Copper Catalysis for Synthesizing Main-Group Organometallics Containing B, Sn or Si

Copper-catalyzed α-selective hydrostannylation of alkynes for the synthesis of branched alkenylstannanes

(2015) H. Yoshida et al.   CHEMICAL COMMUNICATIONS

Borylstannylation of alkynes with inverse regioselectivity: copper-catalyzed three-component coupling using a masked diboron

(2015) H. Yoshida et al.   CHEMICAL COMMUNICATIONS

Inverse regioselectivity in the silylstannylation of alkynes and allenes: copper-catalyzed three-component coupling with a silylborane and a tin alkoxide

(2015) H. Yoshida et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed borylative transformations of non-polar carbon–carbon unsaturated compounds employing borylcopper as an active catalyst species

(2015) Kazuhiko Semba et al.   TETRAHEDRON

Copper-Catalyzed Borylative Allyl-Allyl Coupling Reaction

(2014) Kazuhiko Semba et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Cross-Coupling of Boronic Esters with Aryl Iodides and Application to the Carboboration of Alkynes and Allenes

(2014) Yiqing Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A masked diboron in Cu-catalysed borylation reaction: highly regioselective formal hydroboration of alkynes for synthesis of branched alkenylborons

(2014) Hiroto Yoshida et al.   CHEMICAL COMMUNICATIONS

Alkene Carboboration Enabled by Synergistic Catalysis

(2014) Kevin B. Smith et al.   CHEMISTRY-A EUROPEAN JOURNAL

Arylboration of Alkenes by Cooperative Palladium/Copper Catalysis

(2014) Kazuhiko Semba et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Catalyzed Highly Regioselective Formal Hydroboration of Alkynes

(2014) Hiroto Yoshida et al.   ORGANIC LETTERS

Three-Component Carboboration of Alkenes under Copper Catalysis

(2014) Hiroto Yoshida et al.   SYNTHESIS-STUTTGART

Facile Access to vic-Borylstannylalkanes via Copper-Catalyzed Three-Component Borylstannylation of Alkenes

(2014) Hiroto Yoshida et al.   SYNTHESIS-STUTTGART

Recent developments in alkyne borylations

(2014) Renaud Barbeyron et al.   TETRAHEDRON

Regioselective transformation of alkynes catalyzed by a copper hydride or boryl copper species

(2014) Tetsuaki Fujihara et al.   Catalysis Science & Technology

Direct Synthesis of Boron-Protected Alkenyl- and Alkylborons via Copper-Catalyzed Formal Hydroboration of Alkynes and Alkenes

(2014) Hiroto Yoshida et al.   Asian Journal of Organic Chemistry

Synchronous ArF and ArSn Bond Formation through Fluorostannylation of Arynes

(2013) Hiroto Yoshida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed distannylation of alkynes

(2013) Hiroto Yoshida et al.   CHEMICAL COMMUNICATIONS

Copper-Catalyzed Three-Component Carboboration of Alkynes and Alkenes

(2013) Hiroto Yoshida et al.   ORGANIC LETTERS

Copper(I)-Catalyzed Boron Addition Reactions of Alkynes with Diboron Reagents

(2013) Jaesook Yun   Asian Journal of Organic Chemistry

Copper(I)-Catalyzed Allylic Substitution of Silyl Nucleophiles through SiSi Bond Activation

(2012) Hajime Ito et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-Catalyzed Silacarboxylation of Internal Alkynes by Employing Carbon Dioxide and Silylboranes

(2012) Tetsuaki Fujihara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Three-Component Borylstannylation of Alkynes

(2012) Yuki Takemoto et al.   CHEMISTRY-A EUROPEAN JOURNAL

Activation of Si-Si Bonds for Copper(I)-Catalyzed Conjugate Silylation

(2012) Laura Iannazzo et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Multicomponent Coupling Reaction of Arynes for Construction of Heterocyclic Skeletons

(2012) Hiroto Yoshida et al.   HETEROCYCLES

Copper(I)-Catalyzed Formal Carboboration of Alkynes: Synthesis of Tri- and Tetrasubstituted Vinylboronates

(2012) Ricardo Alfaro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Boracarboxylation of Alkynes with Diborane and Carbon Dioxide by an N-Heterocyclic Carbene Copper Catalyst

(2012) Liang Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aryne Insertion Reactions into Carbon-Carbon σ-Bonds

(2012) Hiroto Yoshida et al.   SYNLETT

Copper-Catalyzed Borylation Reactions of Alkynes and Arynes

(2011) Hiroto Yoshida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Three-component coupling using arynes and DMF: straightforward access to coumarins via ortho-quinone methides

(2011) Hiroto Yoshida et al.   CHEMICAL COMMUNICATIONS

Highly Selective Methods for Synthesis of Internal (α-) Vinylboronates through Efficient NHC–Cu-Catalyzed Hydroboration of Terminal Alkynes. Utility in Chemical Synthesis and Mechanistic Basis for Selectivity

(2011) Hwanjong Jang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Highly Regioselective Silylcupration of Terminal Alkynes to Form α-Vinylsilanes

(2011) Peng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed SiB Bond Activation in Branched-Selective Allylic Substitution of Linear Allylic Chlorides

(2010) Devendra J. Vyas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aryne,ortho-Quinone Methide, andortho-Quinodimethane: Synthesis of Multisubstituted Arenes Using the Aromatic Reactive Intermediates

(2010) Hiroto Yoshida et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Platinum-catalysed diborylation of arynes: synthesis and reaction of 1,2-diborylarenes

(2010) Hiroto Yoshida et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed asymmetric addition of arylboronates to isatins: a catalytic cycle involving alkoxocopper intermediates

(2010) Ryo Shintani et al.   CHEMICAL COMMUNICATIONS

Rhodium-catalyzed Dehydroborylation of Styrenes with Naphthalene-1,8-diaminatoborane [(dan)BH]: New Synthesis of Masked β-Borylstyrenes as New Phenylene–Vinylene Cross-coupling Modules

(2010) Noriyuki Iwadate et al.   CHEMISTRY LETTERS

Enantioselective Synthesis oftrans-Aryl- and -Heteroaryl-Substituted Cyclopropylboronates by Copper(I)-Catalyzed Reactions of Allylic Phosphates with a Diboron Derivative

(2010) Chongmin Zhong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereospecific Synthesis of Cyclobutylboronates through Copper(I)-Catalyzed Reaction of Homoallylic Sulfonates and a Diboron Derivative

(2010) Hajime Ito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Differentially Protected Diboron for Regioselective Diboration of Alkynes: Internal-Selective Cross-Coupling of 1-Alkene-1,2-diboronic Acid Derivatives

(2010) Noriyuki Iwadate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Borostannylation of Alkynes and Enynes. Scope and Limitations of the Reaction and Utility of the Adducts

(2010) Ramakrishna Reddy Singidi et al.   ORGANIC LETTERS

Catalytic SN2′-Selective Substitution of Allylic Chlorides With Arylboronic Esters

(2010) Aaron M. Whittaker et al.   ORGANIC LETTERS

Copper-catalysed bromoalkynylation of arynes

(2009) Takami Morishita et al.   CHEMICAL COMMUNICATIONS

Asymmetric 1,4-Dihydroxylation of 1,3-Dienes by Catalytic Enantioselective Diboration

(2009) Heather E. Burks et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Boron−Copper Additions to Aryl-Substituted Alkenes Promoted by NHC−Based Catalysts. Enantioselective Cu-Catalyzed Hydroboration Reactions

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fluorenes as new molecular scaffolds for carbon–carbon σ-bond cleavage reaction: acylfluorenylation of arynes

(2008) Hiroto Yoshida et al.   CHEMICAL COMMUNICATIONS

Palladium-catalyzed carboboration of alkynes using chloroborane and organozirconium reagents

(2008) Masaki Daini et al.   CHEMICAL COMMUNICATIONS

Three-Component Coupling Using Arynes and Aminosilanes for ortho-Selective Double Functionalization of Aromatic Skeletons

(2008) Takami Morishita et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Markovnikov Terminal Arylalkynes Hydrostannation: Application to the Synthesis of 1,1-Diarylethylenes

(2008) Abdallah Hamze et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzedtrans- andcis-Carboboration of Alkynes Tethered to Chloroborane with Organozirconium Reagents:  Ligand-Dependent Complementary Stereoselectivity

(2008) Masaki Daini et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Substitution of Propargylic Carbonates with Diboron: Selective Synthesis of Multisubstituted Allenylboronates

(2008) Hajime Ito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Differentially Protected Benzenediboronic Acids:  Divalent Cross-Coupling Modules for the Efficient Synthesis of Boron-Substituted Oligoarenes

(2008) Hiroyoshi Noguchi et al.   ORGANIC LETTERS

Copper-Catalyzed 2:1 Coupling Reaction of Arynes with Alkynes

(2008) Hiroto Yoshida et al.   ORGANIC LETTERS