期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 16, 页码 5053-5057出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201600697
关键词
carboxylation; C-N activation; homogeneous catalysis; nickel; reductive coupling
资金
- ICIQ
- European Research Council [ERC-277883]
- MINECO [CTQ2012-34054, SEV-2013-0319]
- Cellex Foundation
- ICREA Funding Source: Custom
A user-friendly Ni-catalyzed reductive carboxylation of benzylic C-N bonds with CO2 is described. This procedure outperforms state-of-the-art techniques for the carboxylation of benzyl electrophiles by avoiding commonly observed parasitic pathways, such as homodimerization or -hydride elimination, thus leading to new knowledge in cross-electrophile reactions.
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