Metal‐Free Multi‐Component Sulfur Dioxide Insertion Reaction Leading to Quinoxalin‐2‐One‐Containing Vinyl Sulfones under Visible‐Light Photoredox Catalysis

Sulfonylation of Aryl Halides by Visible Light/Copper Catalysis

(2021) Qiuli Yan et al.   ORGANIC LETTERS

Visible-light-initiated malic acid-promoted cascade coupling/cyclization of aromatic amines and KSCN to 2-aminobenzothiazoles without photocatalyst

(2020) Wei-Bao He et al.   CHINESE CHEMICAL LETTERS

Iron‐Mediated Cyanoalkylsulfonylation/Arylation of Active Alkenes with Cycloketone Oxime Derivatives via Sulfur Dioxide Insertion

(2020) Zan Chen et al.   ADVANCED SYNTHESIS & CATALYSIS

Visible Light-Driven Radical-Mediated C–C Bond Cleavage/Functionalization in Organic Synthesis

(2020) Xiao-Ye Yu et al.   CHEMICAL REVIEWS

Visible-light-induced regioselective cross-dehydrogenative coupling of 2-isothiocyanatonaphthalenes with amines using molecular oxygen

(2020) Ziyu Gan et al.   Science China-Chemistry

Metal‐free Photo‐induced Cascade Sulfonylation/Addition/Cyclization of 3‐Arylethynyl‐[1,1'‐biphenyl]‐2‐carbonitriles with Aryldiazonium Tetrafluoroborates via the Insertion of Sulfur Dioxide

(2020) Nengneng Zhou et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper‐Catalyzed Regio‐ and Stereoselective Oxidative Vinylsulfonylation of Quinoxalinones with Alkynes and Sulfonyl Hydrazides

(2020) Chayan Dhar Clinton et al.   ADVANCED SYNTHESIS & CATALYSIS

Visible-light-induced three-component reaction of quinoxalin-2(1H)-ones, alkenes and CF3SO2Na leading to 3-trifluoroalkylated quinoxalin-2(1H)-ones

(2020) Na Meng et al.   CHINESE CHEMICAL LETTERS

Metal-free C3-alkoxycarbonylation of quinoxalin-2(1H)-ones with carbazates as ecofriendly ester sources

(2019) Long-Yong Xie et al.   Science China-Chemistry

Cu-Catalyzed Photoredox Chlorosulfonation of Alkenes and Alkynes

(2019) Murat Alkan-Zambada et al.   JOURNAL OF ORGANIC CHEMISTRY

Aryl Methyl Sulfone Construction from Eco-Friendly Inorganic Sulfur Dioxide and Methyl Reagents

(2019) Ming Wang et al.   ChemSusChem

Metal‐Free Synthesis of Thiosulfonates via Insertion of Sulfur Dioxide

(2019) Guoqing Li et al.   ADVANCED SYNTHESIS & CATALYSIS

Access to Polycyclic Sulfonyl Indolines via Fe(II)-Catalyzed or UV-Driven Formal [2 + 2 + 1] Cyclization Reactions of N-((1H-indol-3-yl)methyl)propiolamides with NaHSO3

(2019) Lin Lu et al.   ORGANIC LETTERS

Visible Light-Induced Co- or Cu-Catalyzed Selenosulfonylation of Alkynes: Synthesis of β-(Seleno)vinyl Sulfones

(2019) Rong Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

(Thio)etherification of Quinoxalinones under Visible‐Light Photoredox Catalysis

(2019) Jiadi Zhou et al.   ADVANCED SYNTHESIS & CATALYSIS

Metal Free Benzylation and Alkylation of Quinoxalin‐2(1 H )‐ones with Alkenes Triggered by Sulfonyl Radical Generated from Sulfinic Acids

(2019) Himangsu Sekhar Dutta et al.   ADVANCED SYNTHESIS & CATALYSIS

Multicomponent Reductive Cross-Coupling of an Inorganic Sulfur Dioxide Surrogate: Straightforward Construction of Diversely Functionalized Sulfones

(2019) Yingying Meng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

TFA promoted multi-component reaction of aryldiazonium with sodium metabisulphite and thiols: Construction of thiosulfonate under transition-metal free conditions

(2019) Cheng-Mi Huang et al.   CHINESE CHEMICAL LETTERS

Functionalization of Alkynes and Alkenes Using a Cascade Reaction Approach: Synthesis of β-Keto Sulfones under Metal-free Conditions

(2019) Mukesh Kumar et al.   JOURNAL OF ORGANIC CHEMISTRY

Radicals and Sulfur Dioxide: A Versatile Combination for the Construction of Sulfonyl-Containing Molecules

(2018) Kamil Hofman et al.   CHEMISTRY-A EUROPEAN JOURNAL

Visible-light mediated 3-component synthesis of sulfonylated coumarins from sulfur dioxide

(2018) Zhengkai Chen et al.   GREEN CHEMISTRY

Insertion of sulfur dioxide via a radical process: an efficient route to sulfonyl compounds

(2018) Guanyinsheng Qiu et al.   Organic Chemistry Frontiers

Recent advances in the sulfonylation of alkenes with the insertion of sulfur dioxide via radical reactions

(2018) Guanyinsheng Qiu et al.   CHEMICAL COMMUNICATIONS

Modern approaches for SO2 insertion in heterocyclic synthesis (microreview)

(2018) Krista Suta et al.   Chemistry of Heterocyclic Compounds

Photoinduced synthesis of (E)-vinyl sulfones through the insertion of sulfur dioxide

(2018) Tong Liu et al.   Organic Chemistry Frontiers

Manganese-Catalyzed Acceptorless Dehydrogenative Coupling of Alcohols With Sulfones: A Tool To Access Highly Substituted Vinyl Sulfones

(2018) Satyadeep Waiba et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of (E)-β-Selenovinyl Sulfones through a Multicomponent Regio- and Stereospecific Selenosulfonation of Alkynes with Insertion of Sulfur Dioxide

(2018) Kai Sun et al.   ORGANIC LETTERS

Metal-Free C(sp2)–H/N–H Cross-Dehydrogenative Coupling of Quinoxalinones with Aliphatic Amines under Visible-Light Photoredox Catalysis

(2018) Wei Wei et al.   ORGANIC LETTERS

Metal-free selenosulfonylation of alkynes: rapid access to β-(seleno)vinyl sulfones via a cationic-species-induced pathway

(2017) Kai Sun et al.   GREEN CHEMISTRY

Copper-Catalyzed Three Component Regio- and Stereospecific Selenosulfonation of Alkynes: Synthesis of (E)-β-Selenovinyl Sulfones

(2017) Yang Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Metal-free Oxidative Coupling of Aromatic Alkenes with Thiols Leading to (E)-Vinyl Sulfones

(2017) Leilei Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Design and Synthesis of Potent and Multifunctional Aldose Reductase Inhibitors Based on Quinoxalinones

(2015) Xiangyu Qin et al.   JOURNAL OF MEDICINAL CHEMISTRY

Phosphoric Acid-Mediated Synthesis of Vinyl Sulfones through Decarboxylative Coupling Reactions of Sodium Sulfinates with Phenylpropiolic Acids

(2015) Guangwei Rong et al.   JOURNAL OF ORGANIC CHEMISTRY

Iron/Copper Co-Catalyzed Synthesis of Vinyl Sulfones from Sulfonyl Hydrazides and Alkyne Derivatives

(2015) Guangwei Rong et al.   JOURNAL OF ORGANIC CHEMISTRY

The Development and Application of Sulfur Dioxide Surrogates in Synthetic Organic Chemistry

(2015) Edward J. Emmett et al.   Asian Journal of Organic Chemistry

Copper-catalyzed direct decarboxylative hydrosulfonylation of aryl propiolic acids with sulfonylhydrazides leading to vinylsulfones

(2015) Siyu Li et al.   Organic Chemistry Frontiers

Chemoselective Synthesis of Unsymmetrical Internal Alkynes or Vinyl SulfonesviaPalladium-Catalyzed Cross-Coupling Reaction of Sodium Sulfinates with Alkynes

(2014) Yanli Xu et al.   ADVANCED SYNTHESIS & CATALYSIS

Gold-Catalyzed Intermolecular CS Bond Formation: Efficient Synthesis of α-Substituted Vinyl Sulfones

(2014) Yumeng Xi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed highly selective direct hydrosulfonylation of alkynes with arylsulfinic acids leading to vinyl sulfones

(2014) Wei Wei et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Catalytic and direct methyl sulfonylation of alkenes and alkynes using a methyl sulfonyl radical generated from a DMSO, dioxygen and copper system

(2014) Yaojia Jiang et al.   Chemical Science

Rhodium-Catalyzed Asymmetric Hydrogenation of β-Acetylamino Acrylosulfones: A Practical Approach to Chiral β-Amido Sulfones

(2014) Jun Jiang et al.   ACS Catalysis

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

Taming sulfur dioxide: a breakthrough for its wide utilization in chemistry and biology

(2013) Philippe Bisseret et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective Synthesis of Chiral Sulfones by Ir-Catalyzed Asymmetric Hydrogenation: A Facile Approach to the Preparation of Chiral Allylic and Homoallylic Compounds

(2012) Taigang Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Oxidative Hydrosulfonylation of Alkynes Using Sodium Sulfinates in Air

(2012) Nobukazu Taniguchi   SYNLETT

Metal-free, one-pot highly selective synthesis of (E)-vinyl sulfones and sulfoxides via addition–oxidation of thiols with alkynes

(2012) Qicai Xue et al.   TETRAHEDRON LETTERS

DABCO-Bis(sulfur dioxide), DABSO, as a Convenient Source of Sulfur Dioxide for Organic Synthesis: Utility in Sulfonamide and Sulfamide Preparation

(2011) Holly Woolven et al.   ORGANIC LETTERS

Evolving Organic Synthesis Fostered by the Pluripotent Phenylsulfone Moiety

(2009) Ahmad El-Awa et al.   CHEMICAL REVIEWS

Development of Peptidomimetics with a Vinyl Sulfone Warhead as Irreversible Falcipain-2 Inhibitors

(2008) Roberta Ettari et al.   JOURNAL OF MEDICINAL CHEMISTRY