeng Zhang, Yanshuo Li, Zhenxin Zhang
Summary: This study successfully improved the catalytic activity of a zeolitic octahedral metal oxide by incorporating a single zinc species into its micropore. The zinc incorporation achieved a high ethane conversion rate and ethylene selectivity. Mechanism study showed that the isolated zinc site played a crucial role in activating oxygen and ethane, as well as stabilizing intermediates and transition states.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Ruoqi Liu, Hao Fei, Jian Wang, Ting Guo, Fangyang Liu, Zhuangzhi Wu, Dezhi Wang
Summary: This work successfully synthesized a high-performing S-enriched MoS2 catalyst for electrocatalytic nitrogen reduction reaction (NRR), demonstrating high activity and selectivity. The synergistic effect of the 1T phase and bridging S22- species was shown to play a positive role in NRR performances, and DFT calculations revealed the mechanism behind the improved performance.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Pan Xia, Lele Zhao, Xi Chen, Zhihong Ye, Zhihong Zheng, Qiang He, Ignasi Sires
Summary: This study presents a modified gas-diffusion electrode (GDE) for highly efficient and stable H2O2 electrosynthesis by using trace polymethylhydrosiloxane (PMHS). DFT calculations provide an in-depth understanding of the roles of PMHS functional groups.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Kwangchol Ri, Songsik Pak, Dunyu Sun, Qiang Zhong, Shaogui Yang, Songil Sin, Leliang Wu, Yue Sun, Hui Cao, Chunxiao Han, Chenmin Xu, Yazi Liu, Huan He, Shiyin Li, Cheng Sun
Summary: Different B-doped rGO catalysts were synthesized and their 2e- oxygen reduction reaction (ORR) performance was investigated. It was found that the 2e- ORR selectivity of B-doped rGO was influenced by the B content and oxygen mass transfer conditions. The synthesized catalyst exhibited high 2e- ORR selectivity and was capable of degrading organic pollutants continuously.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Li Lv, Lin Lei, Qi-Wen Chen, Cheng-Li Yin, Huiqing Fan, Jian-Ping Zhou
Summary: Monoclinic phase La2Ti2O7 and orthorhombic phase Bi4Ti3O12 are widely used in photocatalysis due to their layered crystal structure. The electronic structures of these phases play a crucial role in their photocatalytic activity. Heat treatment in a nitrogen atmosphere introduces more oxygen vacancies into the S-scheme heterojunction, leading to enhanced NO removal efficiency.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Choe Earn Choong, Minhee Kim, Jun Sup Lim, Young June Hong, Geon Joon Lee, Keun Hwa Chae, In Wook Nah, Yeomin Yoon, Eun Ha Choi, Min Jang
Summary: In this study, the synergistic effect between argon-plasma-system (AP) and catalysts in promoting the production of reactive species for water remediation was investigated. By altering the oxygen vacancies concentration of CeO2/Bi2O3 catalyst, the production of hydrated electrons was stimulated for PFOA removal. The results showed that the built-in electric field in the Bi/Ce0.43 interface enhanced electron migration and eaq- generation, leading to improved PFOA removal efficiency.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Yushan Wu, Di Xu, Yanfei Xu, Xin Tian, Mingyue Ding
Summary: Efficient synthesis of primary amines from carbonyl compounds was achieved via reductive amination using Ru@NC-Al2O3 as a catalyst, exhibiting high activity and selectivity under mild conditions.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Yilan Jiang, Peifang Wang, Tingyue Chen, Keyi Gao, Yiran Xiong, Yin Lu, Dionysios D. Dionysiou, Dawei Wang
Summary: By controlling the content of Co and Ni in Co1-xNixFe2O4, the production of O-1(2) from H2O2 can be regulated. NiFe2O4, with the lowest lattice distortion degree, can efficiently produce O-1(2) as the dominant reactive oxygen species. The system also exhibits significant resistance to water matrix interference.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Shuai Feng, Donglian Li, Hao Dong, Song Xie, Yaping Miao, Xuming Zhang, Biao Gao, Paul K. Chu, Xiang Peng
Summary: In this study, MoO2/Mo2N heterostructures were prepared by regulating the coordination of Mo atoms. The electrocatalyst exhibits high current density and excellent stability for hydrogen evolution reaction.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Jia-Cheng E. Yang, Min -Ping Zhu, Daqin Guan, Baoling Yuan, Darren Delai Sun, Chenghua Sun, Ming-Lai Fu
Summary: This study successfully modulated the electron configuration and spin state of millimetric metal catalysts by adjusting the support curvature radius. The electronic structure-oriented spin catalysis was found to affect the degradation of pollutants, providing new insights for the design and production of highly active, reusable, and stable catalysts.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Tao Zhong, Su Tang, Wenbin Huang, Wei Liu, Huinan Zhao, Lingling Hu, Shuanghong Tian, Chun He
Summary: In this study, a highly efficient photocatalyst for the elimination of CH3SH was developed by engineering different crystal facets and coupling them with PHI. Cu (111)/PHI exhibited the highest elimination efficiency and showed good stability and reusability. The enhanced surface electron pump effect and effective adsorption mechanisms were revealed through comprehensive characterizations and DFT calculations.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Feifei Yang, Tianyu Zhang, Jiankang Zhao, Wei Zhou, Nicole J. Libretto, Jeffrey T. Miller
Summary: A Ni3Sn intermetallic nano particle was found to have geometrically isolated Ni sites that could selectively cleave C-O bonds in biomass derivatives. This nano particle showed high activity and selectivity towards 2-methylfuran, unlike Ni nanoparticles that produced other unwanted products derived from the aromatic rings.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Lulu Qiao, Di Liu, Anquan Zhu, Jinxian Feng, Pengfei Zhou, Chunfa Liu, Kar Wei Ng, Hui Pan
Summary: This study reveals that surface evolution plays a crucial role in enhancing the electrocatalytic performance of transition metal oxides for electrochemical nitrate reduction reaction (e-NO3RR). Incorporating nickel into Co3O4 can promote surface reconstruction and improve the adsorption of intermediates and reduce energy barriers, leading to enhanced catalytic performance. The reconstructed cobalt-nickel hydroxides (CoyNi1_y(OH)2) on the catalyst's surface serve as the active phase.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Xinyu Song, Yang Shi, Zelin Wu, Bingkun Huang, Xinhao Wang, Heng Zhang, Peng Zhou, Wen Liu, Zhicheng Pan, Zhaokun Xiong, Bo Lai
Summary: This study explores the discriminative activities and mechanisms for activation of O-O bond in peroxy compounds via single-atom catalysts (SACs) with higher coordination numbers (M-N5). The atomic catalyst (Fe-SAC) with Fe-N5 as the active center was constructed, effectively activating peroxymonosulfate (PMS), peroxydisulfate (PDS), and hydrogen peroxide (H2O2). The study demonstrates the degradation efficiencies of acyclovir are related to the O-O bond length in different peroxy compounds, and reveals the discriminative mechanisms for activation of O-O bond in different Fenton-like systems.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Yangzhuo He, Hong Qin, Ziwei Wang, Han Wang, Yuan Zhu, Chengyun Zhou, Ying Zeng, Yicheng Li, Piao Xu, Guangming Zeng
Summary: A dual-metal-organic framework (MOF) assisted strategy was proposed to construct a magnetic Fe-Mn oxycarbide anchored on N-doped carbon for peroxymonosulfate (PMS) activation. The FeMn@NC-800 catalyst exhibited superior activity with almost 100% degradation of sulfamethazine (SMZ) in 30 minutes. The study provided insights for the rational design of high-performance heterogeneous catalysts and proposed a novel nonradical-based catalytic oxidation for environmental cleaning.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)