Aminoalkyl radicals as halogen-atom transfer agents for activation of alkyl and aryl halides

Palladium-catalyzed reductive Heck reaction of α,β-unsaturated alkenes and cycloalkyl iodides

(2019) Zhenwei Liu et al.   TETRAHEDRON LETTERS

Direct Alkylation of 1-Azabicyclo[1.1.0]butanes

(2019) Ryan Gianatassio et al.   ORGANIC LETTERS

Cu(OTf)2-Promoted 1,4-Addition of Alkyl Bromides to Dehydroalanine

(2019) Jung-Ah Shin et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalyst-Free Deaminative Functionalizations of Primary Amines by Photoinduced Single-Electron Transfer

(2019) Jingjing Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-, Photocatalyst-, and Light-Free Minisci C–H Alkylation of N-Heteroarenes with Oxalates

(2019) Jianyang Dong et al.   JOURNAL OF ORGANIC CHEMISTRY

Radical Addition to Strained σ-Bonds Enables the Stereocontrolled Synthesis of Cyclobutyl Boronic Esters

(2019) Mattia Silvi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pyridinium Salts as Redox-Active Functional Group Transfer Reagents

(2019) Antonio Togni et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed para -Selective Alkylation of Electron-Deficient Arenes

(2018) Zhiwei Jiao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Thirty Years of (TMS)3SiH: A Milestone in Radical-Based Synthetic Chemistry

(2018) Chryssostomos Chatgilialoglu et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Decarboxylative Heck-Type Coupling of Activated Aliphatic Carboxylic Acids Enabled by Visible Light

(2018) Maximilian Koy et al.   CHEMISTRY-A EUROPEAN JOURNAL

Spin-Center Shift-Enabled Direct Enantioselective α-Benzylation of Aldehydes with Alcohols

(2018) Eric D. Nacsa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalysis of Radical Cyclizations from Alkyl Iodides under H2: Evidence for Electron Transfer from [CpV(CO)3H]−

(2018) Jonathan L. Kuo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Controlled Chemoselective C(acyl)–O Bond vs C(aryl)–C Bond Activation of Aromatic Esters in Nickel Catalyzed C(sp2)–C(sp3) Cross-Couplings

(2018) Adisak Chatupheeraphat et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electron Transfer Reactions: KOtBu (but not NaOtBu) Photo-reduces Benzophenone, under Activation by Visible Light

(2018) Giuseppe Nocera et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Switchable Decarboxylative Heck-Type Reaction and Oxo-alkylation of Styrenes with N-Hydroxyphthalimide Esters under Photocatalysis

(2018) Zi-Hao Xia et al.   ORGANIC LETTERS

Irradiation-Induced Palladium-Catalyzed Decarboxylative Heck Reaction of Aliphatic N-(Acyloxy)phthalimides at Room Temperature

(2018) Guang-Zu Wang et al.   ORGANIC LETTERS

A radical approach to the copper oxidative addition problem: Trifluoromethylation of bromoarenes

(2018) Chip Le et al.   SCIENCE

Lithium bis-catechol borate as an effective reductive quencher in photoredox catalysis

(2018) Martin J. Sevrin et al.   TETRAHEDRON

Radical Retrosynthesis

(2018) Joel M. Smith et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic dehydrogenative decarboxyolefination of carboxylic acids

(2018) Xiang Sun et al.   Nature Chemistry

Aminoalkyl Radicals as Powerful Intermediates for the Synthesis of Unnatural Amino Acids and Peptides

(2018) R. Adam Aycock et al.   ACS Catalysis

Forging C(sp3)–C(sp3) Bonds with Carbon-Centered Radicals in the Synthesis of Complex Molecules

(2018) Spencer P. Pitre et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light-Induced Decarboxylative C–H Adamantylation of Azoles at Ambient Temperature

(2018) Lutz Ackermann et al.   SYNTHESIS-STUTTGART

β-Selective Reductive Coupling of Alkenylpyridines with Aldehydes and Imines via Synergistic Lewis Acid/Photoredox Catalysis

(2017) Katarzyna N. Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Irradiation-Induced Heck Reaction of Unactivated Alkyl Halides at Room Temperature

(2017) Guang-Zu Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Radical Deuteration with D2O: Catalysis and Mechanistic Insights

(2017) Valentin Soulard et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Reductive Conjugate Addition of Primary Alkyl Bromides to Enones To Form Silyl Enol Ethers

(2017) Kierra M. M. Huihui et al.   ORGANIC LETTERS

Cross-Coupling Reactions of Aryldiazonium Salts with Allylsilanes under Merged Gold/Visible-Light Photoredox Catalysis

(2017) Manjur O. Akram et al.   ORGANIC LETTERS

Photoredox-catalyzed deuteration and tritiation of pharmaceutical compounds

(2017) Yong Yao Loh et al.   SCIENCE

Photoinduced decarboxylative borylation of carboxylic acids

(2017) Alexander Fawcett et al.   SCIENCE

Recent Advances in Nickel Catalysis Enabled by Stoichiometric Metallic Reducing Agents

(2017) Edward Richmond et al.   SYNTHESIS-STUTTGART

Photoredox-Mediated Routes to Radicals: The Value of Catalytic Radical Generation in Synthetic Methods Development

(2017) Jennifer K. Matsui et al.   ACS Catalysis

Synthetic Utilization of α-Aminoalkyl Radicals and Related Species in Visible Light Photoredox Catalysis

(2016) Kazunari Nakajima et al.   ACCOUNTS OF CHEMICAL RESEARCH

Core chemotype diversification in the HIV-1 entry inhibitor class using field-based bioisosteric replacement

(2016) Marina Tuyishime et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Organic photoredox catalysis for the oxidation of silicates: applications in radical synthesis and dual catalysis

(2016) Christophe Lévêque et al.   CHEMICAL COMMUNICATIONS

Organic Photoredox Catalysis

(2016) Nathan A. Romero et al.   CHEMICAL REVIEWS

Silyl Radical Activation of Alkyl Halides in Metallaphotoredox Catalysis: A Unique Pathway for Cross-Electrophile Coupling

(2016) Patricia Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Arylation of Pyrroles via Indirect Electroreductive C–H Functionalization Using Perylene Bisimide as an Electron-Transfer Mediator

(2016) Guoquan Sun et al.   ORGANIC LETTERS

Visible-Light-Promoted Atom Transfer Radical Cyclization of Unactivated Alkyl Iodides

(2016) Yangyang Shen et al.   ACS Catalysis

Donor–Acceptor Fluorophores for Visible-Light-Promoted Organic Synthesis: Photoredox/Ni Dual Catalytic C(sp3)–C(sp2) Cross-Coupling

(2016) Jian Luo et al.   ACS Catalysis

Visible-Light-Induced Decarboxylative Functionalization of Carboxylic Acids and Their Derivatives

(2015) Jun Xuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed Cross-Coupling of 3- and 4-Iodopiperidines with Grignard Reagents

(2015) Laurine Gonnard et al.   CHEMISTRY-A EUROPEAN JOURNAL

Sulfate Radical Anion (SO4•–) Mediated C(sp3)–H Nitrogenation/Oxygenation in N-Aryl Benzylic Amines Expanded the Scope for the Synthesis of Benzamidine/Oxazine Heterocycles

(2015) Joydev K. Laha et al.   JOURNAL OF ORGANIC CHEMISTRY

Selective Radical–Radical Cross-Couplings: Design of a Formal β-Mannich Reaction

(2015) Jenna L. Jeffrey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling

(2015) Christopher C. Nawrat et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Cross-Coupling Reaction of Allyl Boron Ester with 1°/2°/3°-Halogenated Alkanes

(2015) Guang-Zu Wang et al.   ORGANIC LETTERS

Experimental and Calculated Electrochemical Potentials of Common Organic Molecules for Applications to Single-Electron Redox Chemistry

(2015) David Nicewicz et al.   SYNLETT

Simple Sulfinate Synthesis Enables CH Trifluoromethylcyclopropanation

(2014) Ryan Gianatassio et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cross-Electrophile Coupling: Principles of Reactivity and Selectivity

(2014) Daniel A. Everson et al.   JOURNAL OF ORGANIC CHEMISTRY

Reduction of aryl halides by consecutive visible light-induced electron transfer processes

(2014) I. Ghosh et al.   SCIENCE

Photocatalytic Dehalogenation of Vicinal Dibromo Compounds Utilizing Sexithiophene and Visible-Light Irradiation

(2014) Christopher D. McTiernan et al.   ACS Catalysis

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

Solvent Effect on Thermally Activated Delayed Fluorescence by 1,2,3,5-Tetrakis(carbazol-9-yl)-4,6-dicyanobenzene

(2013) Ryoichi Ishimatsu et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Room-Temperature Arylation of Arenes and Heteroarenes with Diaryl­iodonium Salts by Photoredox Catalysis

(2013) Dong Xue et al.   SYNLETT

Direct, Enantioselective Iridium-Catalyzed Allylic Amination of Racemic Allylic Alcohols

(2012) Marc Lafrance et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Induced Photocatalytic Reductive Transformations of Organohalides

(2012) Hyejin Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free arylation of benzene and pyridine promoted by amino-linked nitrogen heterocyclic carbenes

(2012) Wen-Ching Chen et al.   CHEMICAL COMMUNICATIONS

Electrochemically Induced Chemically Reversible Proton-Coupled Electron Transfer Reactions of Riboflavin (Vitamin B2)

(2012) Serena L. J. Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Practical and innate carbon–hydrogen functionalization of heterocycles

(2012) Yuta Fujiwara et al.   NATURE

Engaging unactivated alkyl, alkenyl and aryl iodides in visible-light-mediated free radical reactions

(2012) John D. Nguyen et al.   Nature Chemistry

A palladium chelating complex of ionic water-soluble nitrogen-containing ligand: the efficient precatalyst for Suzuki–Miyaura reaction in water

(2011) Chunshan Zhou et al.   GREEN CHEMISTRY

Effect of the damping function in dispersion corrected density functional theory

(2011) Stefan Grimme et al.   JOURNAL OF COMPUTATIONAL CHEMISTRY

Copper-Catalyzed C(sp3)–C(sp3) Bond Formation Using a Hypervalent Iodine Reagent: An Efficient Allylic Trifluoromethylation

(2011) Xi Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Improving the Atom Efficiency of the Wittig Reaction by a “Waste as Catalyst/Co-catalyst” Strategy

(2010) Jun-Jie Cao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

(2010) Stefan Grimme et al.   JOURNAL OF CHEMICAL PHYSICS

Palladium-Catalyzed Cross-Coupling Reactions of Potassium Alkenyltrifluoroborates with Organic Halides in Aqueous Media†

(2009) Emilio Alacid et al.   JOURNAL OF ORGANIC CHEMISTRY

Preparation of Heteroaryloxetanes and Heteroarylazetidines by Use of a Minisci Reaction

(2009) Matthew A. J. Duncton et al.   JOURNAL OF ORGANIC CHEMISTRY

Halogen abstraction reaction between aminoalkyl radicals and alkyl halides: Unusual high rate constants

(2008) J. Lalevée et al.   CHEMICAL PHYSICS LETTERS