Cross-Coupling of Organolithium with Ethers or Aryl Ammonium Salts by C−O or C−N Bond Cleavage

Phenyltrimethylammonium Salts as Methylation Reagents in the Nickel-Catalyzed Methylation of C−H Bonds

(2016) Takeshi Uemura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Carboxylation of Benzylic C−N Bonds with CO2

(2016) Toni Moragas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed, tert- Butyllithium-Mediated Dimerization of Aryl Halides and Its Application in the Atropselective Total Synthesis of Mastigophorene A

(2016) Jeffrey Buter et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis Acid Assisted Nickel-Catalyzed Cross-Coupling of Aryl Methyl Ethers by C−O Bond-Cleaving Alkylation: Prevention of Undesired β-Hydride Elimination

(2016) Xiangqian Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Cross-Coupling of Organolithium Reagents with (Hetero)Aryl Electrophiles

(2016) Dorus Heijnen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Tandem C(sp2)–OMe Activation/C(sp2)–C(sp2) Coupling in Early Transition-Metal Complexes: Aromatic C–O Activation beyond Late Transition Metals

(2016) Vasily Radkov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Developments in Negishi Cross-Coupling Reactions

(2016) Diana Haas et al.   ACS Catalysis

Density Functional Study of Nickel N-Heterocyclic Carbene Catalyzed C–O Bond Hydrogenolysis of Methyl Phenyl Ether: The Concerted β-H Transfer Mechanism

(2016) Taveechai Wititsuwannakul et al.   ACS Catalysis

Nickel-Catalyzed Cross-Coupling of (Hetero)aryl Chlorides with Aryllithium Compounds

(2016) Jian-Long Tao et al.   Asian Journal of Organic Chemistry

Stereospecific Nickel-Catalyzed Cross-Coupling Reactions of Benzylic Ethers and Esters

(2015) Emily J. Tollefson et al.   ACCOUNTS OF CHEMICAL RESEARCH

Exploration of Earth-Abundant Transition Metals (Fe, Co, and Ni) as Catalysts in Unreactive Chemical Bond Activations

(2015) Bo Su et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cross-Couplings Using Aryl Ethers via C–O Bond Activation Enabled by Nickel Catalysts

(2015) Mamoru Tobisu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Ruthenium-Catalyzed Monoalkenylation of Aromatic Ketones by Cleavage of Carbon-Heteroatom Bonds with Unconventional Chemoselectivity

(2015) Hikaru Kondo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Allylic Alkylation with Diarylmethane Pronucleophiles: Reaction Development and Mechanistic Insights

(2015) Sheng-Chun Sha et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel catalyzed dealkoxylative Csp2–Csp3 cross coupling reactions – stereospecific synthesis of allylsilanes from enol ethers

(2015) Lin Guo et al.   CHEMICAL COMMUNICATIONS

Transition-Metal-Catalyzed Cleavage of C–N Single Bonds

(2015) Kunbing Ouyang et al.   CHEMICAL REVIEWS

Nickel-catalyzed Cross-coupling of Anisole Derivatives with Trimethylaluminum through the Cleavage of Carbon–Oxygen Bonds

(2015) Toshifumi Morioka et al.   CHEMISTRY LETTERS

How and Why Does Ni0Promote Smooth Etheric CO Bond Cleavage and CC Bond Formation? A Theoretical Study

(2015) Hiroyuki Ogawa et al.   CHEMISTRY-A EUROPEAN JOURNAL

tBuLi-Mediated One-Pot Direct Highly Selective Cross-Coupling of Two Distinct Aryl Bromides

(2015) Carlos Vila et al.   CHEMISTRY-A EUROPEAN JOURNAL

Making Dimethylamino a Transformable Directing Group by Nickel-Catalyzed CN Borylation

(2015) Hua Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nickel-Catalyzed Borylation of Aryl- and Benzyltrimethylammonium Salts via C–N Bond Cleavage

(2015) Jiefeng Hu et al.   JOURNAL OF ORGANIC CHEMISTRY

Regio- and Chemoselective Kumada–Tamao–Corriu Reaction of Aryl Alkyl Ethers Catalyzed by Chromium Under Mild Conditions

(2015) Xuefeng Cong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Borylation of Aryl 2-Pyridyl Ethers through Cleavage of the Carbon–Oxygen Bond: Borylative Removal of the Directing Group

(2015) Hirotaka Kinuta et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed C(sp3)–C(sp2) Cross-Coupling of (Trimethylsilyl)methyllithium with (Hetero)Aryl Halides

(2015) Dorus Heijnen et al.   ORGANIC LETTERS

Palladium-Catalyzed C–H Arylation of (Benzo)oxazoles or (Benzo)thiazoles with Aryltrimethylammonium Triflates

(2015) Feng Zhu et al.   ORGANIC LETTERS

Nickel-Catalyzed Cross-Coupling of Anisoles with Alkyl Grignard Reagents via C–O Bond Cleavage

(2015) Mamoru Tobisu et al.   ORGANIC LETTERS

Nickel-Catalyzed Alkynylation of Anisoles via C–O Bond Cleavage

(2015) Mamoru Tobisu et al.   ORGANIC LETTERS

Mixed NHC/Phosphine Ni(II) Complexes: Synthesis and Their Applications as Versatile Catalysts for Selective Cross-Couplings of ArMgX with Aryl Chlorides, Fluorides, and Methyl Ethers

(2015) Jie Zhang et al.   ORGANOMETALLICS

Sieving hydrogen isotopes through two-dimensional crystals

(2015) M. Lozada-Hidalgo et al.   SCIENCE

Direct catalytic cross-coupling of alkenyllithium compounds

(2015) Valentín Hornillos et al.   Chemical Science

Metal-Catalyzed Dealkoxylative CarylC sp 3 Cross-Coupling-Replacement of Aromatic Methoxy Groups of Aryl Ethers by Employing a Functionalized Nucleophile

(2014) Matthias Leiendecker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Expanding the Synthetic Portfolio of Organolithiums: Direct Use in Catalytic Cross-Coupling Reactions

(2014) Vittorio Pace et al.   ChemCatChem

Metal-catalyzed activation of ethers via C–O bond cleavage: a new strategy for molecular diversity

(2014) Josep Cornella et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalysed Direct Cross-Coupling of Organolithium Reagents with Aryl and Vinyl Triflates

(2014) Carlos Vila et al.   CHEMISTRY-A EUROPEAN JOURNAL

Beyond Directed ortho Metalation: Ru-Catalyzed CAr–O Activation/Cross-Coupling Reaction by Amide Chelation

(2014) Yigang Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Mild Ni/Cu-Catalyzed Silylation via C–O Cleavage

(2014) Cayetana Zarate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereospecific Cross-Coupling Reactions of Aryl-Substituted Tetrahydrofurans, Tetrahydropyrans, and Lactones

(2014) Emily J. Tollefson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in homogeneous nickel catalysis

(2014) Sarah Z. Tasker et al.   NATURE

Pd-Catalyzed Cross-Coupling of Aryllithium Reagents with 2-Alkoxy-Substituted Aryl Chlorides: Mild and Efficient Synthesis of 3,3′-Diaryl BINOLs

(2014) Luis M. Castelló et al.   ORGANIC LETTERS

1,3-Dicyclohexylimidazol-2-ylidene as a Superior Ligand for the Nickel-Catalyzed Cross-Couplings of Aryl and Benzyl Methyl Ethers with Organoboron Reagents

(2014) Mamoru Tobisu et al.   ORGANIC LETTERS

Chelation-Assisted Regioselective Catalytic Functionalization of C–H, C–O, C–N and C–F Bonds

(2014) Fumitoshi Kakiuchi et al.   SYNLETT

Structural and reactivity insights in Mg–Zn hybrid chemistry: Zn–I exchange and Pd-catalysed cross-coupling applications of aromatic substrates

(2014) Tobias D. Bluemke et al.   Chemical Science

Hindered Aryllithium Reagents as Partners in Palladium-Catalyzed Cross-Coupling: Synthesis of Tri- and Tetra-ortho-Substituted Biaryls under Ambient Conditions

(2013) Massimo Giannerini et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An efficient cleavage of the aryl ether C–O bond in supercritical carbon dioxide–water

(2013) Maya Chatterjee et al.   CHEMICAL COMMUNICATIONS

Fe-promoted cross coupling of homobenzylic methyl ethers with Grignard reagents via sp3 C–O bond cleavage

(2013) Shuang Luo et al.   CHEMICAL COMMUNICATIONS

Mixed AggregAte (MAA): A Single Concept for All Dipolar Organometallic Aggregates. 1. Structural Data

(2013) Anne Harrison-Marchand et al.   CHEMICAL REVIEWS

Mixed AggregAte (MAA): A Single Concept for All Dipolar Organometallic Aggregates. 2. Syntheses and Reactivities of Homo/HeteroMAAs

(2013) Florence Mongin et al.   CHEMICAL REVIEWS

Role of Organolithium Aggregates and Mixed Aggregates in Organolithium Mechanisms

(2013) Hans J. Reich   CHEMICAL REVIEWS

An alternative picture of alkali-metal-mediated metallation: cleave and capture chemistry

(2013) Robert E. Mulvey   DALTON TRANSACTIONS

Murahashi Coupling Polymerization: Nickel(II)–N-Heterocyclic Carbene Complex-Catalyzed Polycondensation of Organolithium Species of (Hetero)arenes

(2013) Kanta Fuji et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combined Experimental and Theoretical Study on the Reductive Cleavage of Inert C–O Bonds with Silanes: Ruling out a Classical Ni(0)/Ni(II) Catalytic Couple and Evidence for Ni(I) Intermediates

(2013) Josep Cornella et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Functional-Group-Tolerant, Nickel-Catalyzed Cross-Coupling Reaction for Enantioselective Construction of Tertiary Methyl-Bearing Stereocenters

(2013) Hanna M. Wisniewska et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct catalytic cross-coupling of organolithium compounds

(2013) Massimo Giannerini et al.   Nature Chemistry

Catalytic Direct Cross-Coupling of Organolithium Compounds with Aryl Chlorides

(2013) Valentín Hornillos et al.   ORGANIC LETTERS

Programmed Selective sp2 C–O Bond Activation toward Multiarylated Benzenes

(2013) Fei Zhao et al.   ORGANIC LETTERS

Ni-Catalyzed Stereoselective Arylation of Inert C–O bonds at Low Temperatures

(2013) Josep Cornella et al.   ORGANIC LETTERS

Palladium-catalysed direct cross-coupling of secondary alkyllithium reagents

(2013) Carlos Vila et al.   Chemical Science

Synthesis of Enantioenriched Triarylmethanes by Stereospecific Cross-Coupling Reactions

(2012) Buck L. H. Taylor et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Cross-Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize

(2012) Carin C. C. Johansson Seechurn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aryl Ether as a Negishi Coupling Partner: An Approach for Constructing CC Bonds under Mild Conditions

(2012) Chao Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Unification of Anion Relay Chemistry with the Takeda and Hiyama Cross-Coupling Reactions: Identification of an Effective Silicon-Based Transfer Agent

(2012) Amos B. Smith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Mediated Hydrogenolysis of C–O Bonds of Aryl Ethers: What Is the Source of the Hydrogen?

(2012) Paul Kelley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Cross Couplings of Benzylic Ammonium Salts and Boronic Acids: Stereospecific Formation of Diarylethanes via C–N Bond Activation

(2012) Prantik Maity et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Kumada–Tamao–Corriu Coupling of Heteroaromatic Chlorides and Aryl Ethers Catalyzed by (IPr)Ni(allyl)Cl

(2012) María José Iglesias et al.   ORGANIC LETTERS

Ni(0)/NHC-catalyzed amination of N-heteroaryl methyl ethers through the cleavage of carbon‒oxygen bonds

(2012) Mamoru Tobisu et al.   TETRAHEDRON

Nickel-Catalyzed Cross-Coupling of Aryltrimethylammonium Iodides with Organozinc Reagents

(2011) Lan-Gui Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-catalyzed reductive cleavage of aryl–oxygen bonds in alkoxy- and pivaloxyarenes using hydrosilanes as a mild reducing agent

(2011) Mamoru Tobisu et al.   CHEMICAL COMMUNICATIONS

Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners

(2011) Ranjan Jana et al.   CHEMICAL REVIEWS

Cross-coupling of Aryl/Alkenyl Silyl Ethers with Grignard Reagents through Nickel-catalyzed C–O Bond Activation

(2011) Fei Zhao et al.   CHEMISTRY LETTERS

Cross-Coupling of Aryl/Alkenyl Ethers with Aryl Grignard Reagents through Nickel-Catalyzed CO Activation

(2011) Lan-Gui Xie et al.   CHEMISTRY-A EUROPEAN JOURNAL

Activation of “Inert” Alkenyl/Aryl CO Bond and Its Application in Cross-Coupling Reactions

(2011) Bi-Jie Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Selective, Nickel-Catalyzed Hydrogenolysis of Aryl Ethers

(2011) A. G. Sergeev et al.   SCIENCE

1,4-Dilithio-1,3-dienes: Reaction and Synthetic Applications

(2010) Zhenfeng Xi   ACCOUNTS OF CHEMICAL RESEARCH

Cross-Coupling in a Flow Microreactor: Space Integration of Lithiation and Murahashi Coupling

(2010) Aiichiro Nagaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Cross-Couplings Involving Carbon−Oxygen Bonds

(2010) Brad M. Rosen et al.   CHEMICAL REVIEWS

MeLi + LiCl in THF: One Heterodimer and No Tetramers†

(2010) Baptiste Lecachey et al.   JOURNAL OF ORGANIC CHEMISTRY

Ni-Catalyzed Reduction of Inert C−O Bonds: A New Strategy for Using Aryl Ethers as Easily Removable Directing Groups

(2010) Paula Álvarez-Bercedo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereospecific Nickel-Catalyzed Cross-Coupling Reactions of Alkyl Ethers: Enantioselective Synthesis of Diarylethanes

(2010) Buck L. H. Taylor et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Room Temperature Palladium-Catalyzed Cross Coupling of Aryltrimethylammonium Triflates with Aryl Grignard Reagents

(2010) Jonathan T. Reeves et al.   ORGANIC LETTERS

Avant-Garde Metalating Agents: Structural Basis of Alkali-Metal-Mediated Metalation

(2009) Robert E. Mulvey   ACCOUNTS OF CHEMICAL RESEARCH

Aminations of allylic phenyl ethers via micellar catalysis at room temperature in water

(2009) Takashi Nishikata et al.   CHEMICAL COMMUNICATIONS

Ni0-catalyzed Direct Amination of Anisoles Involving the Cleavage of Carbon–Oxygen Bonds

(2009) Mamoru Tobisu et al.   CHEMISTRY LETTERS

Nickel-Catalyzed Cross-Coupling of Aryl Methyl Ethers with Aryl Boronic Esters

(2008) Mamoru Tobisu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Methylation of arenes via Ni-catalyzed aryl C–O/F activation

(2008) Bing-Tao Guan et al.   CHEMICAL COMMUNICATIONS

Development of Highly Chemoselective Bulky Zincate Complex,tBu4ZnLi2: Design, Structure, and Practical Applications in Small-/Macromolecular Synthesis

(2008) Taniyuki Furuyama et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct Benzylic Alkylation via Ni-Catalyzed Selective Benzylic sp3C−O Activation

(2008) Bing-Tao Guan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Generation and Suppression of 3-/4-Functionalized Benzynes Using Zinc Ate Base (TMP−Zn−ate):  New Approaches to Multisubstituted Benzenes

(2007) Masanobu Uchiyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY