Article
Biochemistry & Molecular Biology
Feng-Ping Wang, Bo Li, Mei-Yan Sun, Fazli Wahid, Hong-Mei Zhang, Shu-Jun Wang, Yan-Yan Xie, Shi-Ru Jia, Cheng Zhong
Summary: This study explores the use of starches to regulate the structural properties of bacterial cellulose (BC), leading to membrane modifications for oil-water separation. Starches impact the synthesis of BC and alter membrane properties, providing insights into expanding the applications of BC.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2022)
Article
Thermodynamics
Paulo Vitor Franca Lemos, Lucas Guimaraes Cardoso, Jania Betania Alves da Silva, Carolina Oliveira de Souza, Janice Izabel Druzian
Summary: The study aimed to prepare and characterize amylose inclusion complexes with rhynchophorol aggregation pheromone. Both potato and cassava V-amylose-rhynchophorol complexes were successfully obtained, presenting high crystalline indexes and thermal stability. The starch polymers studied were found suitable for the retention of rhynchophorol guest molecules, as demonstrated by TG and GC-MS analysis.
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
(2021)
Article
Physics, Fluids & Plasmas
Christophe Kusina, Wilbert J. Smit, Jean-Baptiste Boitte, Odile Aubrun, Annie Colin
Summary: The study shows that the aging process of cornstarch particles and the viscosity changes in cornstarch suspensions vary depending on the solvent used. The increase in viscosity is attributed to air trapped in the pore space, granule swelling, and leakage of amylopectin into the surrounding water.
Article
Mathematics
Muhammad Kamran, Sadik Delen, Riaz Hussain Khan, Nadeem Salamat, A. Q. Baig, Ismail Naci Cangul, Md. Ashraful Alam
Summary: Polysaccharides are biomaterials with great properties, and this paper focuses on computing the topological indices of two polysaccharides and studying their physicochemical characterization.
JOURNAL OF MATHEMATICS
(2022)
Review
Plant Sciences
Md Mahadi Hasan, Nadiyah M. Alabdallah, Abdalrhaman M. Salih, Aisha S. Al-Shammari, Saleha Saeed ALZahrani, Ali H. Al Lawati, Mohammad Shah Jahan, Md Atikur Rahman, Xiang-Wen Fang
Summary: Starch, a type of carbohydrate commonly found in plants, is a major source of energy in human food. Drought and salinity can significantly affect starch content in economically important crop species. The effects of abiotic stress on starch accumulation vary depending on the plant type, duration of stress exposure, and specific environmental factors.
JOURNAL OF SOIL SCIENCE AND PLANT NUTRITION
(2023)
Article
Materials Science, Multidisciplinary
Meiling Wu, Ye Zhang, Lin Xu, Chunpeng Yang, Min Hong, Mingjin Cui, Bryson C. Clifford, Shuaiming He, Shuangshuang Jing, Yan Yao, Liangbing Hu
Summary: A chitosan-Zn electrolyte with high mechanical strength, Zn2+ conductivity, and water bonding capability is demonstrated for high-performance Zn-metal batteries. It enables desirable Zn-deposition morphology and shows exceptional cycling stability and rate performance.
Article
Chemistry, Applied
Yuyue Zhong, Yu Tian, Xingxun Liu, Li Ding, Jacob Judas Kain Kirkensgaard, Kim Hebelstrup, Jean-Luc Putaux, Andreas Blennow
Summary: The study showed that microwave treatment has different effects on the structure and properties of pure granular amylose (AM) and pure granular amylopectin (AP) starches. The crystallinity of AM starch initially increased then decreased, while that of AP starch decreased and then increased. Prolonged treatment of AM granules significantly increased resistant starch and water solubility.
FOOD HYDROCOLLOIDS
(2021)
Article
Chemistry, Physical
Cong Gao, Shuo Wang, Baojie Liu, Shuangquan Yao, Yi Dai, Long Zhou, Chengrong Qin, Pedram Fatehi
Summary: In this study, DANC was incorporated into chitosan to manufacture biodegradable films with enhanced gas barrier properties. The addition of DANC significantly improved the gas barrier performance and mechanical strength of the composite film. Chitosan/DANC films exhibited superior thermal stability and gas barrier compared to chitosan/CNC films.
Article
Biochemistry & Molecular Biology
Bin Wang, Guixin Zhang, Shouxin Yan, Xin Xu, Deyin Wang, Bo Cui, A. M. Abd El-Aty
Summary: This study explored the relationship between the chain structure of corn starch and the properties of corn starch-based films. The degree of gelatinization, chain length distribution, amylose content, and molecular weight of the corn starch were determined. The films formed with starch pastes showed changes in thickness, surface roughness, solubility, water content, water vapor permeability, mechanical properties, and maximum thermal degradation rate with increasing heat treatment temperature. The decrease in amylose content led to a change in the performance of the corn starch-based films.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Chemistry, Applied
Qian Liang, Qunyu Gao
Summary: This study proposed a green approach to prepare CM-starches/PUL nanofibers as encapsulates of thymol. The CM-starches from different corn starches were synthesized and studied, and PUL was used to obtain the CM-starches/PUL nanofibers. The electrospinning technique was used to encapsulate the CM-starches-thymol complex in the PUL nanofibers, resulting in nanofibers with increased diameter and improved thermal stability and encapsulation efficiency for thymol.
FOOD HYDROCOLLOIDS
(2023)
Article
Engineering, Chemical
Mayara L. Goiana, Fabiano A. N. Fernandes
Summary: This study evaluated the effects of dielectric barrier discharge (DBD) plasma technology on some physicochemical and structural properties of corn starch. The results showed that treatment with DBD plasma at 200 Hz significantly altered the properties of the starch, including the amylose content, solubility, water absorption index, and surface morphology.
Article
Plant Sciences
Ju-Kyung Yu, Yong-Sun Moon
Summary: Corn starch is a crucial food, feed, and industrial raw material. It comprises branched amylopectin and linear amylose, with the former accounting for about 75% and the latter for about 25% of corn starch. Breeding for improved starch quantity and quality has become a significant objective due to the development of specialty grain markets and increased demand for biofuel production.
Article
Polymer Science
Oscar Pulgarin, Dominique Larrea-Wachtendorff, Giovanna Ferrari
Summary: This study examines the effects of amylose/amylopectin content on the gelation of starch and the physical properties of hydrogels produced by HPP. The study also evaluates the impact of storage temperature and packaging type on the stability of hydrogels during a 30-day storage period. The results show that amylose has an antagonistic role in water absorption and gel formation, as well as the physical stability of hydrogels. A minimum amylose concentration of 20% is needed to form stable corn starch HPP hydrogels. Storage at a temperature of 20 degrees C and the use of polymeric bags are recommended for long-term storage of corn starch hydrogels.
Review
Food Science & Technology
Jana van Rooyen, Senay Simsek, Samson A. Oyeyinka, Marena Manley
Summary: Bread dough and bread are complex systems influenced by the interaction between starch polymers, flour components, and added ingredients. Starch, along with gluten proteins, plays a crucial role in determining the quality characteristics of the final baked product. Wheat starch, consisting of amylose and amylopectin, is organized in granules and interacts with various components during the breadmaking process. Understanding the starch structure-function relationship and the factors affecting it during dough formation, fermentation, baking, cooling, and storage is essential for comprehending the textural perception of bread.
COMPREHENSIVE REVIEWS IN FOOD SCIENCE AND FOOD SAFETY
(2023)
Article
Chemistry, Physical
Ashkan Bahadoran, Qinglei Liu, Saeid Masudy-Panah, Jeffrey Roshan De Lile, Seeram Ramakrishna, Ali Fakhri, Vinod Kumar Gupta
Summary: Ag-doped CoTiO3 (Ag-CTO) and Ag-doped CoTiO3/Chitosan-amylopectin (Ag-CTO/CSAP) were prepared using hydrothermal method for photocatalysis, showing a reduction in band-gap energy of Ag-CTO/CSAP nanocomposites and the highest catalytic activity for dye degradation. The nanocomposites have substantial bactericidal and fungicidal properties against specific microorganisms.
SURFACES AND INTERFACES
(2021)
Article
Chemistry, Multidisciplinary
Guobi Li, Rhett Smith, Milan Gembicky, Arnold L. Rheingold, John D. Protasiewicz
Summary: In this study, a di-hypervalent iodine compound was synthesized using a bulky 1,4-di-iodobenzene with four para-Bu-t-C6H4 group substituents. The compound underwent cyclization under mild conditions to form a dicyclic di-iodonium di-triflate salt. The introduction of para-tert-butyl groups improved the solubility of the compounds, making them more suitable for applications as recyclable reagents, materials precursors, and Lewis acids.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Claudia Lopez, Ashlyn D. Smith, Rhett C. Smith
Summary: In this study, high strength composites were prepared by reacting sulfur, plant oils, and brown grease. These composites exhibited impressive mechanical properties, making them a promising application for low value animal coproducts.
Article
Materials Science, Composites
Charini P. Maladeniya, Rhett C. Smith
Summary: Terpenoids are potentially sustainable replacements for petrochemical olefins and composites with attractive properties have been made from terpenoids and sulfur. The ratio of sulfur to terpenoid and the terpenoid olefin content significantly influence the thermal and mechanical properties of the composites, with compressive strength reaching up to 43 MPa for FarS(x) materials.
JOURNAL OF COMPOSITES SCIENCE
(2021)
Article
Polymer Science
Matthew J. Graham, Claudia V. Lopez, Charini P. Maladeniya, Andrew G. Tennyson, Rhett C. Smith
Summary: Low cost and high durability have made Portland cement the most widely-used building material, but its production contributes to 8-10% of CO2 emissions. High sulfur-content materials (HSMs) are greener alternatives with smaller carbon footprint and superior properties. The HSMs, CanS and SunS, prepared at low temperatures, exhibit high strength, low water uptake, and exceptional resistance to acid-induced corrosion. The polymer cement-pozzolan composites can be used as greener alternatives to traditional Portland cement.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Menisha S. Karunarathna, Charini P. Maladeniya, Moira K. Lauer, Andrew G. Tennyson, Rhett C. Smith
Summary: Productive utilization of lignocellulosic biomass is crucial, but the lack of upconversion methods for the lignin component is a major challenge. By esterifying lignin with oleic acid and reacting it with sulfur, a new protocol was developed to increase lignin hydrophobicity and incorporate it into sulfur-rich materials. The resulting esterified lignin-sulfur (ELS) composites exhibited high compressive strength values (>20 MPa) exceeding ordinary Portland cements, making them sustainable alternatives for durable composites.
Article
Materials Science, Composites
Katelyn A. Tisdale, Charini P. Maladeniya, Claudia V. Lopez, Andrew G. Tennyson, Rhett C. Smith
Summary: Sulfur cements that can be formed by the vulcanization of elemental sulfur and plant-derived olefins such as terpenoids are promising as sustainable binders. This study investigates the mechanical properties and chemical resistance of sulfur-terpenoid cements with the addition of pozzolan fines. The results show that the addition of pozzolans has varying effects on the compressional strength of the composites.
JOURNAL OF COMPOSITES SCIENCE
(2023)
Article
Polymer Science
Charini P. Maladeniya, Andrew G. Tennyson, Rhett C. Smith
Summary: Plastic waste poses a growing threat to the environment and human health, yet most of it is still disposed of in landfills. A disconnect between technology and implementation is hindering the recycling of plastic waste into valuable commodities. This study introduces a simple, single-stage process to chemically recycle PET into composite materials with properties comparable to commercial structural materials like Portland cement.
JOURNAL OF POLYMER SCIENCE
(2023)
Article
Materials Science, Composites
Perla Y. Sauceda-Olono, Ana C. Borbon-Almada, Martin Gaxiola, Ashlyn D. Smith, Andrew G. Tennyson, Rhett C. Smith
Summary: The production of Ordinary Portland Cement (OPC) consumes large amounts of water and energy, and releases significant amounts of CO2. Developing an alternative to OPC that requires no water, releases less CO2, and consumes less energy would be a transformative advancement in industrial decarbonization and greatly improve public health by increasing access to safe drinking water. However, any OPC alternative must meet or exceed the structural capabilities of OPC to be widely adopted.
JOURNAL OF COMPOSITES SCIENCE
(2023)
Article
Polymer Science
Katelyn M. Derr, Claudia V. Lopez, Charini P. Maladeniya, Andrew G. Tennyson, Rhett C. Smith
Summary: Despite improvements in chemical recycling, most post-consumer plastics are still deposited in landfills where they pose a significant threat to ecological health. Herein we report a two-stage method for chemically recycling PET using terpenoids and waste sulfur to yield composites. The resulting composites showed mechanical strengths comparable to commercial bricks, making them a viable alternative to existing building materials.
JOURNAL OF POLYMER SCIENCE
(2023)
Article
Materials Science, Multidisciplinary
Claudia V. Lopez, Rhett C. Smith
Summary: In this study, a three-stage process for the chemical recycling of PET was developed using sustainably-sourced organic materials and industrial byproduct sulfur. PET was first glycolyzed with diethylene glycol to produce low molecular weight oligomers, which were then esterified and vulcanized with oleoyl chloride and elemental sulfur, respectively. The resulting composites exhibited excellent mechanical properties comparable to existing commercial structural materials.
MATERIALS ADVANCES
(2023)
Article
Polymer Science
Katelyn M. Derr, Rhett C. Smith
Summary: A method of chemically upcycling polycarbonate while dismantling endocrine-disrupting BPA units is reported, using elemental sulfur to produce structurally viable building materials.
JOURNAL OF POLYMER SCIENCE
(2023)
Article
Polymer Science
Shalini K. Wijeyatunga, Katelyn M. Derr, Charini P. Maladeniya, Perla Y. Sauceda-Olono, Andrew G. Tennyson, Rhett C. Smith
Summary: This study presents a two-stage chemical upcycling process for Poly(methyl methacrylate) (PMMA). By modifying PMMA with a bio-derived olefin-bearing terpenoid and reacting it with sulfur, a durable composite with mechanical properties competitive with traditional building materials is obtained.
JOURNAL OF POLYMER SCIENCE
(2023)
Article
Materials Science, Multidisciplinary
Moira K. Lauer, Andrew G. Tennyson, Rhett C. Smith
Summary: In this study, vulcanized starch composites were prepared through modification and sulfuration of starch. The esterified starch derivatives contain more crosslinkable carbon atoms, resulting in lower stiffness and higher strength.
MATERIALS ADVANCES
(2022)
Article
Materials Science, Multidisciplinary
Moira K. Lauer, Zoe E. Sanders, Ashlyn D. Smith, Rhett C. Smith
Summary: This study evaluated the influence of lignocellulose biomass particle size on the properties of biomass-sulfur composites. It was found that composites prepared with biomass particles of defined size ranges exhibited faster reaction rates and maintained excellent strength characteristics. While composites prepared with smaller particles showed better dispersion, similar ultimate strength characteristics were observed for most composites regardless of particle size.
MATERIALS ADVANCES
(2021)
Article
Materials Science, Multidisciplinary
Moira K. Lauer, Andrew G. Tennyson, Rhett C. Smith
Summary: The method of preparing recyclable thermoplastic materials using sulfur-starch composites is novel. These composites have high extractable sulfur content and reasonable thermal stability, and exhibit high flexural strength due to their relatively low crosslink density.
MATERIALS ADVANCES
(2021)