Copper-Catalyzed Borylation of α-Alkoxy Allenes with Bis(pinacolato)diboron: Efficient Synthesis of 2-Boryl 1,3-Butadienes

Amide-Controlled Highly Selective Catalytic Borylcupration of Allenes

(2013) Weiming Yuan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Selective Copper-Catalyzed Hydroboration of Allenes and 1,3-Dienes

(2013) Kazuhiko Semba et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper(I)-Catalyzed Borylative exo-Cyclization of Alkenyl Halides Containing Unactivated Double Bond

(2013) Koji Kubota et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

NHC–Cu-Catalyzed Protoboration of Monosubstituted Allenes. Ligand-Controlled Site Selectivity, Application to Synthesis and Mechanism

(2013) Fanke Meng et al.   ORGANIC LETTERS

Ligand Controlled Highly Selective Copper-Catalyzed Borylcuprations of Allenes with Bis(pinacolato)diboron

(2012) Weiming Yuan et al.   ADVANCED SYNTHESIS & CATALYSIS

Preparation and Diels–Alder/Cross Coupling Reactions of New 2-Boron-Substituted 1,3-Dienes

(2012) Liqiong Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Enantioselective Allylic Substitution with Alkylboranes

(2012) Yoshinori Shido et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site- and Enantioselective Formation of Allene-Bearing Tertiary or Quaternary Carbon Stereogenic Centers through NHC–Cu-Catalyzed Allylic Substitution

(2012) Byunghyuck Jung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regiocontrolled CuI-Catalyzed Borylation of Propargylic-Functionalized Internal Alkynes

(2012) Abraham L. Moure et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly (≥98%) Stereo- and Regioselective Trisubstituted Alkene Synthesis of Wide Applicability via 1-Halo-1-alkyne Hydro- boration-Tandem Negishi-Suzuki Coupling or Organoborate Migratory Insertion

(2011) Shiqing Xu et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper(I)-Catalyzed Regioselective Monoborylation of 1,3-Enynes with an Internal Triple Bond: Selective Synthesis of 1,3-Dienylboronates and 3-Alkynylboronates

(2011) Yusuke Sasaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly regio- and stereoselective synthesis of alkenylboronic esters by copper-catalyzed boron additions to disubstituted alkynes

(2011) Hye Ryung Kim et al.   CHEMICAL COMMUNICATIONS

Highly Selective Methods for Synthesis of Internal (α-) Vinylboronates through Efficient NHC–Cu-Catalyzed Hydroboration of Terminal Alkynes. Utility in Chemical Synthesis and Mechanistic Basis for Selectivity

(2011) Hwanjong Jang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed γ-Selective Allyl−Alkyl Coupling between Allylic Phosphates and Alkylboranes

(2010) Hirohisa Ohmiya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct enantio-convergent transformation of racemic substrates without racemization or symmetrization

(2010) Hajime Ito et al.   Nature Chemistry

Desymmetrization of meso-2-Alkene-1,4-diol Derivatives through Copper(I)-Catalyzed Asymmetric Boryl Substitution and Stereoselective Allylation of Aldehydes

(2009) Hajime Ito et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of 2-boryl-1,3-butadienes from tributylphosphine stabilized zirconacyclopropenes and alkynes

(2009) Alina Botvinik et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

(E)-2-Boryl-1,3-butadiene Derivatives of the 10-TMS-9-BBDs: Highly Selective Reagents for the Asymmetric Synthesis ofanti-1,2-Disubstituted 3,4-Pentadien-1-ols

(2009) Javier R. González et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Allylcopper Intermediates with N-Heterocyclic Carbene Ligands: Synthesis, Structure, and Catalysis

(2009) Vincenzo Russo et al.   ORGANIC LETTERS

Carboxylation of Organoboronic Esters Catalyzed by N‐Heterocyclic Carbene Copper(I) Complexes

(2008) Takeshi Ohishi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diels–Alder Reaction of 2,3-Bis(pinacolatoboryl)-1,3-butadiene: Facile Preparation of 1,2-Bis(pinacolatoboryl)cyclohexenes and -1,4-cyclohexadiene

(2008) Masaki Shimizu et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

A Simple, Modular Synthesis of Substituted Pyridines

(2008) Songbai Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Substitution of Propargylic Carbonates with Diboron: Selective Synthesis of Multisubstituted Allenylboronates

(2008) Hajime Ito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Carboxylation of Aryl- and Alkenylboronic Esters

(2008) Jun Takaya et al.   ORGANIC LETTERS

Copper-catalyzed substitution of allylic carbonates with diboron: A new approach to allylboronate synthesis

(2008) Hajime Ito et al.   PURE AND APPLIED CHEMISTRY