Bromo Radical‐Mediated Photoredox Aldehyde Decarbonylation towards Transition‐Metal‐Free Hydroalkylation of Acrylamides at Room Temperature

Photocatalytic Giese‐type reaction using alkylsilicates bearing C,O‐bidentate ligands

(2021) Tatsuya Morofuji et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chiral Alkyl Amine Synthesis via Catalytic Enantioselective Hydroalkylation of Enecarbamates

(2021) Deyun Qian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Advances in Photoredox‐Mediated Radical Conjugate Addition Reactions: An Expanding Toolkit for the Giese Reaction

(2021) Anastasia L. Gant Kanegusuku et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper Catalyzed C(sp3)–H Bond Alkylation via Photoinduced Ligand-to-Metal Charge Transfer

(2021) Sean M. Treacy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reductive Radical Conjugate Addition of Alkyl Electrophiles Catalyzed by a Cobalt/Iridium Photoredox System

(2021) Randolph A. Escobar et al.   ORGANIC LETTERS

Visible-Light-Mediated C–I Difluoroallylation with an α-Aminoalkyl Radical as a Mediator

(2021) Fuyang Yue et al.   ORGANIC LETTERS

Catalytic Asymmetric Hydroalkylation of α,β-Unsaturated Amides Enabled by Regio-Reversed and Enantiodifferentiating syn-Hydronickellation

(2021) Fang Zhou et al.   ACS Catalysis

Cerium-Catalyzed C–H Functionalizations of Alkanes Utilizing Alcohols as Hydrogen Atom Transfer Agents

(2020) Qing An et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroalkylation of Aryl Alkenes with Organohalides Catalyzed by Molybdenum Oxido Based Lewis Pairs

(2020) Niklas Zwettler et al.   ADVANCED SYNTHESIS & CATALYSIS

Selective Decarbonylation via Transition-Metal-Catalyzed Carbon–Carbon Bond Cleavage

(2020) Hong Lu et al.   CHEMICAL REVIEWS

A photochemical dehydrogenative strategy for aniline synthesis

(2020) Shashikant U. Dighe et al.   NATURE

C(sp3)–H functionalizations of light hydrocarbons using decatungstate photocatalysis in flow

(2020) Gabriele Laudadio et al.   SCIENCE

Regio‐ and Enantioselective Ni‐Catalyzed Formal Hydroalkylation, Hydrobenzylation and Hydropropargylation of Acrylamides to α‐Tertiary Amides

(2020) Wei Shu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phenylglyoxylic Acid: An Efficient Initiator for the Photochemical Hydrogen Atom Transfer C−H Functionalization of Heterocycles

(2020) Giorgos N. Papadopoulos et al.   ChemSusChem

Photoredox-Catalyzed Deaminative Alkylation via C–N Bond Activation of Primary Amines

(2020) Melissa A. Ashley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Regioselective Hydroarylation of Internal Enamides

(2020) Chenchen Wang et al.   ORGANIC LETTERS

Enantioconvergent Cross−Couplings of Alkyl Electrophiles: The Catalytic Asymmetric Synthesis of Organosilanes

(2019) Gregory C Fu   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Construction of alpha-Chiral Silanes by Nickel-Catalyzed C(sp3)-C(sp3) Cross-Coupling

(2019) Hong Yi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Redox-Active Nickel Complex that Acts as an Electron Mediator in Photochemical Giese Reactions

(2019) Thomas van Leeuwen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Induced Atom Transfer Radical Addition and Cyclization of Perfluoroalkyl Halides with 1,n-Enynes

(2019) Shuo-Wen Wang et al.   ACS Sustainable Chemistry & Engineering

Nickel-Catalyzed Regioselective Hydroalkylation and Hydroarylation of Alkenyl Boronic Esters

(2019) Srikrishna Bera et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Radical Addition/Cross-Coupling of Organozinc Reagents, Alkyl Iodides, and Alkenyl Boron Reagents

(2019) Matteo Chierchia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand-Controlled Regiodivergent Hydroalkylation of Pyrrolines

(2019) Deyun Qian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Site-Selective Catalytic Deaminative Alkylation of Unactivated Olefins

(2019) Shang-Zheng Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Green Metal-Free Photochemical Hydroacylation of Unactivated Olefins

(2019) Errika Voutyritsa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

NiH-Catalyzed Reductive Relay Hydroalkylation: A Strategy for the Remote C(sp3 )−H Alkylation of Alkenes

(2018) Fang Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Green Photo-Organocatalytic C−H Activation of Aldehydes: Selective Hydroacylation of Electron-Deficient Alkenes

(2018) Giorgos N. Papadopoulos et al.   CHEMISTRY-A EUROPEAN JOURNAL

Silyl-mediated photoredox-catalyzed Giese reaction: addition of non-activated alkyl bromides

(2018) Abdellatif ElMarrouni et al.   Chemical Science

Palladium-Catalyzed Hydroalkylation of Alkynes with Cyclopropanols: Access to γ,δ-Unsaturated Ketones

(2018) Hao Liu et al.   ADVANCED SYNTHESIS & CATALYSIS

Microtubing-Reactor-Assisted Aliphatic C−H Functionalization with HCl as a Hydrogen-Atom-Transfer Catalyst Precursor in Conjunction with an Organic Photoredox Catalyst

(2018) Hong-Ping Deng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Employing Photoredox Catalysis for DNA-Encoded Chemistry: Decarboxylative Alkylation of α-Amino Acids

(2018) Dominik K. Kölmel et al.   ChemMedChem

Site-Selective Ni-Catalyzed Reductive Coupling of α-Haloboranes with Unactivated Olefins

(2018) Shang-Zheng Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective functionalization of methane, ethane, and higher alkanes by cerium photocatalysis

(2018) Anhua Hu et al.   SCIENCE

Lewis Acid Catalyst-steered Divergent Synthesis of Functionalized Vicinal Amino Alcohols and Pyrroles from Tertiary Enamides

(2018) Xin-Ming Xu et al.   Organic Chemistry Frontiers

Aliphatic Aldehyde: A Novel Radical Alkylating Reagent

(2018) Wen-Chao Yang et al.   ADVANCED SYNTHESIS & CATALYSIS

Photoredox radical conjugate addition of dithiane-2-carboxylate promoted by an iridium(iii) phenyl-tetrazole complex: a formal radical methylation of Michael acceptors

(2017) Andrea Gualandi et al.   Chemical Science

Transition-Metal Catalysis of Nucleophilic Substitution Reactions: A Radical Alternative to SN1 and SN2 Processes

(2017) Gregory C. Fu   ACS Central Science

Metal-Free Oxidative Decarbonylative Hydroalkylation of Alkynes with Secondary and Tertiary Alkyl Aldehydes

(2016) Xuan-Hui Ouyang et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Asymmetric Tandem Reaction of Tertiary Enamides: Expeditious Synthesis of Pyrrolo[2,1-a ]isoquinoline Alkaloid Derivatives

(2016) Xin-Ming Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aerobic oxidative cyclization of benzamides via meta-selective C–H tert-alkylation: rapid entry to 7-alkylated isoquinolinediones

(2016) Shi Tang et al.   CHEMICAL COMMUNICATIONS

Radicals: Reactive Intermediates with Translational Potential

(2016) Ming Yan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal catalyzed defunctionalization reactions

(2016) Atanu Modak et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A general, modular method for the catalytic asymmetric synthesis of alkylboronate esters

(2016) J. Schmidt et al.   SCIENCE

Donor–Acceptor Fluorophores for Visible-Light-Promoted Organic Synthesis: Photoredox/Ni Dual Catalytic C(sp3)–C(sp2) Cross-Coupling

(2016) Jian Luo et al.   ACS Catalysis

Metal-Catalyzed β-Functionalization of Michael Acceptors through Reductive Radical Addition Reactions

(2015) Jan Streuff et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silicates as Latent Alkyl Radical Precursors: Visible-Light Photocatalytic Oxidation of Hypervalent Bis-Catecholato Silicon Compounds

(2015) Vincent Corcé et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalysis of Radical Reactions: A Radical Chemistry Perspective

(2015) Armido Studer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Exploring tertiary enamides as versatile synthons in organic synthesis

(2015) Mei-Xiang Wang   CHEMICAL COMMUNICATIONS

Carboxylic Acids as A Traceless Activation Group for Conjugate Additions: A Three-Step Synthesis of (±)-Pregabalin

(2014) Lingling Chu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in homogeneous nickel catalysis

(2014) Sarah Z. Tasker et al.   NATURE

Direct Construction of Quaternary Carbons from Tertiary Alcohols via Photoredox-Catalyzed Fragmentation of tert-Alkyl N-Phthalimidoyl Oxalates

(2013) Gregory L. Lackner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The First Decarbonylative Coupling of Aldehydes and Norbornenes Catalyzed by Rhodium

(2010) Luo Yang et al.   ADVANCED SYNTHESIS & CATALYSIS

Efficient and General Continuous-Flow Hydroarylation and Hydroalkylation of Styrenes

(2010) Magnus Rueping et al.   ADVANCED SYNTHESIS & CATALYSIS

Ruthenium-Catalyzed Alkene Synthesis by the Decarbonylative Coupling of Aldehydes with Alkynes

(2010) C. Liana Allen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium as a general catalyst for the decarbonylative addition of aldehydes to alkynes

(2010) Jun Wang et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Ru-Catalyzed Decarbonylative Addition of Aliphatic Aldehydes to Terminal Alkynes

(2010) Xiangyu Guo et al.   ORGANIC LETTERS

A novel catalytic decarbonylative Heck-type reaction and conjugate addition of aldehydes to unsaturated carbonyl compounds

(2010) Luo Yang et al.   TETRAHEDRON LETTERS

Escape from Flatland: Increasing Saturation as an Approach to Improving Clinical Success

(2009) Frank Lovering et al.   JOURNAL OF MEDICINAL CHEMISTRY

An Olefination via Ruthenium-Catalyzed Decarbonylative Addition of Aldehydes to Terminal Alkynes

(2009) Xiangyu Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Acyl Radical Reactions in Fullerene Chemistry: Direct Acylation of [60]Fullerene through an Efficient Decatungstate-Photomediated Approach

(2009) Manolis D. Tzirakis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY