Organocatalytic Enantioselective Vinylogous Pinacol Rearrangement Enabled by Chiral Ion Pairing

Copper-Catalyzed Formal [2+2+1] Heteroannulation of Alkenes, Alkylnitriles, and Water: Method Development and Application to a Total Synthesis of (±)-Sacidumlignan D

(2016) Tu M. Ha et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Phosphoric Acid Catalyzed Asymmetric Ugi Reaction by Dynamic Kinetic Resolution of the Primary Multicomponent Adduct

(2016) Yun Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Phosphoric Acid-Catalyzed Enantioselective Formal [3+2] Cycloaddition of Azomethine Imines with Enecarbamates

(2016) Yang Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Dual Catalysis Using Boronic Acid and Chiral Amine: Acyclic Quaternary Carbons via Enantioselective Alkylation of Branched Aldehydes with Allylic Alcohols

(2016) Xiaobin Mo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in research on lignans and neolignans

(2016) Rémy Bertrand Teponno et al.   NATURAL PRODUCT REPORTS

Catalytic Asymmetric 1,6-Conjugate Addition ofpara-Quinone Methides: Formation of All-Carbon Quaternary Stereocenters

(2015) Zhaobin Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Applications of Supramolecular Anion Recognition

(2015) Nathalie Busschaert et al.   CHEMICAL REVIEWS

Enantioselective Halogenative Semi-Pinacol Rearrangement: Extension of Substrate Scope and Mechanistic Investigations

(2015) Fedor Romanov-Michailidis et al.   CHEMISTRY-A EUROPEAN JOURNAL

Phosphoric Acid Catalyzed Desymmetrization of Bicyclic Bislactones Bearing an All-Carbon Stereogenic Center: Total Syntheses of (−)-Rhazinilam and (−)-Leucomidine B

(2014) Jean-Baptiste Gualtierotti et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Piperidines through the Formation of Chiral Mixed Phosphoric Acid Acetals: Experimental and Theoretical Studies

(2014) Zhankui Sun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates

(2014) Dixit Parmar et al.   CHEMICAL REVIEWS

Catalytic Asymmetric α-Iminol Rearrangement: New Chiral Platforms

(2014) Xin Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Brønsted acid catalyzed enantioselective intermolecular allylic aminations

(2014) Minyang Zhuang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

An Organocatalytic Asymmetric Allylic Alkylation Allows Enantioselective Total Synthesis of Hydroxymetasequirin-A and Metasequirin-B Tetramethyl Ether Diacetates

(2014) Pu-Sheng Wang et al.   ORGANIC LETTERS

The Anion-Binding Approach to Catalytic Enantioselective Acyl Transfer

(2014) Daniel Seidel   SYNLETT

Enantio- and Diastereoselective Assembly of Tetrahydrofuran and Tetrahydropyran Skeletons with All-Carbon-Substituted Quaternary Stereocenters

(2013) Zhilong Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Michael Addition of α-Aryl-α-Isocyanoacetates to Vinyl Selenone: Synthesis of α,α-Disubstituted α-Amino Acids and (+)- and (−)-Trigonoliimine A

(2013) Thomas Buyck et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Organocatalytic Fluorination-Induced Wagner-Meerwein Rearrangement

(2013) Fedor Romanov-Michailidis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic asymmetric semipinacol rearrangements

(2013) Shao-Hua Wang et al.   CHEMICAL COMMUNICATIONS

Cascade Oxidative Dearomatization/Semipinacol Rearrangement: An Approach to 2-Spirocyclo-3-oxindole Derivatives

(2013) Jin-Bao Peng et al.   Chemistry-An Asian Journal

Enantioselective Organocatalytic Iodination-Initiated Wagner–Meerwein Rearrangement

(2013) Fedor Romanov-Michailidis et al.   ORGANIC LETTERS

14-Step Synthesis of (+)-Ingenol from (+)-3-Carene

(2013) L. Jorgensen et al.   SCIENCE

Asymmetric Ion-Pairing Catalysis

(2012) Katrien Brak et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Counteranion-Directed Catalysis: Concept, Definition, and Applications

(2012) Manuel Mahlau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric binary acid catalysis: chiral phosphoric acid as dual ligand and acid

(2012) Jian Lv et al.   CHEMICAL COMMUNICATIONS

Organocatalytic Enantioselective One-Pot Four-Component Ugi-Type Multicomponent Reaction for the Synthesis of Epoxy-tetrahydropyrrolo[3,4-b]pyridin-5-ones

(2012) Yingpeng Su et al.   CHEMISTRY-A EUROPEAN JOURNAL

Total Synthesis of (−)-Sacidumlignans B and D

(2012) Jeetendra Kumar Rout et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric spiroacetalization catalysed by confined Brønsted acids

(2012) Ilija Čorić et al.   NATURE

The progression of chiral anions from concepts to applications in asymmetric catalysis

(2012) Robert J. Phipps et al.   Nature Chemistry

Brønsted-Acid-Catalyzed Asymmetric Multicomponent Reactions for the Facile Synthesis of Highly Enantioenriched Structurally Diverse Nitrogenous Heterocycles

(2011) Jie Yu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Stereoselective Construction of Quaternary Carbon Stereocenters via a Semipinacol Rearrangement Strategy

(2011) Baomin Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cinchona Alkaloid Amide Catalyzed Enantioselective Formal [2+2] Cycloadditions of Allenoates and Imines: Synthesis of 2,4-Disubstituted Azetidines

(2011) Jean-Baptiste Denis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Divergent Synthetic Routes for Ring Expansion or Cyclization from 1,4-Allylic Diol Derivatives via Gold(I) Catalysis or Zinc(II) Mediation

(2011) Li−Li Zhu et al.   JOURNAL OF ORGANIC CHEMISTRY

Chiral Phosphoric Acid-Catalyzed Enantioselective Three-Component Povarov Reaction Using Enecarbamates as Dienophiles: Highly Diastereo- and Enantioselective Synthesis of Substituted 4-Aminotetrahydroquinolines

(2011) Guillaume Dagousset et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Organic Contact Ion Pairs in Metal-Free Catalytic Asymmetric Allylic Substitutions

(2011) Magnus Rueping et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric synthesis of a dopamine D1 agonist, dihydrexidine from d-serine

(2011) Rajesh Malhotra et al.   TETRAHEDRON-ASYMMETRY

Chiral Brønsted Acid Catalyzed Pinacol Rearrangement

(2010) Tao Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Organocatalytic Rearrangement Reactions

(2010) Albert Moyano et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Asymmetric Transacetalization

(2010) Ilija Čorić et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations

(2010) Masahiro Terada   SYNTHESIS-STUTTGART

Brønsted Acid Catalyzed Enantioselective Semipinacol Rearrangement for the Synthesis of Chiral Spiroethers

(2009) Qing-Wei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

(Thio)urea organocatalysis—What can be learnt from anion recognition?

(2009) Zhiguo Zhang et al.   CHEMICAL SOCIETY REVIEWS

Gold(I)-Catalyzed Enantioselective Ring Expansion of Allenylcyclopropanols

(2009) Florian Kleinbeck et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Direct Aldol-Type Reaction of Azlactone via Protonation of Vinyl Ethers by a Chiral Brønsted Acid Catalyst

(2009) Masahiro Terada et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Asymmetric Vinylogous α-Ketol Rearrangement: Enantioselective Construction of Chiral All-Carbon Quaternary Stereocenters in Spirocyclic Diketones via Semipinacol-Type 1,2-Carbon Migration

(2009) En Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen-Bond-Mediated Asymmetric Catalysis

(2008) Xinhong Yu et al.   Chemistry-An Asian Journal

Chiral Anion-Mediated Asymmetric Ring Opening ofmeso-Aziridinium and Episulfonium Ions

(2008) Gregory L. Hamilton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Diastereo- and Enantioselective Wagner−Meerwein Shift: Control of Absolute Stereochemistry in the C−C Bond Migration Event

(2008) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Thiourea-Catalyzed Additions to Oxocarbenium Ions

(2008) Sarah E. Reisman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Brønsted Acid Catalyst for the Enantioselective Protonation Reaction

(2008) Cheol Hong Cheon et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY