Mechanistic Study of Enantioselective Pd-Catalyzed C(sp3)–H Activation of Thioethers Involving Two Distinct Stereomodels

Bidentate Directing Groups: An Efficient Tool in C–H Bond Functionalization Chemistry for the Expedient Construction of C–C Bonds

(2020) Supriya Rej et al.   CHEMICAL REVIEWS

Enantioselective remote C–H activation directed by a chiral cation

(2020) Georgi R. Genov et al.   SCIENCE

Insights into the Role of Transient Chiral Mediators and Pyridone Ligands in Asymmetric Pd-Catalyzed C–H Functionalization

(2020) David E. Hill et al.   JOURNAL OF ORGANIC CHEMISTRY

Recent Developments in Enantioselective Transition Metal Catalysis Featuring Attractive Noncovalent Interactions between Ligand and Substrate

(2020) Alexander Fanourakis et al.   ACS Catalysis

Conformational Effects on Physical-Organic Descriptors: The Case of Sterimol Steric Parameters

(2019) Alexandre V. Brethomé et al.   ACS Catalysis

Asymmetric, Nearly Barrierless C(sp3)–H Activation Promoted by Easily-Accessible N-Protected Aminosulfoxides as New Chiral Ligands

(2019) Soufyan Jerhaoui et al.   ACS Catalysis

P-Chiral Phosphines Enabled by Palladium/Xiao-Phos-Catalyzed Asymmetric P–C Cross-Coupling of Secondary Phosphine Oxides and Aryl Bromides

(2019) Qiang Dai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective, Lewis Base-Catalyzed Sulfenocyclization of Polyenes

(2018) Zhonglin Tao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective C(sp3)‒H bond activation by chiral transition metal catalysts

(2018) Tyler G. Saint-Denis et al.   SCIENCE

Enantiocontrol by assembled attractive interactions in copper-catalyzed asymmetric direct alkynylation of α-ketoesters with terminal alkynes: OH⋯O/sp3-CH⋯O two-point hydrogen bonding combined with dispersive attractions

(2018) Martin C. Schwarzer et al.   Chemical Science

Palladium-Catalyzed γ-C(sp3 )−H Arylation of Thiols by a Detachable Protecting/Directing Group

(2018) Likun Jin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

(2018) Carlo Sambiagio et al.   CHEMICAL SOCIETY REVIEWS

Enantiodivergent Pd-catalyzed C–C bond formation enabled through ligand parameterization

(2018) Shibin Zhao et al.   SCIENCE

Exploiting non-covalent π interactions for catalyst design

(2017) Andrew J. Neel et al.   NATURE

Quantifying Structural Effects of Amino Acid Ligands in Pd(II)-Catalyzed Enantioselective C–H Functionalization Reactions

(2017) Yoonsu Park et al.   ORGANOMETALLICS

Formation of α-chiral centers by asymmetric β-C(sp 3 )–H arylation, alkenylation, and alkynylation

(2017) Qing-Feng Wu et al.   SCIENCE

Hexafluoroisopropanol as a highly versatile solvent

(2017) Ignacio Colomer et al.   Nature Reviews Chemistry

Explaining Anomalies in Enamine Catalysis: “Downstream Species” as a New Paradigm for Stereocontrol

(2016) Jordi Burés et al.   ACCOUNTS OF CHEMICAL RESEARCH

Understanding Palladium Acetate from a User Perspective

(2016) William A. Carole et al.   CHEMISTRY-A EUROPEAN JOURNAL

London Dispersion in Molecular Chemistry-Reconsidering Steric Effects

(2015) J. Philipp Wagner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A data-intensive approach to mechanistic elucidation applied to chiral anion catalysis

(2015) A. Milo et al.   SCIENCE

Hydrogen-Bond-Promoted Palladium Catalysis: Allylic Alkylation of Indoles with Unsymmetrical 1,3-Disubstituted Allyl Acetates Using Chiral Bis(sulfoxide) Phosphine Ligands

(2013) Le Du et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Controllable Mono-/Dialkenylation of Benzyl Thioethers through Rh-Catalyzed Aryl CH Activation

(2013) Xi-Sha Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iron-Catalyzed Cross-Coupling of Unactivated Secondary Alkyl Thio Ethers and Sulfones with Aryl Grignard Reagents

(2013) Scott E. Denmark et al.   JOURNAL OF ORGANIC CHEMISTRY

Thioethers as Directing Group for the Palladium-Catalyzed Direct Arylation of Arenes

(2012) Jinzhong Yao et al.   ADVANCED SYNTHESIS & CATALYSIS

Multidimensional steric parameters in the analysis of asymmetric catalytic reactions

(2012) Kaid C. Harper et al.   Nature Chemistry

Enantioselective Acylation of 1,2- and 1,3-Diols Catalyzed by Aminophosphinite Derivatives of (1S,2R)-1-Amino-2-indanol

(2012) Hiroyuki Aida et al.   ORGANIC LETTERS

Palladium-Catalyzed C–H Alkenylation of Arenes Using Thioethers as Directing Groups

(2012) Ming Yu et al.   ORGANIC LETTERS

Sulfur-Directed Olefin Oxidations: Observation of Divergent Reaction Mechanisms in the Palladium-Mediated Acetoxylation of Unsaturated Thioacetals

(2011) Sam E. Mann et al.   ORGANOMETALLICS

Transient chirality in a distal-substituted resorcinarene metal complex

(2010) Dewald J. Kleinhans et al.   DALTON TRANSACTIONS

Examination of the Role of Taft-Type Steric Parameters in Asymmetric Catalysis

(2009) Matthew S. Sigman et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium clusters Pd4(SR)4(OAc)4 and Pd6(SR)12 (R = Bu, Ph): Structure and properties

(2009) A. I. Stash et al.   RUSSIAN JOURNAL OF COORDINATION CHEMISTRY