Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration

Copper-Catalyzed Enantioselective Hydroboration of Unactivated 1,1-Disubstituted Alkenes

(2017) Won Jun Jang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stable, Yet Highly Reactive Nonclassical Iron(II) Polyhydride Pincer Complexes: Z-Selective Dimerization and Hydroboration of Terminal Alkynes

(2017) Nikolaus Gorgas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Asymmetric Hydroboration/Cyclization of 1,6-Enynes with Pinacolborane

(2017) Songjie Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed 1,1-Diboration of Terminal Alkynes: Scope, Mechanism, and Synthetic Applications

(2017) Simon Krautwald et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Asymmetric Sequential Hydroboration/Hydrogenation of Internal Alkynes

(2017) Jun Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mode of Activation of Cobalt(II) Amides for Catalytic Hydrosilylation of Alkenes with Tertiary Silanes

(2017) Yang Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Structure, and Reactivity of a Terminal Magnesium Hydride Compound with a Carbatrane Motif, [TismPriBenz]MgH: A Multifunctional Catalyst for Hydrosilylation and Hydroboration

(2017) Michael Rauch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C(sp2)–H Borylation of Fluorinated Arenes Using an Air-Stable Cobalt Precatalyst: Electronically Enhanced Site Selectivity Enables Synthetic Opportunities

(2017) Jennifer V. Obligacion et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Rhodium(III)-Catalyzed Markovnikov Hydroboration of Unactivated Terminal Alkenes

(2017) James R. Smith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation and discovery of earth-abundant metal catalysts using sodium tert-butoxide

(2017) Jamie H. Docherty et al.   Nature Chemistry

Hydrosilylation of Olefins Catalyzed by Iron Complexes Bearing Ketimine-Type Iminobipyridine Ligands

(2017) Yuki Toya et al.   ORGANOMETALLICS

Control of Selectivity through Synergy between Catalysts, Silanes, and Reaction Conditions in Cobalt-Catalyzed Hydrosilylation of Dienes and Terminal Alkenes

(2017) Balaram Raya et al.   ACS Catalysis

Advances in Base-Metal-Catalyzed Alkene Hydrosilylation

(2017) Xiaoyong Du et al.   ACS Catalysis

Insights into a Chemoselective Cobalt Catalyst for the Hydroboration of Alkenes and Nitriles

(2017) Abdulrahman D. Ibrahim et al.   ACS Catalysis

Highly Selective Hydroboration of Alkenes, Ketones and Aldehydes Catalyzed by a Well-Defined Manganese Complex

(2016) Guoqi Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Easily Accessed Nickel Nanoparticle Catalyst for Alkene Hydrosilylation with Tertiary Silanes

(2016) Ivan Buslov et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Hydroboration: Unlocking Reactivity through Ligand Modulation

(2016) Maialen Espinal-Viguri et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cobalt-bis(imino)pyridine complexes as catalysts for hydroalumination–isomerisation of internal olefins

(2016) Nandita M. Weliange et al.   DALTON TRANSACTIONS

Transmetallation from CCC-NHC pincer Zr complexes in the synthesis of air-stable CCC-NHC pincer Co(iii) complexes and initial hydroboration trials

(2016) Sean W. Reilly et al.   DALTON TRANSACTIONS

Bis(acetylacetonato)Ni(II)/NaBHEt3-catalyzed hydrosilylation of 1,3-dienes, alkenes and alkynes

(2016) Venu Srinivas et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Non-Precious-Metal Catalytic Systems Involving Iron or Cobalt Carboxylates and Alkyl Isocyanides for Hydrosilylation of Alkenes with Hydrosiloxanes

(2016) Daisuke Noda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal–Organic Frameworks Stabilize Solution-Inaccessible Cobalt Catalysts for Highly Efficient Broad-Scope Organic Transformations

(2016) Teng Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-catalysed tritiation of pharmaceuticals

(2016) Renyuan Pony Yu et al.   NATURE

Alkoxy Hydrosilanes As Surrogates of Gaseous Silanes for Hydrosilylation of Alkenes

(2016) Ivan Buslov et al.   ORGANIC LETTERS

Synthesis of Secondary and Tertiary Alkylboranes via Formal Hydroboration of Terminal and 1,1-Disubstituted Alkenes

(2016) Hilary A. Kerchner et al.   ORGANIC LETTERS

Heteroleptic Nickel Complexes for the Markovnikov-Selective Hydroboration of Styrenes

(2016) Eric E. Touney et al.   ORGANOMETALLICS

Bench-Stable, Substrate-Activated Cobalt Carboxylate Pre-Catalysts for Alkene Hydrosilylation with Tertiary Silanes

(2016) Christopher H. Schuster et al.   ACS Catalysis

A Highly Chemoselective Cobalt Catalyst for the Hydrosilylation of Alkenes using Tertiary Silanes and Hydrosiloxanes

(2016) Abdulrahman D. Ibrahim et al.   ACS Catalysis

Alkene Hydrosilylation Using Tertiary Silanes with α-Diimine Nickel Catalysts. Redox-Active Ligands Promote a Distinct Mechanistic Pathway from Platinum Catalysts

(2016) Iraklis Pappas et al.   ACS Catalysis

Markovnikov-Selective, Activator-Free Iron-Catalyzed Vinylarene Hydroboration

(2016) Alistair J. MacNair et al.   ACS Catalysis

Recent Advances in Transition-Metal-Catalyzed Synthetic Transformations of Organosilicon Reagents

(2016) Takeshi Komiyama et al.   ACS Catalysis

Platinum Catalysis Revisited—Unraveling Principles of Catalytic Olefin Hydrosilylation

(2016) Teresa K. Meister et al.   ACS Catalysis

Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

(2016) Alois Fürstner   ACS Central Science

Iron- and Cobalt-Catalyzed Alkene Hydrogenation: Catalysis with Both Redox-Active and Strong Field Ligands

(2015) Paul J. Chirik   ACCOUNTS OF CHEMICAL RESEARCH

Chemoselective Alkene Hydrosilylation Catalyzed by Nickel Pincer Complexes

(2015) Ivan Buslov et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphine-Iminopyridines as Platforms for Catalytic Hydrofunctionalization of Alkenes

(2015) Ryan Gilbert-Wilson et al.   INORGANIC CHEMISTRY

Hydrosilylation vs. dehydrogenative silylation of styrene catalysed by iron(0) carbonyl complexes with multivinylsilicon ligands – Mechanistic implications

(2015) Bogdan Marciniec et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Synthesis of 1,1,1-Tris(boronates) from Vinylarenes by Co-Catalyzed Dehydrogenative Borylations–Hydroboration

(2015) Lei Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rapid, Regioconvergent, Solvent-Free Alkene Hydrosilylation with a Cobalt Catalyst

(2015) Chi Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt Catalyzed Z-Selective Hydroboration of Terminal Alkynes and Elucidation of the Origin of Selectivity

(2015) Jennifer V. Obligacion et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alkene Isomerization–Hydroboration Promoted by Phosphine-Ligated Cobalt Catalysts

(2015) Margaret L. Scheuermann et al.   ORGANIC LETTERS

Cobalt Complex-Catalyzed Hydrosilylation of Alkenes and Alkynes

(2015) Jian Sun et al.   ACS Catalysis

Iron-Catalysed Chemo-, Regio-, and Stereoselective Hydrosilylation of Alkenes and Alkynes using a Bench-Stable Iron(II) Pre-Catalyst

(2014) Mark D. Greenhalgh et al.   ADVANCED SYNTHESIS & CATALYSIS

A Cobalt-Catalyzed Alkene Hydroboration with Pinacolborane

(2014) Lei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[(NHC)Fe(CO)4] Efficient Pre-catalyst for Selective Hydroboration of Alkenes

(2014) Jianxia Zheng et al.   ChemCatChem

(N-Phosphinoamidinate)cobalt-Catalyzed Hydroboration: Alkene Isomerization Affords Terminal Selectivity

(2014) Adam J. Ruddy et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cobalt-Catalyzed Enantioselective Hydroboration of 1,1-Disubstituted Aryl Alkenes

(2014) Lei Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bis(imino)pyridine Cobalt-Catalyzed Dehydrogenative Silylation of Alkenes: Scope, Mechanism, and Origins of Selective Allylsilane Formation

(2014) Crisita Carmen Hojilla Atienza et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed C–H Borylation

(2014) Jennifer V. Obligacion et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iminopyridine Oxazoline Iron Catalyst for Asymmetric Hydroboration of 1,1-Disubtituted Aryl Alkenes

(2014) Jianhui Chen et al.   ORGANIC LETTERS

Disilaferracycle Dicarbonyl Complex Containing Weakly Coordinated η2-(H-Si) Ligands: Application to C–H Functionalization of Indoles and Arenes

(2014) Yusuke Sunada et al.   ORGANOMETALLICS

Regulation of Iron-Catalyzed Olefin Hydroboration by Ligand Modifications at a Remote Site

(2014) Kuei-Nin T. Tseng et al.   ACS Catalysis

High-Activity Cobalt Catalysts for Alkene Hydroboration with Electronically Responsive Terpyridine and α-Diimine Ligands

(2014) W. Neil Palmer et al.   ACS Catalysis

Iron-Catalyzed, Atom-Economical, Chemo- and Regioselective Alkene Hydroboration with Pinacolborane

(2013) Lei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalyst design for iron-promoted reductions: an iron disilyl-dicarbonyl complex bearing weakly coordinating η2-(H–Si) moieties

(2013) Yusuke Sunada et al.   DALTON TRANSACTIONS

Bis(imino)pyridine Cobalt-Catalyzed Alkene Isomerization–Hydroboration: A Strategy for Remote Hydrofunctionalization with Terminal Selectivity

(2013) Jennifer V. Obligacion et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Bis(imino)pyridine Iron-Catalyzed Alkene Hydroboration

(2013) Jennifer V. Obligacion et al.   ORGANIC LETTERS

Photoswitchable Metal-Mediated Catalysis: Remotely Tuned Alkene and Alkyne Hydroborations

(2013) Bethany M. Neilson et al.   ORGANOMETALLICS

Cobalt Precursors for High-Throughput Discovery of Base Metal Asymmetric Alkene Hydrogenation Catalysts

(2013) M. R. Friedfeld et al.   SCIENCE

Preparation of Allyl and Vinyl Silanes by the Palladium-Catalyzed Silylation of Terminal Olefins: A Silyl-Heck Reaction

(2012) Jesse R. McAtee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

In Situ Platinum Recovery and Color Removal from Organosilicon Streams

(2012) He Bai   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Synthesis and Reactivity of Nickel Hydride Complexes of an α-Diimine Ligand

(2012) Qingsong Dong et al.   INORGANIC CHEMISTRY

Oxidative Addition of Carbon–Carbon Bonds with a Redox-Active Bis(imino)pyridine Iron Complex

(2012) Jonathan M. Darmon et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiopure C1-Symmetric Bis(imino)pyridine Cobalt Complexes for Asymmetric Alkene Hydrogenation

(2012) Sebastien Monfette et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium Catalyzed Hydroboration of Terminal Alkynes to Z-Vinylboronates

(2012) Chidambaram Gunanathan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electronic Effects in 4-Substituted Bis(imino)pyridines and the Corresponding Reduced Iron Compounds

(2012) Jonathan M. Darmon et al.   ORGANOMETALLICS

Synthesis, Electronic Structure, and Alkene Hydrosilylation Activity of Terpyridine and Bis(imino)pyridine Iron Dialkyl Complexes

(2012) Aaron M. Tondreau et al.   ORGANOMETALLICS

Iron Catalysts for Selective Anti-Markovnikov Alkene Hydrosilylation Using Tertiary Silanes

(2012) A. M. Tondreau et al.   SCIENCE

High-Selectivity Bis(imino)pyridine Iron Catalysts for the Hydrosilylation of 1,2,4-Trivinylcyclohexane

(2012) Crisita Carmen Hojilla Atienza et al.   ACS Catalysis

NHC-Cu-Catalyzed Enantioselective Hydroboration of Acyclic and Exocyclic 1,1-Disubstituted Aryl Alkenes

(2011) Rosa Corberán et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view

(2011) Dennis Troegel et al.   COORDINATION CHEMISTRY REVIEWS

Preface: Forum on Redox-Active Ligands

(2011) Paul J. Chirik   INORGANIC CHEMISTRY

Highly Selective Methods for Synthesis of Internal (α-) Vinylboronates through Efficient NHC–Cu-Catalyzed Hydroboration of Terminal Alkynes. Utility in Chemical Synthesis and Mechanistic Basis for Selectivity

(2011) Hwanjong Jang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly regio- and enantioselective catalytic asymmetric hydroboration of α-substituted styrenyl derivatives

(2010) Clément Mazet et al.   CHEMICAL COMMUNICATIONS

Synthesis of Aryl-Substituted Bis(imino)pyridine Iron Dinitrogen Complexes

(2010) Sarah K. Russell et al.   INORGANIC CHEMISTRY

Direct Hydrogenation of Amides to Alcohols and Amines under Mild Conditions

(2010) Ekambaram Balaraman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Radical Ligands Confer Nobility on Base-Metal Catalysts

(2010) P. J. Chirik et al.   SCIENCE

Iron-Catalyzed 1,4-Hydroboration of 1,3-Dienes

(2009) Jessica Y. Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dramatic Effect of Lewis Acids on the Rhodium-Catalyzed Hydroboration of Olefins

(2009) Christopher J. Lata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiopure Pyridine Bis(oxazoline) “Pybox” and Bis(oxazoline) “Box” Iron Dialkyl Complexes: Comparison to Bis(imino)pyridine Compounds and Application to Catalytic Hydrosilylation of Ketones

(2009) Aaron M. Tondreau et al.   ORGANOMETALLICS

Reduction Chemistry of Aryl- and Alkyl-Substituted Bis(imino)pyridine Iron Dihalide Compounds: Molecular and Electronic Structures of [(PDI)2Fe] Derivatives

(2008) Bradley M. Wile et al.   INORGANIC CHEMISTRY

Global Release Liner Industry Conference 2008

(2008) Andrew J. Holwell