Copper-Catalyzed Transformations Using Cu-H, Cu-B, and Cu-Si as Active Catalyst Species

Copper Catalysis for Synthesizing Main-Group Organometallics Containing B, Sn or Si

(2016) Hiroto Yoshida   CHEMICAL RECORD

Copper-catalyzed C–C bond-forming transformation of CO2 to alcohol oxidation level: selective synthesis of homoallylic alcohols from allenes, CO2, and hydrosilanes

(2015) Yosuke Tani et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed Silylative Allylation of Ketones and Aldehydes Employing Allenes and Silylboranes

(2015) Yosuke Tani et al.   CHEMISTRY LETTERS

Ligand-Controlled Regiodivergent Cu-Catalyzed Aminoboration of Unactivated Terminal Alkenes

(2015) Ryosuke Sakae et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Semihydrogenation of Alkynes to Z-Alkenes

(2015) Kazuhiko Semba et al.   SYNLETT

Copper-catalyzed borylative transformations of non-polar carbon–carbon unsaturated compounds employing borylcopper as an active catalyst species

(2015) Kazuhiko Semba et al.   TETRAHEDRON

Copper-Catalyzed Borylative Allyl-Allyl Coupling Reaction

(2014) Kazuhiko Semba et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unlocking theN2 Selectivity of Benzotriazoles: Regiodivergent and Highly Selective Coupling of Benzotriazoles with Allenes

(2014) Kun Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atom-Economic, Regiodivergent, and Stereoselective Coupling of Imidazole Derivatives with Terminal Allenes

(2014) Kun Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd/C-catalyzed direct formylation of aromatic iodides to aryl aldehydes using carbon dioxide as a C1 resource

(2014) Bo Yu et al.   CHEMICAL COMMUNICATIONS

Cu(I)-NHC-Catalyzed Silylation of Allenes: Diastereoselective Three-Component Coupling with Aldehydes

(2014) James Rae et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regiocontrolled Palladium-Catalyzed Arylative Cyclizations of Alkynols

(2014) Daishi Fujino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Regiodivergent Silacarboxylation of Allenes with Carbon Dioxide and a Silylborane

(2014) Yosuke Tani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Controlled Regiodivergent Ni-Catalyzed Reductive Carboxylation of Allyl Esters with CO2

(2014) Toni Moragas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multifunctional organoboron compounds for scalable natural product synthesis

(2014) Fanke Meng et al.   NATURE

Regioselective Allene Hydroarylation via One-Pot Allene Hydrosilylation/Pd-Catalyzed Cross-Coupling

(2014) Zachary D. Miller et al.   ORGANIC LETTERS

Cu(I)/Cu(III) catalytic cycle involved in Ullmann-type cross-coupling reactions

(2014) Xavi Ribas et al.   PURE AND APPLIED CHEMISTRY

Three-Component Carboboration of Alkenes under Copper Catalysis

(2014) Hiroto Yoshida et al.   SYNTHESIS-STUTTGART

1,3-Diyne chemistry: synthesis and derivations

(2014) Wei Shi et al.   TETRAHEDRON LETTERS

Regioselective transformation of alkynes catalyzed by a copper hydride or boryl copper species

(2014) Tetsuaki Fujihara et al.   Catalysis Science & Technology

Cu-Catalyzed Chemoselective Preparation of 2-(Pinacolato)boron-Substituted Allylcopper Complexes and their In Situ Site-, Diastereo-, and Enantioselective Additions to Aldehydes and Ketones

(2013) Fanke Meng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Borylation of α-Alkoxy Allenes with Bis(pinacolato)diboron: Efficient Synthesis of 2-Boryl 1,3-Butadienes

(2013) Kazuhiko Semba et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Amide-Controlled Highly Selective Catalytic Borylcupration of Allenes

(2013) Weiming Yuan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Selective Copper-Catalyzed Hydroboration of Allenes and 1,3-Dienes

(2013) Kazuhiko Semba et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cu-Catalyzed Asymmetric Borylative Cyclization of Cyclohexadienone-Containing 1,6-Enynes

(2013) Ping Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective Allene Hydrosilylation Catalyzed by N-Heterocyclic Carbene Complexes of Nickel and Palladium

(2013) Zachary D. Miller et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fe-Catalyzed Regiodivergent [1,2]-Shift of α-Aryl Aldehydes

(2013) Álvaro Gutiérrez-Bonet et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides

(2013) Yang Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Regiodivergent Opening of Epoxides with Aryl Halides: Co-Catalysis Controls Regioselectivity

(2013) Yang Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Borylative exo-Cyclization of Alkenyl Halides Containing Unactivated Double Bond

(2013) Koji Kubota et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regiodivergent Access to Five- and Six-Membered Benzo-Fused Lactams: Ru-Catalyzed Olefin Hydrocarbamoylation

(2013) Bin Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Three-Component Carboboration of Alkynes and Alkenes

(2013) Hiroto Yoshida et al.   ORGANIC LETTERS

NHC–Cu-Catalyzed Protoboration of Monosubstituted Allenes. Ligand-Controlled Site Selectivity, Application to Synthesis and Mechanism

(2013) Fanke Meng et al.   ORGANIC LETTERS

The role of organometallic copper(iii) complexes in homogeneous catalysis

(2013) Alicia Casitas et al.   Chemical Science

Homogeneous hydrogenation of carbon dioxide to methanol

(2013) Yu-Nong Li et al.   Catalysis Science & Technology

Copper(I)-Catalyzed Boron Addition Reactions of Alkynes with Diboron Reagents

(2013) Jaesook Yun   Asian Journal of Organic Chemistry

Ligand Controlled Highly Selective Copper-Catalyzed Borylcuprations of Allenes with Bis(pinacolato)diboron

(2012) Weiming Yuan et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-Catalyzed Highly Selective Semihydrogenation of Non-Polar Carbon-Carbon Multiple Bonds using a Silane and an Alcohol

(2012) Kazuhiko Semba et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-Catalyzed Silacarboxylation of Internal Alkynes by Employing Carbon Dioxide and Silylboranes

(2012) Tetsuaki Fujihara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbon dioxide as a carbon source in organic transformation: carbon–carbon bond forming reactions by transition-metal catalysts

(2012) Yasushi Tsuji et al.   CHEMICAL COMMUNICATIONS

Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis

(2012) Martin Oestreich et al.   CHEMICAL REVIEWS

Copper-Catalyzed Highly Regio- and Stereoselective Directed Hydroboration of Unsymmetrical Internal Alkynes: Controlling Regioselectivity by Choice of Catalytic Species

(2012) Kazuhiko Semba et al.   CHEMISTRY-A EUROPEAN JOURNAL

Activation of Si-Si Bonds for Copper(I)-Catalyzed Conjugate Silylation

(2012) Laura Iannazzo et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Enantioselective Allylic Substitution with Alkylboranes

(2012) Yoshinori Shido et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible 1,3-anti/syn-Stereochemical Courses in Copper-Catalyzed γ-Selective Allyl–Alkyl Coupling between Chiral Allylic Phosphates and Alkylboranes

(2012) Kazunori Nagao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site- and Enantioselective Formation of Allene-Bearing Tertiary or Quaternary Carbon Stereogenic Centers through NHC–Cu-Catalyzed Allylic Substitution

(2012) Byunghyuck Jung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Formal Carboboration of Alkynes: Synthesis of Tri- and Tetrasubstituted Vinylboronates

(2012) Ricardo Alfaro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Boracarboxylation of Alkynes with Diborane and Carbon Dioxide by an N-Heterocyclic Carbene Copper Catalyst

(2012) Liang Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transformation of Carbon Dioxide with Homogeneous Transition-Metal Catalysts: A Molecular Solution to a Global Challenge?

(2011) Mirza Cokoja et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly regio- and stereoselective synthesis of alkenylboronic esters by copper-catalyzed boron additions to disubstituted alkynes

(2011) Hye Ryung Kim et al.   CHEMICAL COMMUNICATIONS

Transition-metal-catalyzed C–C bond formation through the fixation of carbon dioxide

(2011) Kun Huang et al.   CHEMICAL SOCIETY REVIEWS

Copper-Mediated Reduction of CO2with pinB-SiMe2Ph via CO2Insertion into a Copper–Silicon Bond

(2011) Christian Kleeberg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Methods for Synthesis of Internal (α-) Vinylboronates through Efficient NHC–Cu-Catalyzed Hydroboration of Terminal Alkynes. Utility in Chemical Synthesis and Mechanistic Basis for Selectivity

(2011) Hwanjong Jang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Hydrosilylation with a Bowl-Shaped Phosphane Ligand: Preferential Reduction of a Bulky Ketone in the Presence of an Aldehyde

(2010) Tetsuaki Fujihara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Hydrocarboxylation of Alkynes Using Carbon Dioxide and Hydrosilanes

(2010) Tetsuaki Fujihara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed γ-Selective Allyl−Alkyl Coupling between Allylic Phosphates and Alkylboranes

(2010) Hirohisa Ohmiya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct enantio-convergent transformation of racemic substrates without racemization or symmetrization

(2010) Hajime Ito et al.   Nature Chemistry

Diamine ligands in copper-catalyzed reactions

(2010) David S. Surry et al.   Chemical Science

Catalytic CC, CN, and CO Ullmann-Type Coupling Reactions

(2009) Florian Monnier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silylboranes as New Tools in Organic Synthesis

(2009) Toshimichi Ohmura et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Bis(imidazoline-2-thione)–copper(i) catalyzed regioselective boron addition to internal alkynes

(2009) Hye Ryung Kim et al.   CHEMICAL COMMUNICATIONS

Allylcopper Intermediates with N-Heterocyclic Carbene Ligands: Synthesis, Structure, and Catalysis

(2009) Vincenzo Russo et al.   ORGANIC LETTERS

Gold(I) Hydride Intermediate in Catalysis: Dehydrogenative Alcohol Silylation Catalyzed by Gold(I) Complex

(2009) Hajime Ito et al.   ORGANOMETALLICS

Rediscovering Organocopper Chemistry Through Copper Hydride. It’s All About the Ligand

(2009) Bruce Lipshutz   SYNLETT

Copper, Silver, and Gold Complexes in Hydrosilylation Reactions

(2008) Silvia Díez-González et al.   ACCOUNTS OF CHEMICAL RESEARCH

Synthesis of Activated Alkenylboronates from Acetylenic Esters by CuH-Catalyzed 1,2-Addition/Transmetalation

(2008) Bruce H. Lipshutz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed addition of diboron reagents to α,β-acetylenic esters: efficient synthesis of β-boryl-α,β-ethylenic esters

(2008) Ji-Eon Lee et al.   CHEMICAL COMMUNICATIONS

CuH-Catalyzed Reactions

(2008) Carl Deutsch et al.   CHEMICAL REVIEWS

Copper-Mediated Coupling Reactions and Their Applications in Natural Products and Designed Biomolecules Synthesis

(2008) Gwilherm Evano et al.   CHEMICAL REVIEWS

Synthesis and Reactivity of Functionalized Arylcopper Compounds by Transmetalation of Organosilanes

(2008) Jessica R. Herron et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Reductive Carboxylation of Styrenes Using CO2

(2008) Catherine M. Williams et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrocarboxylation of Allenes with CO2Catalyzed by Silyl Pincer-Type Palladium Complex

(2008) Jun Takaya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Substitution of Propargylic Carbonates with Diboron: Selective Synthesis of Multisubstituted Allenylboronates

(2008) Hajime Ito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

4,4,5,5-Tetraphenyl-1,3,2-dioxaborolane: A Bulky Borane for the Transition Metal Catalysed Hydroboration of Alkenes

(2007) Claudia B. Fritschi et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

(BDP)CuH:  A “Hot” Stryker's Reagent for Use in Achiral Conjugate Reductions

(2007) Benjamin A. Baker et al.   ORGANIC LETTERS