期刊
ACS CATALYSIS
卷 7, 期 1, 页码 409-412出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b03205
关键词
visible light; alkyl halide; photocatalysis; atom economy; radical cyclization
资金
- ICIQ
- European Research Council [ERC-277883]
- MINECO [CTQ2015-65496-R]
- MINECO (Severo Ochoa Excellence Accreditation) [SEV-2013-0319]
- Cellex Foundation
- CSC
- COFUND
- European Union [FP7-PEOPLE-2012-IEF-328381]
- ICREA Funding Source: Custom
A visible-light-mediated atom transfer radical cyclization of unactivated alkyl iodides is described. This protocol operates under mild conditions and exhibits high chemoselectivity profile while avoiding parasitic hydrogen atom transfer pathways. Preliminary mechanistic studies challenge the perception that a canonical photoredox catalytic cycle is being operative.
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