Silver‐Catalyzed Asymmetric Dearomatization of Electron‐Deficient Heteroarenes via Interrupted Barton–Zard Reaction

Palladium‐Catalyzed Enantioselective Heteroarenyne Cycloisomerization Reaction

(2021) Yi-Xia Jia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-catalyzed Z-retentive asymmetric allylic substitution reactions

(2021) Ru Jiang et al.   SCIENCE

Advances in Catalytic Asymmetric Dearomatization

(2021) Chao Zheng et al.   ACS Central Science

Formation of 3,4-Diarylpyrrole- and Pyrrolocoumarin Core of Natural Marine Products via Barton-Zard Reaction and Selective O-demethylation

(2020) Eugenia A. Silyanova et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Recent Advances in the Catalytic Dearomatization of Naphthols

(2020) Juzneg An et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Modular Synthesis of Polycyclic Alkaloid Scaffolds via an Enantioselective Dearomative Cascade

(2020) James A. Rossi-Ashton et al.   ORGANIC LETTERS

Enantioselective Synthesis of Spiroindolines via Cascade Isomerization/Spirocyclization/Dearomatization Reaction

(2020) Zhiqiang Pan et al.   ORGANIC LETTERS

Asymmetric Dearomative Fluorination of 2‐Naphthols with Dicarboxylate Phase‐Transfer Catalyst

(2020) Hiromichi Egami et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Evidence for Simultaneous Dearomatization of Two Aromatic Rings Under Mild Conditions in Cu(I)-Catalyzed Direct Asymmetric Dearomatization of Pyridine

(2020) Michael W. Gribble et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly stereoselective construction of polycyclic benzofused tropane scaffolds and their latent bioactivities: bifunctional phosphonium salt-enabled cyclodearomatization process

(2020) Jian-Ping Tan et al.   Science China-Chemistry

A Dearomatization/Debromination Strategy for the [4+1] Spiroannulation of Bromophenols with α,β‐Unsaturated Imines

(2020) Yicong Ge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Time-dependent enantiodivergent synthesis via sequential kinetic resolution

(2020) Hang-Fei Tu et al.   Nature Chemistry

Recent Developments on Catalytic Enantioselective Isocyanide‐Based Reactions: Beyond Passerini and Ugi Multicomponent Reactions

(2020) Yun-Lin Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

External Reductant‐free Stepwise [3+2] Cycloaddition/Reductive Cyclization from 2‐Nitrochalcones and Isocyanides: Synthesis of Pyrrolo[3,4‐ c ]quinoline N ‐oxides

(2020) Xinyao Sheng et al.   Asian Journal of Organic Chemistry

Organocatalyzed Dearomative Cycloaddition of 2-Nitrobenzofurans and Isatin-Derived Morita–Baylis–Hillman Carbonates: Highly Stereoselective Construction of Cyclopenta[b]benzofuran Scaffolds

(2019) Jian-Qiang Zhao et al.   ORGANIC LETTERS

Organocatalyzed Asymmetric Dearomative Aza-Michael/Michael Addition Cascade of 2-Nitrobenzofurans and 2-Nitrobenzothiophenes with 2-Aminochalcones

(2019) Xiao-Jian Zhou et al.   JOURNAL OF ORGANIC CHEMISTRY

Phosphine-Catalyzed Enantioselective Dearomative [3+2]-Cycloaddition of 3-Nitroindoles and 2-Nitrobenzofurans

(2019) Huamin Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dearomatization of 3-Nitroindoles by a Phosphine-Catalyzed Enantioselective [3+2] Annulation Reaction

(2019) Kaizhi Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Kinetic Resolution by Enantioselective Aromatization: Conversion of Racemic Intermediates of the Barton-Zard Reaction into Enantioenriched 3-Arylpyrroles

(2019) Sheng-Cai Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Barton–Zard Reaction To Access 3-Pyrrole-Containing Axially Chiral Skeletons

(2019) Xiao-Long He et al.   ACS Catalysis

Organocatalytic Asymmetric Dearomatization of 3-Nitroindoles and 3-Nitrobenzothiophenes via Thiol-Triggered Diastereo- and Enantioselective Double Michael Addition Reaction

(2019) Xin-Meng Chen et al.   ORGANIC LETTERS

Diastereo- and enantioselective palladium-catalyzed dearomative [4 + 2] cycloaddition of 3-nitroindoles

(2019) Jia-Jia Suo et al.   CHINESE CHEMICAL LETTERS

Enantioselective Synthesis of Dihydropyridines Containing Quaternary Stereocenters Through Dearomatization of Pyridinium Salts

(2019) Donovan J. Robinson et al.   ACS Catalysis

Recent Advances in the Catalytic Functionalization of “Electrophilic” Indoles

(2019) Alessandro Cerveri et al.   CHINESE JOURNAL OF CHEMISTRY

Enantioselective Synthesis of Fused Polycyclic Tropanes via Dearomative [3 + 2] Cycloaddition Reactions of 2-Nitrobenzofurans

(2019) Zhen Wang et al.   ORGANIC LETTERS

Stereodivergent Synthesis of Tetrahydrofuroindoles through Pd-Catalyzed Asymmetric Dearomative Formal [3+2] Cycloaddition

(2018) Qiang Cheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereo- and Enantioselective Palladium-Catalyzed Dearomative [3+2] Cycloaddition of 3-Nitroindoles

(2018) Jia-Jia Suo et al.   Chemistry-An Asian Journal

Catalytic Asymmetric Dearomative [3 + 2] Cycloaddition of Electron-Deficient Indoles with All-Carbon 1,3-Dipoles

(2018) Meng Sun et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd-Catalyzed Asymmetric Dearomative Cycloaddition for Construction of Optically Active Pyrroloindoline and Cyclopentaindoline Derivatives: Access to 3a-Aminopyrroloindolines

(2018) Jun-Qi Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Diastereo- and Enantioselective Dearomative [3 + 2] Cycloaddition Reaction of 2-Nitrobenzofurans with 3-Isothiocyanato Oxindoles

(2018) Jian-Qiang Zhao et al.   ORGANIC LETTERS

Zn-Catalyzed Diastereo- and Enantioselective Dearomative [3+2] Cycloaddition Reaction of 2-Nitroindoles and 2-Nitrobenzothiophenes

(2018) Jian-Qiang Zhao et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Enantio- and Diastereoselective Mannich Addition of TosMIC to Ketimines

(2018) Darren James Dixon et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Silver-Catalyzed Cascade Synthesis of Fused Lactone and Lactam Oxazolines

(2018) Raquel de la Campa et al.   ORGANIC LETTERS

Catalytic Atropenantioselective Heteroannulation between Isocyanoacetates and Alkynyl Ketones: Synthesis of Enantioenriched Axially Chiral 3-Arylpyrroles

(2018) Sheng-Cai Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent progress in transition-metal-catalyzed enantioselective indole functionalizations

(2017) Jing-Biao Chen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Multiple Hydrogen-Bonding Bifunctional Thiourea-Catalyzed Asymmetric Dearomative [4 + 2] Annulation of 3-Nitroindoles: Highly Enantioselective Access to Hydrocarbazole Skeletons

(2017) Deng-Feng Yue et al.   ORGANIC LETTERS

Formal [3 + 2] cycloaddition of α-unsubstituted isocyanoacetates and methyleneindolinones: enantioselective synthesis of spirooxindoles

(2017) Xiao-Jiao Peng et al.   Organic Chemistry Frontiers

Palladium-Catalyzed Highly Stereoselective Dearomative [3 + 2] Cycloaddition of Nitrobenzofurans

(2017) Qiang Cheng et al.   Chem

Assembly of Enantioenrichedcis-3a,8a-Hexahydropyrrolo[2,3-b]indole Scaffolds by Silver(I)-Catalyzed Asymmetric Domino Reaction of Isocyanoacetates in the Presence ofCinchona-Derived Chiral Phosphorus Ligands

(2016) Hengguang Cheng et al.   ADVANCED SYNTHESIS & CATALYSIS

Cross-Cycloaddition of Two Different Isocyanides: Chemoselective Heterodimerization and [3+2]-Cyclization of 1,4-Diazabutatriene

(2016) Zhongyan Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total syntheses of (±)-spiroindimicins B and C enabled by a late-stage Schöllkopf–Magnus–Barton–Zard (SMBZ) reaction

(2016) Lachlan M. Blair et al.   CHEMICAL COMMUNICATIONS

Catalytic enantio- and diastereoselective Mannich reaction of α-substituted isocyanoacetates and ketimines

(2016) Raquel de la Campa et al.   CHEMICAL COMMUNICATIONS

Catalytic asymmetric dearomatization (CADA) reactions of phenol and aniline derivatives

(2016) Wen-Ting Wu et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective dearomative [3 + 2] cycloadditions of indoles with azomethine ylides derived from alanine imino esters

(2016) Anthony L. Gerten et al.   Organic Chemistry Frontiers

Catalytic Asymmetric Dearomatization by Transition-Metal Catalysis: A Method for Transformations of Aromatic Compounds

(2016) Chao Zheng et al.   Chem

Direct Catalytic Enantio- and Diastereoselective Ketone Aldol Reactions of Isocyanoacetates

(2015) Raquel de la Campa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

4,8-Dihydropyrrol[3,4-f]isoindole as a Useful Building Block for Near-Infrared Dyes

(2015) Hidemitsu Uno et al.   HETEROCYCLES

Catalytic Divergent Synthesis of 3H or 1H Pyrroles by [3 + 2] Cyclization of Allenoates with Activated Isocyanides

(2015) Jia-Yu Liao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Cycloprodigiosin Identifies the Natural Isolate as a Scalemic Mixture

(2015) Rebecca E. Johnson et al.   ORGANIC LETTERS

Zn-Catalyzed Diastereo- and Enantioselective Cascade Reaction of 3-Isothiocyanato Oxindoles and 3-Nitroindoles: Stereocontrolled Syntheses of Polycyclic Spirooxindoles

(2015) Jian-Qiang Zhao et al.   ORGANIC LETTERS

Asymmetric Michael/Cyclization Cascade Reaction of 3-Isothiocyanato Oxindoles and 3-Nitroindoles with Amino-Thiocarbamate Catalysts: Enantioselective Synthesis of Polycyclic Spirooxindoles

(2015) Jian-Qiang Zhao et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Asymmetric Allylic Dearomatization Reactions

(2014) Chun-Xiang Zhuo et al.   ACCOUNTS OF CHEMICAL RESEARCH

Direct Catalytic Enantio- and Diastereoselective Mannich Reaction of Isocyanoacetates and Ketimines

(2014) Irene Ortín et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

PyBidine/Copper Catalyst: Asymmetricexo′-Selective [3+2] Cycloaddition using Imino Ester and Electrophilic Indole

(2014) Atsuko Awata et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Diastereo- and Enantioselective Silver-Catalyzed Double [3+2] Cyclization of α-Imino Esters with Isocyanoacetate

(2014) Pan-Lin Shao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Dearomative Trimethylenemethane Cycloaddition Reactions

(2014) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile [7C+1C] Annulation as an Efficient Route to Tricyclic Indolizidine Alkaloids

(2013) Xianxiu Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Dearomatization Reactions

(2012) Chun-Xiang Zhuo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Unsymmetrical 3,4-Diaryl-3-pyrrolin-2-ones Utilizing Pyrrole Weinreb Amides

(2011) Jessica G. Greger et al.   JOURNAL OF ORGANIC CHEMISTRY

A New Family of Cinchona-Derived Amino Phosphine Precatalysts: Application to the Highly Enantio- and Diastereoselective Silver-Catalyzed Isocyanoacetate Aldol Reaction

(2011) Filippo Sladojevich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Double Isocyanide Cyclization: A Synthetic Strategy for Two-Carbon-Tethered Pyrrole/Oxazole Pairs

(2011) Yifei Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular palladium-catalysed enolate arylation of 2- and 3-iodoindole derivatives for the synthesis of β-carbolines, γ-carbolines, and pyrrolo[3,4-b]indoles

(2011) Daniel Solé et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of hydrogenated 2,7-dimethylpyrrolo[3,4-b]indoles – analogs of dimebon

(2010) A. V. Ivachtchenko et al.   Chemistry of Heterocyclic Compounds

Tandem Double-Michael-Addition/Cyclization/Acyl Migration of 1,4-Dien-3-ones and Ethyl Isocyanoacetate: Stereoselective Synthesis of Pyrrolizidines

(2009) Jing Tan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Barton-Zard Pyrrole Synthesis and Its Application to Synthesis of Porphyrins, Polypyrroles, and Dipyrromethene Dyes

(2009) Noboru Ono   HETEROCYCLES

Organocatalytic Asymmetric Formal [3+2] Cycloaddition Reaction of Isocyanoesters to Nitroolefins Leading to Highly Optically Active Dihydropyrroles

(2008) Chang Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION