Asymmetric Synthesis of Heterocyclic γ-Amino-Acid and Diamine Derivatives by Three-Component Radical Cascade Reactions

Photocatalytic decarboxylative alkylations mediated by triphenylphosphine and sodium iodide

(2019) Ming-Chen Fu et al.   SCIENCE

Recent Advances in Minisci-Type Reactions

(2019) Rupert S. J. Proctor et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Divergent Synthesis of CF3 -Substituted Allenyl Nitriles by Ligand-Controlled Radical 1,2- and 1,4-Addition to 1,3-Enynes

(2018) Fei Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Copper Catalyst with a Cinchona-Alkaloid-Based Sulfonamide Ligand for Asymmetric Radical Oxytrifluoromethylation of Alkenyl Oximes

(2018) Xi-Tao Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic enantioselective Minisci-type addition to heteroarenes

(2018) Rupert S. J. Proctor et al.   SCIENCE

Organocatalytic Enantioselective Addition of α-Aminoalkyl Radicals to Isoquinolines

(2018) Xiangyuan Liu et al.   ORGANIC LETTERS

Cu/Chiral Phosphoric Acid-Catalyzed Asymmetric Three-Component Radical-Initiated 1,2-Dicarbofunctionalization of Alkenes

(2018) Jin-Shun Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoinitiated Three-Component α-Perfluoroalkyl-β-heteroarylation of Unactivated Alkenes via Electron Catalysis

(2018) Danqing Zheng et al.   ORGANIC LETTERS

Asymmetric Cu-Catalyzed Intermolecular Trifluoromethylarylation of Styrenes: Enantioselective Arylation of Benzylic Radicals

(2017) Lianqian Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Copper-Catalyzed Intermolecular Aminoarylation of Styrenes: Efficient Access to Optical 2,2-Diarylethylamines

(2017) Dinghai Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Intermolecular Azidoheteroarylation of Simple Alkenes via Free-Radical Multicomponent Cascade Reactions

(2017) Zhi Liu et al.   ORGANIC LETTERS

Catalytic asymmetric radical aminoperfluoroalkylation and aminodifluoromethylation of alkenes to versatile enantioenriched-fluoroalkyl amines

(2017) Jin-Shun Lin et al.   Nature Communications

Visible Light-Mediated Direct Decarboxylative C–H Functionalization of Heteroarenes

(2017) R. Aleyda Garza-Sanchez et al.   ACS Catalysis

Catalytic Asymmetric Radical Diamination of Alkenes

(2017) Fu-Li Wang et al.   Chem

Synthesis of Chiral Sulfonyl Lactones via Copper-Catalyzed Asymmetric Radical Reaction of DABCO⋅(SO2 )

(2017) Yang Wang et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Enantioselective Functionalization of Unactivated Terminal Alkenes

(2016) John R. Coombs et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Markovnikov free radical addition reactions, a sleeping beauty kissed to life

(2016) Reinhard W. Hoffmann   CHEMICAL SOCIETY REVIEWS

A Dual-Catalytic Strategy To Direct Asymmetric Radical Aminotrifluoromethylation of Alkenes

(2016) Jin-Shun Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Copper-Catalyzed Intermolecular Cyanotrifluoromethylation of Alkenes via Radical Process

(2016) Fei Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct alkylation of heteroarenes with unactivated bromoalkanes using photoredox gold catalysis

(2016) T. McCallum et al.   Chemical Science

Photoredox-mediated Minisci C–H alkylation of N-heteroarenes using boronic acids and hypervalent iodine

(2016) Guo-Xing Li et al.   Chemical Science

Photoredox/Brønsted Acid Co-Catalysis Enabling Decarboxylative Coupling of Amino Acid and Peptide Redox-Active Esters with N-Heteroarenes

(2016) Wan-Min Cheng et al.   ACS Catalysis

Olefinic C–H functionalization through radical alkenylation

(2015) Shan Tang et al.   CHEMICAL SOCIETY REVIEWS

Versatile Enantioselective Synthesis of Functionalized Lactones via Copper-Catalyzed Radical Oxyfunctionalization of Alkenes

(2015) Rong Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alcohols as alkylating agents in heteroarene C–H functionalization

(2015) Jian Jin et al.   NATURE

Direct α-Arylation of Ethers through the Combination of Photoredox-Mediated CH Functionalization and the Minisci Reaction

(2014) Jian Jin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective, Intermolecular Hydroamination of Allenyl Esters Catalyzed by Bifunctional Phosphinothioureas

(2014) Yuan-Qing Fang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Radical Addition to Iminium Ions and Cationic Heterocycles

(2014) Johannes Tauber et al.   MOLECULES

Highly Enantioselective γ-Amination by N-Heterocyclic Carbene Catalyzed [4+2] Annulation of Oxidized Enals and Azodicarboxylates

(2013) Xiang-Yu Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Peptide-Catalyzed Stereoselective Conjugate Addition Reactions Generating All-Carbon Quaternary Stereogenic Centers

(2013) Robert Kastl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Functionalization of Radical Intermediates in Redox Catalysis: Copper-Catalyzed Asymmetric Oxytrifluoromethylation of Alkenes

(2013) Rong Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in Catalytic Sequential Reactions Involving Hydroelement Addition to Carbon–Carbon Multiple Bonds

(2013) Xiaoming Zeng   CHEMICAL REVIEWS

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

Construction of an All-Carbon Quaternary Stereocenter by the Peptide-Catalyzed Asymmetric Michael Addition of Nitromethane to β-Disubstituted α,β-Unsaturated Aldehydes

(2012) Kengo Akagawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intramolecular Alkoxycyanation and Alkoxyacylation Reactions: New Types of Alkene Difunctionalizations for the Construction of Oxygen Heterocycles

(2012) John P. Wolfe   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

γ-Amino Alcohols via Organocascade Reactions Involving Dienamine Catalysis

(2012) Chandrakumar Appayee et al.   JOURNAL OF ORGANIC CHEMISTRY

Side-Arm-Promoted Highly Enantioselective Ring-Opening Reactions and Kinetic Resolution of Donor–Acceptor Cyclopropanes with Amines

(2012) You-Yun Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Drug Discovery Targeting Amino Acid Racemases

(2011) Paola Conti et al.   CHEMICAL REVIEWS

Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications

(2011) Richard I. McDonald et al.   CHEMICAL REVIEWS

Highly Enantioselective γ-Amination of α,β-Unsaturated Acyl Chlorides with Azodicarboxylates: Efficient Synthesis of Chiral γ-Amino Acid Derivatives

(2011) Li-Tao Shen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Minisci reactions: Versatile CH-functionalizations for medicinal chemists

(2011) Matthew A. J. Duncton   MedChemComm

Structural Chemistry of Peptides Containing Backbone Expanded Amino Acid Residues: Conformational Features of β, γ, and Hybrid Peptides

(2010) Prema. G. Vasudev et al.   CHEMICAL REVIEWS

Catalytic Asymmetric Conjugate Addition of Nitroalkanes to 4-Nitro-5-styrylisoxazoles

(2009) Andrea Baschieri et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereospecific Synthesis of Conformationally Constrained γ-Amino Acids: New Foldamer Building Blocks That Support Helical Secondary Structure

(2009) Li Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of γ-Amino Esters via Mn-Mediated Radical Addition to Chiral γ-Hydrazonoesters

(2009) Gregory K. Friestad et al.   ORGANIC LETTERS

Hydroamination: Direct Addition of Amines to Alkenes and Alkynes

(2008) Thomas E. Müller et al.   CHEMICAL REVIEWS

Peptide Catalyzed Asymmetric Conjugate Addition Reactions of Aldehydes to Nitroethylene—A Convenient Entry into γ2-Amino Acids

(2008) Markus Wiesner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Organocatalytic Michael Addition of Aldehydes to Nitroethylene: Efficient Access to γ2-Amino Acids

(2008) Yonggui Chi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Tertiary Diamines in Asymmetric Synthesis

(2007) Jean-Claude Kizirian   CHEMICAL REVIEWS