Reaching the south: metal-catalyzed transformation of the aromatic para-position

Palladium-Catalyzed DirectedparaC−H Functionalization of Phenols

(2016) Tuhin Patra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reaching the south: metal-catalyzed transformation of the aromatic para-position

(2016) Aniruddha Dey et al.   CHEMICAL COMMUNICATIONS

Sequential meta-C–H olefination of synthetically versatile benzyl silanes: effective synthesis of meta-olefinated toluene, benzaldehyde and benzyl alcohols

(2016) Tuhin Patra et al.   CHEMICAL COMMUNICATIONS

Palladium catalysed meta-C–H functionalization reactions

(2016) Aniruddha Dey et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Palladium(II)-Catalyzedmeta-CH Olefination: Constructing Multisubstituted Arenes through Homo-Diolefination and Sequential Hetero-Diolefination

(2015) Milan Bera et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective electrophilic borylation of haloarenes

(2015) Alessandro Del Grosso et al.   CHEMICAL COMMUNICATIONS

Nickel-catalysed para-CH activation of pyridine with switchable regioselective hydroheteroarylation of allylarenes

(2015) Wei-Chih Lee et al.   CHEMICAL COMMUNICATIONS

Para-Selective Cu-Catalyzed C–H Aryloxylation of Electron-Rich Arenes and Heteroarenes

(2015) Igors Sokolovs et al.   JOURNAL OF ORGANIC CHEMISTRY

Cu(II)-Mediated C(sp2)–H Hydroxylation

(2015) Shang-Zheng Sun et al.   JOURNAL OF ORGANIC CHEMISTRY

para-C–H Borylation of Benzene Derivatives by a Bulky Iridium Catalyst

(2015) Yutaro Saito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote para-C–H Functionalization of Arenes by a D-Shaped Biphenyl Template-Based Assembly

(2015) Sukdev Bag et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Controlled Para-Selective C–H Arylation of Monosubstituted Arenes

(2015) Hui Xu et al.   ORGANIC LETTERS

Palladium-Catalyzed Oxidative Arylation of Tertiary Benzamides: Para-Selectivity of Monosubstituted Arenes

(2015) Ze Yang et al.   ORGANIC LETTERS

Pd(ii)-catalyzed remote regiodivergent ortho- and meta-C–H functionalizations of phenylethylamines

(2015) Shangda Li et al.   Chemical Science

Copper-Catalyzed para-Selective C–H Amination of Electron-Rich Arenes

(2015) Beatrise Berzina et al.   ACS Catalysis

Synthesis of Multisubstituted Arenes via PyrDipSi-Directed Unsymmetrical Iterative C–H Functionalizations

(2015) Dhruba Sarkar et al.   ACS Catalysis

Remote Meta-C–H Activation Using a Pyridine-Based Template: Achieving Site-Selectivity via the Recognition of Distance and Geometry

(2015) Ling Chu et al.   ACS Central Science

Functionalization of Remote CH Bonds: Expanding the Frontier

(2014) Johannes Schranck et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iodine(III)-Mediated C–H Alkoxylation of Aniline Derivatives with Alcohols under Metal-Free Conditions

(2014) Qing Jiang et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Intermolecular C–H Amination of (Hetero)arenes via Transient Unsymmetrical λ3-Iodanes

(2014) Igors Sokolovs et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Site-Selective Direct C–H Bond Functionalization of Phenols with α-Aryl-α-diazoacetates and Diazooxindoles via Gold Catalysis

(2014) Zhunzhun Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conformation-induced remote meta-C–H activation of amines

(2014) Ri-Yuan Tang et al.   NATURE

Regioselective Gold-Catalyzed Oxidative C–N Bond Formation

(2014) Louis Marchetti et al.   ORGANIC LETTERS

Copper-Mediated Direct Aryloxylation of Benzamides Assisted by an N,O-Bidentate Directing Group

(2014) Xin-Qi Hao et al.   ORGANIC LETTERS

Remote Control by Steric Effects

(2014) M. Tobisu et al.   SCIENCE

Highly selective acetoxylation of sulfonamides via using phenyliodine(III) diacetate

(2014) Sichang Wang et al.   TETRAHEDRON

Recent advances in directed C–H functionalizations using monodentate nitrogen-based directing groups

(2014) Min Zhang et al.   Organic Chemistry Frontiers

Gold-Catalyzed Rearrangements and Beyond

(2013) Carla Obradors et al.   ACCOUNTS OF CHEMICAL RESEARCH

Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C–H/Het–H Bond Functionalizations

(2013) Lutz Ackermann   ACCOUNTS OF CHEMICAL RESEARCH

Novel Multicomponent Reactions via Trapping of Protic Onium Ylides with Electrophiles

(2013) Xin Guo et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-catalyzed para-selective arylation of phenols with aryl iodides in water

(2013) Zhiqing Wu et al.   CHEMICAL COMMUNICATIONS

Catalytic X–H insertion reactions based on carbenoids

(2013) Dennis Gillingham et al.   CHEMICAL SOCIETY REVIEWS

General and Practical Carboxyl-Group-Directed Remote CH Oxygenation Reactions of Arenes

(2013) Yang Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Arylation with Unsymmetrical Diaryliodonium Salts: A Chemoselectivity Study

(2013) Joel Malmgren et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal-Free OxidativeparaCross-Coupling of Phenols

(2013) Koji Morimoto et al.   CHEMISTRY-A EUROPEAN JOURNAL

Sterically Controlled, Palladium-Catalyzed Intermolecular Amination of Arenes

(2013) Ruja Shrestha et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Gold(I)-Catalyzed Vinylogous [3 + 2] Cycloaddition between Vinyldiazoacetates and Enol Ethers

(2013) John F. Briones et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Meta-Selective C–H Functionalization Using a Nitrile-Based Directing Group and Cleavable Si-Tether

(2013) Sunggi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cross-Coupling of Remote meta-C–H Bonds Directed by a U-Shaped Template

(2013) Li Wan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Divergence between Organometallic and Single-Electron-Transfer Mechanisms in Copper(II)-Mediated Aerobic C–H Oxidation

(2013) Alison M. Suess et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Coupling of Benzamides and Donor/Acceptor Diazo Compounds To Form γ-Lactams via Rh(III)-Catalyzed C–H Activation

(2013) Todd K. Hyster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ortho- and Para-Selective Ruthenium-Catalyzed C(sp2)–H Oxygenations of Phenol Derivatives

(2013) Weiping Liu et al.   ORGANIC LETTERS

Oxidative para-Triflation of Acetanilides

(2013) Amélie Pialat et al.   ORGANIC LETTERS

Copper-Catalyzed Etherification of Arene C–H Bonds

(2013) James Roane et al.   ORGANIC LETTERS

Palladium-catalyzed C–H activation of anilides at room temperature: ortho-arylation and acetoxylation

(2013) Fan Yang et al.   RSC Advances

Transition-Metal-Catalyzed Enantioselective Heteroatom–Hydrogen Bond Insertion Reactions

(2012) Shou-Fei Zhu et al.   ACCOUNTS OF CHEMICAL RESEARCH

CH Activation of Isobutylene Using Frustrated Lewis Pairs: Aluminum and Boron σ-Allyl Complexes

(2012) Gabriel Ménard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

(2012) Nadine Kuhl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemo- and Regioselective Direct Hydroxylation of Arenes with Hydrogen Peroxide Catalyzed by a Divanadium-Substituted Phosphotungstate

(2012) Keigo Kamata et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free direct oxidative intermolecular diarylation of anilides at ambient temperature assisted by cascade selective formation of C–C and C–N bonds

(2012) Rajarshi Samanta et al.   CHEMICAL COMMUNICATIONS

Rh-Catalyzed Intermolecular Carbenoid Functionalization of Aromatic C–H Bonds by α-Diazomalonates

(2012) Wai-Wing Chan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of remote meta-C–H bonds assisted by an end-on template

(2012) Dasheng Leow et al.   NATURE

An Alternative Approach to para-C–H Arylation of Phenol: Palladium-Catalyzed Tandem γ-Arylation/Aromatization of 2-Cyclohexen-1-one Derivatives

(2012) Tatsushi Imahori et al.   ORGANIC LETTERS

Para-Selective Gold-Catalyzed Direct Alkynylation of Anilines

(2012) Jonathan P. Brand et al.   ORGANIC LETTERS

Gold-Catalyzed Direct Arylation

(2012) L. T. Ball et al.   SCIENCE

Organocatalytic, Oxidative, Intramolecular CH Bond Amination and Metal-free Cross-Amination of Unactivated Arenes at Ambient Temperature

(2011) Andrey P. Antonchick et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Phenanthridinones from N-Methoxybenzamides and Arenes by Multiple Palladium-Catalyzed CH Activation Steps at Room Temperature

(2011) Jaganathan Karthikeyan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation

(2011) Seung Hwan Cho et al.   CHEMICAL SOCIETY REVIEWS

Pd-Catalyzed Multiple CH Functionalization to Construct Biologically Active Compounds from Aryl Aldoxime Ethers with Arenes

(2011) Vedhagiri S. Thirunavukkarasu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Merging Organocatalysis and Gold Catalysis: Enantioselective Synthesis of Tetracyclic Indole Derivatives through a Sequential Double Friedel-Crafts Type Reaction

(2011) Charles C. J. Loh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Efficient Epoxidation of Electron-Deficient Alkenes with Hydrogen Peroxide Catalyzed by [γ-PW10O38V2(μ-OH)2]3−

(2011) Keigo Kamata et al.   CHEMISTRY-A EUROPEAN JOURNAL

Pd(II)-Catalyzedpara-Selective C–H Arylation of Monosubstituted Arenes

(2011) Xisheng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermolecular Oxidative C–N Bond Formation under Metal-Free Conditions: Control of Chemoselectivity between Aryl sp2and Benzylic sp3C–H Bond Imidation

(2011) Hyun Jin Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Intermolecular Oxidative C–N Bond Formation via Tandem C–H and N–H Bond Functionalization

(2011) Abhishek A. Kantak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed C−H Aminations of Anilides withN-Fluorobenzenesulfonimide

(2011) Kai Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct acetoxylation and etherification of anilides using phenyliodine bis(trifluoroacetate)

(2011) Huan Liu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Gold-Catalyzed Direct Amination of Arenes with Azodicarboxylates

(2011) Liuqun Gu et al.   ORGANIC LETTERS

A Highly Para-Selective Copper(II)-Catalyzed Direct Arylation of Aniline and Phenol Derivatives

(2010) Claire-Lise Ciana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regiospecific Reductive Elimination from Diaryliodonium Salts

(2010) Bijia Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Asymmetric One-Pot Sequential Organo- and Gold Catalysis for the Enantioselective Synthesis of Dihydropyrrole Derivatives

(2010) David Monge et al.   CHEMISTRY-A EUROPEAN JOURNAL

Umpolung Direct Arylation Reactions: Facile Process Requiring Only Catalytic Palladium and Substoichiometric Amount of Silver Salts

(2010) James J. Mousseau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective C-4 Alkylation of Pyridine by Nickel/Lewis Acid Catalysis

(2010) Yoshiaki Nakao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimetallic Nickel Aluminun MediatedPara-Selective Alkenylation of Pyridine: Direct Observation of η2,η1-Pyridine Ni(0)−Al(III) Intermediates Prior to C−H Bond Activation

(2010) Chung-Chih Tsai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Amination of Aromatic C−H Bonds with Oxime Esters

(2010) Yichen Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-catalyzed ortho-arylation of phenylacetamides, benzamides, and anilides with simple arenes using sodium persulfate

(2010) Charles S. Yeung et al.   Chemical Science

Palladium- and Copper-Catalyzed Arylation of Carbon−Hydrogen Bonds

(2009) Olafs Daugulis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Enantioselective One-Pot Organocatalytic Michael Addition/Gold-Catalyzed Tandem Acetalization/Cyclization

(2009) S��bastien Belot et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Partial Oxidation of Toluene in CH3COOH by H2O2 in the Presence of VO (acac)2 Catalyst

(2009) Xueqin Wang et al.   Journal of Physical Chemistry C

Palladium-Catalyzed Carboamination of Alkenes Promoted byN-Fluorobenzenesulfonimide via C−H Activation of Arenes

(2009) Carolyn F. Rosewall et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Reactions of Carbene Precursors on Bulk Gold Metal

(2009) Yibo Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Alkenylation and Alkylation of Pyridone Derivatives by Ni/AlMe3Catalysis

(2009) Yoshiaki Nakao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Meta-Selective Copper-Catalyzed C-H Bond Arylation

(2009) R. J. Phipps et al.   SCIENCE

Hypervalent iodine(III): selective and efficient single-electron-transfer (SET) oxidizing agent

(2009) Toshifumi Dohi et al.   TETRAHEDRON

Recent advances in the synthesis of (hetero)aryl-substituted heteroarenes via transition metal-catalysed direct (hetero)arylation of heteroarene C–H bonds with aryl halides or pseudohalides, diaryliodonium salts, and potassium aryltrifluoroborates

(2009) Fabio Bellina et al.   TETRAHEDRON

Di-, Tetra-, and Polynuclear Copper(II) Complexes: Active Catalysts for Oxidation of Toluene and Benzene

(2008) Partha Roy et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A Strategy for C−H Activation of Pyridines:  Direct C-2 Selective Alkenylation of Pyridines by Nickel/Lewis Acid Catalysis

(2008) Yoshiaki Nakao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Twofold C−H Functionalization: Palladium-CatalyzedOrthoArylation of Anilides

(2008) Gordon Brasche et al.   ORGANIC LETTERS