Asymmetric Synthesis of Silicon‐Stereogenic Silanes by Copper‐Catalyzed Desymmetrizing Protoboration of Vinylsilanes

Cobalt-Catalyzed Asymmetric Synthesis of gem-Bis(silyl)alkanes by Double Hydrosilylation of Aliphatic Terminal Alkynes

(2019) Jun Guo et al.   Chem

Rhodium-Catalyzed Reaction of Silacyclobutanes with Unactivated Alkynes to Afford Silacyclohexenes

(2019) Hua Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Asymmetric Reductive Allylation of Ketones with 1,3-Dienes

(2019) Bin Fu et al.   ORGANIC LETTERS

Controllable Si−C Bond Activation Enables Stereocontrol in the Palladium-Catalyzed [4+2] Annulation of Cyclopropenes with Benzosilacyclobutanes

(2019) Xing-Ben Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of Silicon-Stereogenic Vinylhydrosilanes by Cobalt-Catalyzed Regio- and Enantioselective Alkyne Hydrosilylation with Dihydrosilanes

(2018) Huanan Wen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Diastereo- and Enantioselective Borylative Cyclization: Synthesis of Enantioenriched 2,3-Disubstituted Indolines

(2018) Ge Zhang et al.   ORGANIC LETTERS

Asymmetric hydrofunctionalization of minimally functionalized alkenes via earth abundant transition metal catalysis

(2018) Jianhui Chen et al.   Organic Chemistry Frontiers

Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration

(2018) Jennifer V. Obligacion et al.   Nature Reviews Chemistry

Enantioselective Construction of Silicon-Stereogenic Silanes by Scandium-Catalyzed Intermolecular Alkene Hydrosilylation

(2018) Gu Zhan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in Hydrometallation of Alkenes and Alkynes via the First Row Transition Metal Catalysis

(2018) Jianhui Chen et al.   CHINESE JOURNAL OF CHEMISTRY

Recent Advances in Copper-Catalyzed Asymmetric Hydroboration of Electron-Deficient Alkenes: Methodologies and Mechanism

(2018) Andrew Whiting et al.   SYNTHESIS-STUTTGART

Iron Catalysis in Reduction and Hydrometalation Reactions

(2018) Duo Wei et al.   CHEMICAL REVIEWS

Access to Chiral Silicon Centers for Application to Circularly Polarized Luminescence Materials

(2017) Shinya Koga et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Asymmetric Hydroboration of 1,1-Disubstituted Alkenes

(2017) Zining Wang et al.   ORGANIC LETTERS

Recent Progress in Catalytic Enantioselective Desymmetrization of Prochiral Organosilanes for the Synthesis of Silicon-Stereogenic Compounds

(2017) Ryo Shintani   SYNLETT

Construction of Chiral Tetraorganosilicons by Tandem Desymmetrization of Silacyclobutanes/Intermolecular Dehydrogenative Silylation

(2016) Qing-Wei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Transformations Using Cu-H, Cu-B, and Cu-Si as Active Catalyst Species

(2016) Yasushi Tsuji et al.   CHEMICAL RECORD

Silicon-Containing Amino Acids: Synthetic Aspects, Conformational Studies, and Applications to Bioactive Peptides

(2016) Emmanuelle Rémond et al.   CHEMICAL REVIEWS

Rhodium-Catalyzed Synthesis of Chiral Spiro-9-silabifluorenes by Dehydrogenative Silylation: Mechanistic Insights into the Construction of Tetraorganosilicon Stereocenters

(2016) Masahito Murai et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Progress in Asymmetric Synthesis and Application of Difunctionalized Silicon-Stereogenic Silanes

(2016) Jonathan O. Bauer et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Rhodium-catalyzed asymmetric synthesis of silicon-stereogenic silicon-bridged arylpyridinones

(2016) Ryo Shintani et al.   Chemical Science

Rhodium-catalyzed intramolecular alkynylsilylation of alkynes

(2015) Ryo Shintani et al.   CHEMICAL COMMUNICATIONS

Construction of a Chiral Silicon Center by Rhodium-Catalyzed Enantioselective Intramolecular Hydrosilylation

(2015) Yuki Naganawa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Acceleration Effects of Phosphine Ligands on the Rhodium-Catalyzed Dehydrogenative Silylation and Germylation of Unactivated C(sp3)–H Bonds

(2015) Masahito Murai et al.   JOURNAL OF ORGANIC CHEMISTRY

Nickel(0)-Catalyzed Enantio- and Diastereoselective Synthesis of Benzoxasiloles: Ligand-Controlled Switching from Inter- to Intramolecular Aryl-Transfer Process

(2015) Ravindra Kumar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-catalyzed borylative transformations of non-polar carbon–carbon unsaturated compounds employing borylcopper as an active catalyst species

(2015) Kazuhiko Semba et al.   TETRAHEDRON

Recent Advances in the Transition-Metal-Catalyzed Enantioselective Synthesis of Silicon-Stereogenic Organosilanes

(2015) Ryo Shintani   Asian Journal of Organic Chemistry

Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles by Enantioselective [2+2+2] Cycloaddition

(2014) Ryo Shintani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective transformation of alkynes catalyzed by a copper hydride or boryl copper species

(2014) Tetsuaki Fujihara et al.   Catalysis Science & Technology

Recent Advances in Catalytic Sequential Reactions Involving Hydroelement Addition to Carbon–Carbon Multiple Bonds

(2013) Xiaoming Zeng   CHEMICAL REVIEWS

ExceptionallyE- and β-Selective NHC-Cu-Catalyzed Proto-Silyl Additions to Terminal Alkynes and Site- and Enantioselective Proto-Boryl Additions to the Resulting Vinylsilanes: Synthesis of Enantiomerically Enriched Vicinal and Geminal Borosilanes

(2013) Fanke Meng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Desymmetrization Catalyzed by Transition-Metal Complexes: Enantioselective Formation of Silicon-Stereogenic Silanes

(2012) Li-Wen Xu   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Asymmetric Synthesis of Spirosilabifluorene Derivatives

(2012) Yoichiro Kuninobu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Synthesis of Alkenylhydrosilanes

(2012) Kazunobu Igawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of optically active tertiary silanes via Pd-catalyzed enantioselective arylation of secondary silanes

(2012) Yu Kurihara et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles via Enantioselective C–H Bond Functionalization

(2012) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzooxasilines via Enantioselective Transmetalation

(2012) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Carbon–Silicon Bond Activation for Synthesis of Benzosilole Derivatives

(2012) Masahiro Onoe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Desymmetrization of Silacyclobutanes with Alkynes: Enantioselective Synthesis of Silicon-Stereogenic 1-Sila-2-cyclohexenes and Mechanistic Considerations

(2012) Ryo Shintani et al.   ORGANIC LETTERS

Palladium-Catalyzed Enantioselective Desymmetrization of Silacyclobutanes: Construction of Silacycles Possessing a Tetraorganosilicon Stereocenter

(2011) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of Tertiary and Quaternary Allyl- and Crotylsilanes via the Borylation of Lithiated Carbamates

(2011) Varinder K. Aggarwal et al.   ORGANIC LETTERS

The recent synthesis and application of silicon-stereogenic silanes: A renewed and significant challenge in asymmetric synthesis

(2010) Li-Wen Xu et al.   CHEMICAL SOCIETY REVIEWS

Iridium(III)-Catalyzed Enantioselective Si−H Bond Insertion and Formation of an Enantioenriched Silicon Center

(2010) Yoichi Yasutomi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Si–O coupling of alcohols

(2010) Andreas Weickgenannt et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Asymmetric Hydroboration of 1,1-Disubstituted Alkenes

(2009) Stephen P. Thomas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Control of stereochemical structures of silicon-containing polymeric systems

(2009) Yusuke Kawakami et al.   POLYMER INTERNATIONAL

Metal-Catalyzed Reactions of Organoboronic Acids and Esters

(2008) Norio Miyaura   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN