An axial-to-axial chirality transfer strategy for atroposelective construction of C–N axial chirality

Chiral Pd-Catalyzed Enantioselective Syntheses of Various N–C Axially Chiral Compounds and Their Synthetic Applications

(2021) Osamu Kitagawa   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Atroposelective Catellani Reaction Enables Construction of Axially Chiral Biaryl Monophosphine Oxides

(2021) Qiang Feng et al.   CCS Chemistry

Chiral-Phosphoric-Acid-Catalyzed Atroposelective C-H Amination of Arenes

(2020) Bin Tan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of Axially Chiral Phosphamides via Atroposelective N-Allylic Alkylation

(2020) Guo-Hui Yang et al.   ACS Catalysis

Enantioselective Synthesis of N–C Axially Chiral Compounds by Cu‐Catalyzed Atroposelective Aryl Amination

(2020) Johanna Frey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atroposelective Synthesis of Axially Chiral N‐Arylpyrroles by Chiral‐at‐Rhodium Catalysis

(2020) Chen‐Xi Ye et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Construction of Axially Chiral Compounds via Central‐to‐Axial Chirality Conversion

(2020) Hui Yang et al.   Chemistry-An Asian Journal

Stereospecific Si-C coupling and remote control of axial chirality by enantioselective palladium-catalyzed hydrosilylation of maleimides

(2020) Xing-Wei Gu et al.   Nature Communications

Construction of axial chirality via palladium/chiral norbornene cooperative catalysis

(2020) Ze-Shui Liu et al.   Nature Catalysis

Enantioselective Synthesis of Atropisomeric Anilides via Pd(II)-Catalyzed Asymmetric C–H Olefination

(2020) Qi-Jun Yao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Atropisomeric Anilides Synthesis via Cu-Catalyzed Intramolecular Adjacent C–N Coupling

(2019) Xiaozhong Fan et al.   ACS Catalysis

Enantioselective Synthesis of Atropisomers Featuring Pentatomic Heteroaromatics by Pd-Catalyzed C–H Alkynylation

(2019) Shuo Zhang et al.   ACS Catalysis

Enantioselective Synthesis of C-N Axially Chiral N-Aryloxindoles by Asymmetric Rhodium-Catalyzed Dual C-H Activation

(2019) Honghe Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium/Norbornene Cooperative Catalysis

(2019) Jianchun Wang et al.   CHEMICAL REVIEWS

Highly atroposelective synthesis of nonbiaryl naphthalene-1,2-diamine N-C atropisomers through direct enantioselective C-H amination

(2019) He-Yuan Bai et al.   Nature Communications

Practical access to axially chiral sulfonamides and biaryl amino phenols via organocatalytic atroposelective N-alkylation

(2019) Shenci Lu et al.   Nature Communications

Atroposelective Phosphoric Acid Catalyzed Three-Component Cascade Reaction: Enantioselective Synthesis of Axially Chiral N-Arylindoles

(2019) Lei Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Construction of Axially Chiral Compounds via Asymmetric Organocatalysis

(2018) Yong-Bin Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

The Alkylating Reagents Employed in Catellani-Type Reactions

(2018) Qianghui Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Parameterization and Analysis of Peptide-Based Catalysts for the Atroposelective Bromination of 3-Arylquinazolin-4(3H)-ones

(2018) Jennifer M. Crawford et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

From determination of enantiopurity to the construction of complex molecules: The Horeau principle and its application in synthesis

(2018) Andrew M. Harned   TETRAHEDRON

Atroposelective Catalytic Asymmetric Allylic Alkylation Reaction for Axially Chiral Anilides with Achiral Morita–Baylis–Hillman Carbonates

(2018) Shou-Lei Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective remote meta-C–H arylation and alkylation via a chiral transient mediator

(2018) Hang Shi et al.   NATURE

Palladium-catalyzed Asymmetric Annulation between Aryl Iodides and Racemic Epoxides Using a Chiral Norbornene Cocatalyst

(2018) Renhe Li et al.   Organic Chemistry Frontiers

The Pd(II)-Initiated Catellani-type Reactions

(2018) Qianghui Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Atroposelective Synthesis of Arylpyrroles by Catalytic Asymmetric Paal–Knorr Reaction

(2017) Lei Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Programmed serial stereochemical relay and its application in the synthesis of morphinans

(2017) Kun Ho (Kenny) Park et al.   Chemical Science

Brønsted acid-catalysed enantioselective construction of axially chiral arylquinazolinones

(2017) Yong-Bin Wang et al.   Nature Communications

Pd/Norbornene: A Winning Combination for Selective Aromatic Functionalization via C–H Bond Activation

(2016) Nicola Della Ca’ et al.   ACCOUNTS OF CHEMICAL RESEARCH

Discovery and enantiocontrol of axially chiral urazoles via organocatalytic tyrosine click reaction

(2016) Ji-Wei Zhang et al.   Nature Communications

Chirality transfer in metal-catalysed intermolecular addition reactions involving allenes

(2016) José Miguel Alonso et al.   Organic Chemistry Frontiers

Catalytic asymmetric desymmetrization of N-arylmaleimides: efficient construction of both atom chirality and axial chirality

(2015) Jianlin Zhang et al.   CHEMICAL COMMUNICATIONS

Nonbiaryl and Heterobiaryl Atropisomers: Molecular Templates with Promise for Atropselective Chemical Transformations

(2015) Elango Kumarasamy et al.   CHEMICAL REVIEWS

Recent advances and new concepts for the synthesis of axially stereoenriched biaryls

(2015) J. Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective Synthesis of 3-Arylquinazolin-4(3H)-ones via Peptide-Catalyzed Atroposelective Bromination

(2015) Matthew E. Diener et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-catalysed norbornene-mediated C–H functionalization of arenes

(2015) Juntao Ye et al.   Nature Chemistry

Relationship between rotational barriers and structures in N–C axially chiral 3,4-dihydroquinolin-2-one and 3,4-dihydrobenzoquinolin-2-one

(2015) Yuya Suzuki et al.   TETRAHEDRON LETTERS

Remote Control of Axial Chirality: Aminocatalytic Desymmetrization of N-Arylmaleimides via Vinylogous Michael Addition

(2014) Nicola Di Iorio et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of Atropisomeric Compounds with an N‒C Chiral Axis

(2014) Isao Takahashi et al.   ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL

Axial-to-central chirality transfer in cyclization processes

(2013) Damien Campolo et al.   CHEMICAL SOCIETY REVIEWS

Mechanistic Studies of Pd-Catalyzed Regioselective Aryl CH Bond Functionalization with Strained Alkenes: Origin of Regioselectivity

(2011) David I. Chai et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Asymmetric Synthesis of Axially Chiral o-Iodoanilides by Phase-Transfer Catalyzed Alkylations

(2011) Seiji Shirakawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Of the Ortho Effect in Palladium/Norbornene-Catalyzed Reactions: A Theoretical Investigation

(2011) Giovanni Maestri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Brønsted Base-Catalyzed Tandem Isomerization-Michael Reactions of Alkynes: Synthesis of Oxacycles and Azacycles

(2010) Hongjun Liu et al.   ADVANCED SYNTHESIS & CATALYSIS

Stereochemical Relay via Axially Chiral Styrenes: Asymmetric Synthesis of the Antibiotic TAN-1085

(2009) Keiji Mori et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Challenge of Atropisomerism in Drug Discovery

(2009) Jonathan Clayden et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions Employing Dialkylbiaryl Phosphine Ligands

(2008) Ruben Martin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Sequential Reactions Involving Palladacycle-Directed Aryl Coupling Steps

(2008) Marta Catellani et al.   ACCOUNTS OF CHEMICAL RESEARCH