4.7 Article

Chemical vapor deposition of amorphous molybdenum sulphide on black phosphorus for photoelectrochemical water splitting

期刊

出版社

JOURNAL MATER SCI TECHNOL
DOI: 10.1016/j.jmst.2020.07.010

关键词

Amorphous; Molybdenum sulphide; Black phosphorus; Photoanode; Water splitting

资金

  1. National Natural Science Foundation of China Program [51602111]
  2. Guangdong Provincial Grant [2017A010104013]
  3. Special Fund Project of Science and Technology Application in Guangdong [2017B020240002]
  4. Guangdong Provincial Key Laboratory of Optical Information Materials and Technology [2017B030301007]
  5. Guangdong Innovative Research Team Program [2016ZT06C517]
  6. Science and Technology Program of Guangzhou [2019050001]

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The amorphous molybdenum sulphide layer composed of black phosphorus and molybdenum sulphide significantly enhances the performance of photoelectrochemical water splitting on the bismuth vanadate film; inserting a layer of black phosphorus between molybdenum sulphide and bismuth vanadate can improve the photoelectrochemical performance and stability of the electrodes; the molybdenum sulphide/black phosphorus/bismuth vanadate electrode exhibits excellent current density, twice as high as that of the pure bismuth vanadate electrode.
Non-precious metal electrocatalyst molybdenum sulphide (MoS) and black phosphorus (BP) are highly promising catalysts for H-2 evolution reaction (HER). However, BP is environmentally unstable and the basal planes of crystal MoS2 are inactive toward HER. Herein, amorphous molybdenum sulphide (MoSx) directly on BP/BiVO4 film dramatically improves the performance of photoelectrochemical water splitting compared with pure BiVO4. Additionally, we demonstrate that a BP layer, inserted between the MoSx and BiVO4, can enhance the photoelectrochemical performance and improve the stability of the electrodes. Finally, MoSx/BP/BVO electrode shows the excellent current density of 2.1 mA/cm(2) at the potential of 1.2 V (vs Ag/AgCl), which is twice higher than that of pure BVO electrode. Our novel nanostructure materials will lead to a new class of non-precious metal photocatalysts for hydrogen production. (C) 2021 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

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