Organocatalytic Enantioselective Synthesis of Chiral Allenes: Remote Asymmetric 1,8‐Addition of Indole Imine Methides

Remote Stereocontrolled Construction of Vicinal Axially Chiral Tetrasubstituted Allenes and Heteroatom-Functionalized Quaternary Carbon Stereocenters

(2019) Pei Zhang et al.   ORGANIC LETTERS

Catalytic Asymmetric (4+3) Cyclizations of In Situ Generated ortho -Quinone Methides with 2-Indolylmethanols

(2019) Meng Sun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective House–Meinwald Rearrangement: Efficient Construction of All-Carbon Quaternary Stereocenters

(2019) Dengke Ma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Enantioconvergent Synthesis of Tetrasubstituted Allenes via Asymmetric 1,8-Addition to aza-para-Quinone Methides

(2019) Min Chen et al.   ORGANIC LETTERS

Tetrasubstituted allenes via the palladium-catalysed kinetic resolution of propargylic alcohols using a supporting ligand

(2019) Wei-Feng Zheng et al.   Nature Catalysis

Organocatalytic Enantioselective Synthesis of Tetrasubstituted α-Amino Allenoates by Dearomative γ-Addition of 2,3-Disubstituted Indoles to β,γ-Alkynyl-α-imino Esters

(2019) Junxian Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cyclohexyl-Fused, Spirobiindane-Derived, Phosphine-Catalyzed Synthesis of Tricyclic γ-Lactams and Kinetic Resolution of γ-Substituted Allenoates

(2019) Mingyue Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Asymmetric Synthesis of Indole-Based Chiral Heterocycles: Strategies, Reactions, and Outreach

(2019) Yu-Chen Zhang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Chiral Phosphoric Acid Catalyzed Asymmetric Synthesis of Hetero-triarylmethanes from Racemic Indolyl Alcohols

(2018) Caizhen Yue et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperative Catalysis-Enabled Asymmetric α-Arylation of Aldehydes Using 2-Indolylmethanols as Arylation Reagents

(2018) Meng-Meng Xu et al.   JOURNAL OF ORGANIC CHEMISTRY

Application of 7-Indolylmethanols in Catalytic Asymmetric Arylations with Tryptamines: Enantioselective Synthesis of 7-indolylmethanes

(2018) Hai-Qing Wang et al.   ADVANCED SYNTHESIS & CATALYSIS

γ-Regioselective Functionalization of 3-Alkenylindoles via 1,6-Addition to Extended Alkylideneindolenine Intermediates

(2018) Giulio Bertuzzi et al.   ADVANCED SYNTHESIS & CATALYSIS

Tri(o-tolyl)phosphine for highly efficient Suzuki coupling of propargylic carbonates with boronic acids

(2018) Junzhe Xiao et al.   CHEMICAL COMMUNICATIONS

Enantioselective Synthesis of Allenes by Catalytic Traceless Petasis Reactions

(2017) Yao Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Thioureas Promote Enantioselective Pictet–Spengler Cyclization by Stabilizing Every Intermediate and Transition State in the Carboxylic Acid-Catalyzed Reaction

(2017) Rebekka S. Klausen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Direct α-Arylation of Pyrazol-5-ones with 2-Indolylmethanols via Organo-Metal Cooperative Catalysis

(2017) Zi-Qi Zhu et al.   ORGANIC LETTERS

Organocatalytic synthesis of chiral tetrasubstituted allenes from racemic propargylic alcohols

(2017) Deyun Qian et al.   Nature Communications

Recent advances in catalytic asymmetric synthesis of allenes

(2017) Wen-Dao Chu et al.   Catalysis Science & Technology

Chiral Allenes via Alkynylogous Mukaiyama Aldol Reaction

(2016) Aurélien Tap et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Design and Enantioselective Construction of Axially Chiral Naphthyl-Indole Skeletons

(2016) Hong-Hao Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sulfonyl Azoles in the Synthesis of 3-Functionalized Azole Derivatives

(2016) Alessandro Palmieri et al.   CHEMICAL RECORD

Brønsted Acid Catalyzed [3+2]-Cycloaddition of 2-Vinylindoles with In Situ Generated 2-Methide-2H-indoles: Highly Enantioselective Synthesis of Pyrrolo[1,2-a]indoles

(2016) Kalisankar Bera et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Synthesis of Trisubstituted Allenes via Cu(I)-Catalyzed Coupling of Diazoalkanes with Terminal Alkynes

(2016) Wen-Dao Chu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-Catalyzed Stereospecific Synthesis of Allenes from Propargylic Benzoates and Arylboronic Acids

(2016) Jonathan Ruchti et al.   ORGANIC LETTERS

Brønsted Acid Catalyzed [3 + 2]-Cycloaddition of Cyclic Enamides with in Situ Generated 2-Methide-2H-indoles: Enantioselective Synthesis of Indolo[1,2-a]indoles

(2016) Kalisankar Bera et al.   ORGANIC LETTERS

Chirality transfer in metal-catalysed intermolecular addition reactions involving allenes

(2016) José Miguel Alonso et al.   Organic Chemistry Frontiers

Suzuki coupling for preparation of allenes – ligand effects and chirality transfer

(2016) Hongwen Luo et al.   Organic Chemistry Frontiers

Direct Synthesis of Chiral Allenoates from the Asymmetric CH Insertion of α-Diazoesters into Terminal Alkynes

(2015) Yu Tang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric 1,6-Conjugate Addition ofpara-Quinone Methides: Formation of All-Carbon Quaternary Stereocenters

(2015) Zhaobin Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphoric Acid Catalyzed Asymmetric 1,6-Conjugate Addition of Thioacetic Acid to para -Quinone Methides

(2015) Nan Dong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Development and Applications of Disulfonimides in Enantioselective Organocatalysis

(2015) Thomas James et al.   CHEMICAL REVIEWS

Stronger Brønsted Acids: Recent Progress

(2015) Takahiko Akiyama et al.   CHEMICAL REVIEWS

Strategies for the asymmetric functionalization of indoles: an update

(2015) Renato Dalpozzo   CHEMICAL SOCIETY REVIEWS

Mechanistic Insights into a BINOL-Derived Phosphoric Acid-Catalyzed Asymmetric Pictet–Spengler Reaction

(2015) Lois M. Overvoorde et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Highly Substituted Racemic and Enantioenriched Allenylsilanes via Copper-Catalyzed Hydrosilylation of (Z)-2-Alken-4-ynoates with Silylboronate

(2015) Min Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A C–H bond activation-based catalytic approach to tetrasubstituted chiral allenes

(2015) Shangze Wu et al.   Nature Communications

Chiral phosphoramide-catalyzed enantioselective synthesis of 2,3′-diindolylarylmethanes from indol-2-yl carbinols and indoles

(2014) Shuai Qi et al.   CHEMICAL COMMUNICATIONS

Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates

(2014) Dixit Parmar et al.   CHEMICAL REVIEWS

Biotransformations of Racemic 2,3-Allenenitriles in Biphasic Systems: Synthesis and Transformations of Enantioenriched Axially Chiral 2,3-Allenoic Acids and Their Derivatives

(2014) Yu-Fei Ao et al.   JOURNAL OF ORGANIC CHEMISTRY

Diastereo- and Enantioselective Addition of Anilide-Functionalized Allenoates to N-Acylimines Catalyzed by a Pyridylalanine-Based Peptide

(2014) Curren T. Mbofana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the Mechanism of Cu-Catalyzed Enantioselective Extended Conjugate Additions: A Structure-Based Approach

(2014) Tim den Hartog et al.   ACS Catalysis

Alkylideneindoleninium Ions and Alkylideneindolenines: Key Intermediates for the Asymmetric Synthesis of 3-Indolyl Derivatives

(2014) Liang Wang et al.   Asian Journal of Organic Chemistry

Conquering three-carbon axial chirality of allenes

(2014) Juntao Ye et al.   Organic Chemistry Frontiers

Asymmetric Catalytic 1,6-Conjugate Addition/Aromatization ofpara-Quinone Methides: Enantioselective Introduction of Functionalized Diarylmethine Stereogenic Centers

(2013) Wen-Dao Chu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Room-Temperature Catalytic Asymmetric Synthesis of Allenes with ECNU-Phos

(2013) Yuli Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Asymmetric β-Hydride Elimination en Route to Chiral Allenes

(2013) Ian T. Crouch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Enantioselective Synthesis of 2,3-Allenoates by Intermolecular Addition of Nitroalkanes to Activated Enynes

(2013) Hui Qian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phase-transfer-catalysed asymmetric synthesis of tetrasubstituted allenes

(2013) Takuya Hashimoto et al.   Nature Chemistry

Recent Advances in the Catalytic Syntheses of Allenes: A Critical Assessment

(2013) Robynne K. Neff et al.   ACS Catalysis

Allenes in Molecular Materials

(2012) Pablo Rivera-Fuentes et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Decarboxylative Amination: Synthesis of Axially Chiral Allenyl Amines

(2012) Baoqiang Wan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Allenes in Catalytic Asymmetric Synthesis and Natural Product Syntheses

(2012) Shichao Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Regio-, Diastereo-, and Enantioselective 1,6- and 1,8-Additions of Azlactones to Di- and Trienyl N-Acylpyrroles

(2012) Daisuke Uraguchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Conjugated Allenes through Copper-Catalyzed γ-Selective and Stereospecific Coupling between Propargylic Phosphates and Aryl- or Alkenylboronates

(2012) Mingyu Yang et al.   ORGANIC LETTERS

Chiral Allene-Containing Phosphines in Asymmetric Catalysis

(2011) Feng Cai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of Trisubstituted Allenes: Copper-Catalyzed Alkylation and Arylation of Propargylic Phosphates

(2011) Mycah R. Uehling et al.   ORGANIC LETTERS

Chemoselective Cascade Synthesis of N-Fused Heterocycles via Silver(I) Triflate-Catalyzed Friedel-Crafts/N-C Bond Formation Sequence

(2010) Lu Hao et al.   ADVANCED SYNTHESIS & CATALYSIS

Marine Indole Alkaloids: Potential New Drug Leads for the Control of Depression and Anxiety

(2010) Anna J. Kochanowska-Karamyan et al.   CHEMICAL REVIEWS

Organocatalytic strategies for the asymmetric functionalization of indoles

(2010) Giuseppe Bartoli et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective Bromolactonization of Conjugated (Z)-Enynes

(2010) Wei Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Kinetic Resolution of Racemic 2,3-Allenoates by Organocatalytic Asymmetric 1,3-Dipolar Cycloaddition

(2010) Jie Yu et al.   ORGANIC LETTERS

Silver(i)-mediated highly enantioselective synthesis of axially chiral allenes under thermal and microwave-assisted conditions

(2009) Vanessa Kar-Yan Lo et al.   CHEMICAL COMMUNICATIONS

Enantioselective Synthesis of Chiral Allenoates by Guanidine-Catalyzed Isomerization of 3-Alkynoates

(2009) Hongjun Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Allenes in Asymmetric Catalysis: Asymmetric Ring Opening ofmeso-Epoxides Catalyzed by Allene-Containing Phosphine Oxides

(2009) Xiaotao Pu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enzymatic kinetic resolution of primary allenic alcohols. Application to the total synthesis and stereochemical assignment of striatisporolide A

(2009) Jan Deska et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of 3-substituted indoles via reactive alkylideneindolenine intermediates

(2009) Alessandro Palmieri et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Highly Enantioselective Alkylation Reaction of Enamides by Brønsted-Acid Catalysis

(2009) Qi-Xiang Guo et al.   ORGANIC LETTERS

Catalytic enantioselective synthesis of axially chiral allenes

(2009) Masamichi Ogasawara   TETRAHEDRON-ASYMMETRY

Direct and Stereospecific Synthesis of Allenes via Reduction of Propargylic Alcohols with Cp2Zr(H)Cl

(2008) Xiaotao Pu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY