期刊
ORGANIC LETTERS
卷 21, 期 1, 页码 325-329出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b03849
关键词
-
资金
- Alexander von Humboldt Foundation
- European Research Council (ERC) [692640]
A visible-light-initiated alpha-perfluoroalkyl-beta-heteroarylation of various alkenes with perfluoroalkyl iodides and quinoxalin-2(1H)-ones is presented. This three-component radical cascade reaction allows an efficient synthesis of a range of perfluoroalkyl containing quinoxalin-2(1H)-one derivatives in moderate to excellent yields under mild conditions. Reactions proceed via acidic aminyl radicals that are readily deprotonated to give the corresponding radical anions able to sustain the radical chain as single electron transfer reducing reagents. Hence, the overall cascade classifies as an electron-catalyzed process.
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