Transition‐Metal‐Free C−H Silylation: An Emerging Strategy

Catalytic Reduction of Cyclic Ethers with Hydrosilanes

(2019) Sehoon Park   Chemistry-An Asian Journal

B(C 6 F 5 ) 3 ‐Catalyzed sp 3 C‐Si Bond Forming Consecutive Reactions

(2019) Sehoon Park   CHINESE JOURNAL OF CHEMISTRY

The electrophilic aromatic substitution approach to C–H silylation and C–H borylation

(2018) Susanne Bähr et al.   PURE AND APPLIED CHEMISTRY

Transition-Metal-Free Direct C−H Silylation of Electron-Deficient Heteroarenes with Hydrosilanes via a Radical Mechanism

(2018) Ryu Sakamoto et al.   Asian Journal of Organic Chemistry

B(C₆F₅)₃/Amine-Catalyzed C(sp)-H Silylation of Terminal Alkynes with Hydrosilanes: Combined Experimental and Theoretical Studies

(2018) Zhaomin Hou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Yttrium-Catalyzed Regioselective α-C–H Silylation of Methyl Sulfides with Hydrosilanes

(2018) Yong Luo et al.   ACS Catalysis

Switchable C–H Silylation of Indoles Catalyzed by a Thermally Induced Frustrated Lewis Pair

(2018) Yuxi Han et al.   ACS Catalysis

A Mild and Direct Site-Selective sp2 C–H Silylation of (Poly)Azines

(2018) Yiting Gu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Access to Bridged Sila-N-heterocycles from Piperidines via Cascade sp3 and sp2 C–Si Bond Formation

(2018) Jianbo Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Potassium tert-Butoxide-Catalyzed Dehydrogenative C–H Silylation of Heteroaromatics: A Combined Experimental and Computational Mechanistic Study

(2017) Wen-Bo Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ionic and Neutral Mechanisms for C–H Bond Silylation of Aromatic Heterocycles Catalyzed by Potassium tert-Butoxide

(2017) Shibdas Banerjee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alkali Metal-Hydroxide-Catalyzed C(sp)–H Bond silylation

(2017) Anton A. Toutov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

B(C6F5)3-Catalyzed (Convergent) Disproportionation Reaction of Indoles

(2017) Yuxi Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrophilic Aromatic Substitution with Silicon Electrophiles: Catalytic Friedel-Crafts C−H Silylation

(2016) Susanne Bähr et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boron-Catalyzed Aromatic C–H Bond Silylation with Hydrosilanes

(2016) Yuanhong Ma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Brønsted Acid-Promoted Formation of Stabilized Silylium Ions for Catalytic Friedel–Crafts C–H Silylation

(2016) Qing-An Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transfer Hydrosilylation

(2015) Martin Oestreich   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalysis of Radical Reactions: A Radical Chemistry Perspective

(2015) Armido Studer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A unified survey of Si–H and H–H bond activation catalysed by electron-deficient boranes

(2015) Martin Oestreich et al.   CHEMICAL SOCIETY REVIEWS

Frustrated Lewis Pairs

(2015) Douglas W. Stephan   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silylation of C–H bonds in aromatic heterocycles by an Earth-abundant metal catalyst

(2015) Anton A. Toutov et al.   NATURE

Deprotonative C–H Silylation of Functionalized Arenes and Heteroarenes Using Trifluoromethyltrialkylsilane with Fluoride

(2015) Midori Sasaki et al.   ORGANIC LETTERS

Synthesis of silafluorenes and silaindenes via silyl radicals from arylhydrosilanes: intramolecular cyclization and intermolecular annulation with alkynes

(2015) Liang Xu et al.   Organic Chemistry Frontiers

TBHP-promoted sequential radical silylation and aromatisation of aryl isonitriles with silanes

(2014) Lei Wang et al.   CHEMICAL COMMUNICATIONS

The electron is a catalyst

(2014) Armido Studer et al.   Nature Chemistry

9-Silafluorenes via Base-Promoted Homolytic Aromatic Substitution (BHAS) – The Electron as a Catalyst

(2014) Dirk Leifert et al.   ORGANIC LETTERS

B(C6F5)3-Catalyzed Synthesis of Benzofused-Siloles

(2014) Liam D. Curless et al.   ORGANOMETALLICS

E–H (E = R3Si or H) bond activation by B(C6F5)3 and heteroarenes; competitive dehydrosilylation, hydrosilylation and hydrogenation

(2013) Liam D. Curless et al.   CHEMICAL COMMUNICATIONS

Facile Synthetic Route to Highly Luminescent Sila[7]helicene

(2013) Hiromi Oyama et al.   ORGANIC LETTERS

Lewis-base silane activation: from reductive cleavage of aryl ethers to selective ortho-silylation

(2013) Alexey Fedorov et al.   Chemical Science

A New Fluorometric Turn-On Detection of l-Lactic Acid Based on the Cascade Enzymatic and Chemical Reactions and the Abnormal Fluorescent Behavior of Silole

(2012) Xiang Shen et al.   ORGANIC LETTERS

Organocatalysis and CH Activation Meet Radical- and Electron-Transfer Reactions

(2011) Armido Studer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Aspects of Bond Activation with Perfluoroarylboranes

(2011) Warren E. Piers et al.   INORGANIC CHEMISTRY

Bulk Heterojunction Solar Cells Using Thieno[3,4-c]pyrrole-4,6-dione and Dithieno[3,2-b:2′,3′-d]silole Copolymer with a Power Conversion Efficiency of 7.3%

(2011) Ta-Ya Chu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Application of the sila-Friedel–Crafts reaction to the synthesis of π-extended silole derivatives and their properties

(2010) Shunsuke Furukawa et al.   DALTON TRANSACTIONS

tert-Butoxide-Mediated Arylation of Benzene with Aryl Halides in the Presence of a Catalytic 1,10-Phenanthroline Derivative

(2010) Eiji Shirakawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalysis in Cross-Coupling: DMEDA-Catalyzed Direct C−H Arylation of Unactivated Benzene

(2010) Wei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An efficient organocatalytic method for constructing biaryls through aromatic C–H activation

(2010) Chang-Liang Sun et al.   Nature Chemistry

Development of a Sila-Friedel−Crafts Reaction and Its Application to the Synthesis of Dibenzosilole Derivatives

(2009) Shunsuke Furukawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tailoring Structure−Property Relationships in Dithienosilole−Benzothiadiazole Donor−Acceptor Copolymers

(2009) Pierre M. Beaujuge et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Silylene-1,3-Diene [4 + 1] Cycloaddition with Use of (Aminosilyl)boronic Esters as Synthetic Equivalents of Silylene

(2009) Toshimichi Ohmura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diverse Reactions of 1,4-Dilithio-1,3-dienes with Nitriles: Facile Access to Tricyclic Δ1-Bipyrrolines, Multiply Substituted Pyridines, Siloles, and (Z,Z)-Dienylsilanes by Tuning of Substituents on the Butadienyl Skeleton

(2008) Nan Yu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Silylboranes Bearing Dialkylamino Groups on Silicon as Silylene Equivalents:  Palladium-Catalyzed Regioselective Synthesis of 2,4-Disubstituted Siloles

(2008) Toshimichi Ohmura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Characterization, and Photovoltaic Properties of a Low Band Gap Polymer Based on Silole-Containing Polythiophenes and 2,1,3-Benzothiadiazole

(2008) Jianhui Hou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Characterization, and Transistor Response of Semiconducting Silole Polymers with Substantial Hole Mobility and Air Stability. Experiment and Theory

(2008) Gang Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Potassiumt-Butoxide Alone Can Promote the Biaryl Coupling of Electron-Deficient Nitrogen Heterocycles and Haloarenes

(2008) Shuichi Yanagisawa et al.   ORGANIC LETTERS

(Me3Si)3SiH: Twenty Years After Its Discovery as a Radical-Based Reducing Agent

(2007) Chryssostomos Chatgilialoglu   CHEMISTRY-A EUROPEAN JOURNAL