期刊
ORGANIC LETTERS
卷 17, 期 4, 页码 848-851出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol503671b
关键词
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资金
- Japan Society for the promotion of Science [23390002, 25670002]
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- project Platform for Drug Discovery, Informatics, and Structural Life Science from the Ministry of Education, Culture, Sports, Science and Technology, Japan
- Grants-in-Aid for Scientific Research [25670002, 23390002] Funding Source: KAKEN
A highly selective C-H silylation reaction of functionalized arenes and heteroarenes was developed using RuppertPrakash reagent (TMSCF3) activated by alkali metal fluoride. TMSCF3 is considered to play dual roles as a precursor of a mild base and also as a silicon electrophile. The silylation is compatible with sensitive functional groups such as halogen and nitro groups.
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